公开(公告)号：JP2000169149A

公开(公告)日：2000-06-20

申请号：JP34350099

申请日：1999-12-02

Applicant: BASF AG

Inventor： HEIKO ARNOLD DR ,  HARTH KLAUS ,  NEUMANN HANS-PETER ,  HAMMON ULRICH ,  FELDER RAIMUND DR

IPC: C01G49/00 ,  B01J21/16 ,  B01J23/78 ,  B01J23/88 ,  B01J23/887 ,  C01B33/32 ,  C01G29/00 ,  C01G51/00 ,  C01G53/00 ,  C07B61/00 ,  C07C45/33 ,  C07C45/34 ,  C07C45/35 ,  C07C51/25 ,  C07C57/055

Abstract: PROBLEM TO BE SOLVED: To improve activity and selectivity in gas phase oxidation and to improve the space-time yield by preparing the multiple oxide containing Mo, Bi, Co, Ni, Fe, Si, Al, alkali metals and O in a specified compsn. and having a crystal fraction containing compds. in a specified compsn. SOLUTION: This multiple metal oxide material has the compsn. expressed by Mo12BiaX1bFecX2dX3eOy, wherein X1 is Co and/or Ni, X2 is Si and/or Al, X3 is alkali metals, a, b, c, d and e satisfy 3

公开(公告)号：DE59913859D1

公开(公告)日：2006-11-02

申请号：DE59913859

申请日：1999-12-01

Applicant: BASF AG

Inventor： HEIKO ARNOLD DR ,  HARTH KLAUS DR ,  NEUMANN HANS-PETER DR ,  HAMMON ULRICH DR ,  FELDER RAIMUND DR

IPC: B01J37/04 ,  B01J21/16 ,  C01G49/00 ,  B01J23/78 ,  B01J23/88 ,  B01J23/887 ,  B01J37/02 ,  C01B33/32 ,  C01G29/00 ,  C01G51/00 ,  C01G53/00 ,  C07B61/00 ,  C07C45/33 ,  C07C45/34 ,  C07C45/35 ,  C07C51/25 ,  C07C57/055

Abstract: Multimetal oxide mass is of the following expression Mo12BiaX bFecX dX eOy (I), where X is Co and/or Ni; X is Si and/or Al; X is alkali; 0.3 ≤ a ≤ 1; 2 ≤ b ≤ 10; 0.5 ≤ c ≤ 10; 0 ≤ 10; 0 ≤ e ≤ 0.5 and y is a number which is produced by the sum of the valencies and the stoichiometric coefficient of the remaining elements, where in the crystalline portion, lies beta -X MoO4as main component, Fe2(MoO4)3 as sub component and no MoO3. Independent claim is included for (a) process for producing multi-metal oxide, (b) use of multi-metal oxide and (c) catalyst in the form of stone chips, mold body or shell catalyst.