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    Production of 1,2-benzoisothiazoles
    1.
    发明授权
    Production of 1,2-benzoisothiazoles 失效
    生产1,2-苯并唑烷

    公开(公告)号：US3682941A

    公开(公告)日：1972-08-08

    申请号：US3682941D

    申请日：1970-10-15

    Applicant: BASF AG

    Inventor： BECKE FRIEDRICH ,  HAGEN HELMUTH

    IPC: C07D275/04 ,  C07D91/12

    CPC classification number: C07D275/04

    Abstract: Production of 1,2-benzoisothiazoles by reacting dihalomethylaryl compounds with ammonia and elementary sulfur. The products are valuable starting materials for the production of dyes, rubber auxiliaries and oxidation inhibitors.

    Abstract translation: 通过二卤甲基芳基化合物与氨和元素硫反应制备1,2-苯并异噻唑。 该产品是生产染料，橡胶助剂和氧化抑制剂的有价值的原料。

    Production of dithiocarbamates
    2.
    发明授权
    Production of dithiocarbamates 失效
    生产二硫代碳酸酯

    公开(公告)号：US3607870A

    公开(公告)日：1971-09-21

    申请号：US3607870D

    申请日：1968-05-13

    Applicant: BASF AG

    Inventor： BECKE FRIEDRICH ,  HAGEN HELMUTH

    IPC: C07D295/21 ,  C07D87/46

    CPC classification number: C07D295/21

    Abstract: Production of dithiocarbamates by reacting halogenated methanes with elementary sulfur and secondary amines. The products are valuable starting materials for the production of herbicides, fungicides, insecticides, rubber auxiliaries, and stabilizers in the petroleum industry.

    9.
    发明专利
    未知

    公开(公告)号：FR1499786A

    公开(公告)日：1967-10-27

    申请号：FR83792

    申请日：1966-11-16

    Applicant: BASF AG

    Inventor： BECKE FRIEDRICH ,  HAGEN HELMUTH

    Abstract: 1,156,158. Hydroxy alkane- and alkenenitriles. BADISCHE ANILIN- & SODAFABRIK A.G. 16 Nov., 1966 [17 Nov., 1965], No. 51327/66. Heading C2C. Nitriles of hydroxyalkane- and hydroxyalkene-carboxylic acids, in which the hydroxy group is separated from the nitrile group by at least 6 carbons, are obtained by heating the corresponding hydroxyalkane- or hydroxyalkene-carboxylic acids, the ammonium salts or the amides thereof in the presence of at least 2 moles of ammonia per mole of acid or at least one mole of ammonia per mole of the ammonium salt or amide of the said acid to a temperature of 250-400‹ C. in the absence of dehydration catalysts at a pressure of 50-150 atmospheres. The ammonia is preferably used in an amount of 10-30 moles per mole of acid, ammonium salt or amide and water or steam may be added to the reaction mixture. In examples, 7-hydroxy-enanthic acid and ricinoleic acid are converted to the corresponding nitriles.

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