Novel thermally-crosslinkable tri:aryl:amine(s)

    公开(公告)号:DE19643097A1

    公开(公告)日:1998-04-23

    申请号:DE19643097

    申请日:1996-10-18

    Applicant: BASF AG

    Abstract: Novel triarylamines of formula (I)a re claimed. Also claimed are: (1) mixtures of (I) with triarylamines of formula (II); (2) compositions comprising (I) (and optionally also (II)) together with comonomers; and (3) polymers obtained by thermally crosslinking any of the above. Ar and Ar = benzo-annelated homo- or hetero-aromatic groups optionally with one to four 1-6C alkyl, alkoxy or acyl, -COO(1-6C alkyl), oxy(1-6C acyl), halogen, COOH, CHO, OH, SO2H, SO3H, CN, SCN, OCN or NO2 substituents but with the proviso that Ar and/or Ar is substituted by an ethinyl group -C?=CH; X = m-valent group with one or more -C?=CH substituents; m = 1 is as for Ar and Ar ; m and n = 1-6; Ar and Ar = as for Ar and Ar but with the proviso that at least one of them is substituted with at least one -C?=C-Z-R group; Z = a single bond, -O-, -CO-, -COO-, -OOC-, -N(1-6C alkyl)-CO-, -OC-N(1-6C alkyl)- or -(CH2)1-6-; R = H, 1-6C alkyl or benzo-annelated homo- or hetero -aromatic group with 1-4 substituents as per Ar and Ar above with the proviso that at least one R is not H when Z is a single bond and (II) contains more than one -C?=C-Z-R group; Y = an n-valent group which is optionally substituted by one or more -C?=C-Z-R groups; and which is as per Ar and Ar when n = 1.

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