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公开(公告)号:DE59608335D1
公开(公告)日:2002-01-17
申请号:DE59608335
申请日:1996-03-19
Applicant: BASF AG
Inventor: BITTINS DR , HEIDER DR , SCHMIDT-RADDE DR , KELLENBENZ DR , WAGNER KURT JOSEF , ZEHNER DR , BERG DR
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公开(公告)号:DE59610615D1
公开(公告)日:2003-08-28
申请号:DE59610615
申请日:1996-06-27
Applicant: BASF AG
Inventor: HENKELMANN DR , HEIDER DR , RUEHL DR
IPC: B01J31/02 , C07B61/00 , C07D233/56 , C07D233/58 , C07D235/06 , C07D249/08 , C07D521/00
Abstract: Prepn. of N-alkenyl azoles of formula (I) is by reaction of azoles (II) with alkenyl carboxylic acid esters (III) at 0-180 degC/0.01-10 bar. The novel feature being that the reaction is in presence of a base and a quat. salt. X = CHR or N; R and R = H or 1-8C alkyl R -R = H; 1-40C alkyl; 2-40C alkenyl; 3-20C cycloalkyl; 4-20C alkylcycloalkyl or cycloalkyl-alkyl; or aryl or 7-20C alkaryl or aralkyl each opt substd up to 5 times by 1-8C alkyl or alkoxy or halogen; or R +R , R +R or R +R together form a 2-10C alkylene chain opt. substd. up to 6 times by 1-8C alkyl; and R = H; 1-40C alkyl; 3-20C cycloalkyl; 4-20C alkyl-cycloalkyl; aryl or 7-20C aralkyl, each opt. substd. up to 3 times by 1-8C alkyl; or 7-20C alkaryl.
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公开(公告)号:DE59509999D1
公开(公告)日:2002-02-21
申请号:DE59509999
申请日:1995-10-06
Applicant: BASF AG
Inventor: RUEHL DR , MUELLER ROLF , HENKELMANN DR , HEIDER DR
IPC: C07C29/42 , C07C33/04 , C07C33/042 , C07C33/048 , C07C45/68 , C07F1/02
Abstract: Preparation of a monolithium acetylide/ammonia complex by the reaction of lithium amide and acetylene in ammonia, by carrying out the reaction at a temperature of from -10 DEG to 30 DEG C.
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