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    2.
    发明专利
    未知

    公开(公告)号：DE1180511B

    公开(公告)日：1964-10-29

    申请号：DEB0054947

    申请日：1960-09-26

    Applicant: BASF AG

    Inventor： FIKENTSCHER DR HANS ,  HERRLE DR KARL ,  SCHLEMMER LOTHAR ,  WAGNER DR HERBERT

    IPC: B29C47/88 ,  B29C71/00 ,  B29D7/00 ,  B29D7/01

    Abstract: Cast films of polyvinyl chloride, or copolymers containing a major proportion thereof, are drawn from the casting support while still containing solvent and after-dried at 150 DEG -300 DEG C., while held only at the sides, to produce a practically solvent-free film. As shown, the sides of the film may be applied to two endless spiked bands or clamp chains c (Fig. 1), by pressure rollers b, and dried in the heated chamber d. Alternatively (Fig. 2), the sides of the film may be applied by deflecting rollers b1 to two driving discs a1, on which the film is held by an endless wire cable or chain c1, and the film subsequently dried in chamber d1. Conventional heating means are used. By leading the spiked bands or clamp chains apart or by canting the discs a1, the film may be stretched transversely during drying. Films so made have a high gloss and are suitable for packaging. Examples describe the preparation of films from solutions in tetrahydrofurane, and in acetone-toluene mixtures.

    9.
    发明专利
    未知

    公开(公告)号：DE1240286B

    公开(公告)日：1967-05-11

    申请号：DEB0079970

    申请日：1965-01-02

    Applicant: BASF AG

    Inventor： HERRLE DR KARL ,  BECKMANN DR-ING WILHELM

    IPC: B01J10/00 ,  B01J19/24 ,  C08F2/00 ,  C08F2/22 ,  C08F1/06

    Abstract: A process for the continuous emulsion polymerization of conventional olefinically unsaturated monomers which are practically insoluble or at most partly soluble in water, in aqueous medium in the presence of conventional polymerization catalysts, comprises continuous supplying monomers exclusively in the form of a preformed aqueous emulsion through a tube in an upward flow at a flow velocity of 5 to 100 cm. per sec. to the lower part of a vertically arranged circulation system, blending with an excess of polymer dispersion which has already formed, and polymerizing in the circulation system without the use of mechanical stirrers to a mean conversion of more than 75%, the polymer dispersion being withdrawn at a point not higher than the point of entry of the monomer emulsion into the circulation system and at the same rate as the monomer emulsion is supplied. Optional process features include preblending of monomer with polymer, a temperature difference between ascending and descending parts, bubbling inert gas through the ascending part, boiling the ascending dispersion with the aid of reduced pressure, and complex circulation systems. In examples, monomers polymerized are: (1) butyl acrylate-acrylic acid, (2) and (3) methyl methacrylate in the presence of dispersed polymethyl methacrylate, (4) and (5) butyl acrylate-vinyl acetate-acrylic acid, (6) and (7) vinyl propionate-sodium vinyl sulphonate, (8) styrene-acrylic acid-acrylonitrile, (9) vinylidene chloride-acrylonitrile-methacrylamide and (10) butyl acrylate-vinyl acetate-sodium vinyl sulphonate-acrylic acid; the catalyst being potassium persulphate or azodiisobutyronitrile and the emulsifier being selected from dodecylbenzene sulphonate, C10-C16-alkyl sulphonate, polyethoxylated octadecyl alcohol, turkey red oil and sodium salt of sulphochlorinated paraffins. The process can also be applied using other monomers such as ethyl acrylate, vinyl pivalate, vinyl chloride, methacrylic acid, acrylamide and N-methylolmethacrylamide; and with other catalysts, e.g. hydrogen peroxide, ammonium persulphate, benzoyl peroxide and dialkyl percarbonates.

    10.
    发明专利
    未知

    公开(公告)号：DE1133695B

    公开(公告)日：1962-07-26

    申请号：DEB0045256

    申请日：1957-07-10

    Applicant: BASF AG

    Inventor： HARTMARK DIPL-ING BJARNE ,  SCHUSTER DR CURT ,  HERRLE DR KARL

    IPC: C07D207/26 ,  C07D207/27 ,  D06P1/22 ,  D06P1/642

    Abstract: Compounds used as levelling agents in dyeing (see Group IV (c)) and having a plurality of the same or different lactam groups, viz. butyro-, valero- or capro-lactam groups, and wherein each pair of lactam groups is connected through their nitrogen atoms by a carbon chain interrupted by one or more hetero atoms, viz. nitrogen, oxygen or sulphur atoms, the number of carbon atoms in the chain between a lactam nitrogen atom and the adjacent hetero atom being 2-6, are obtained by reacting dichlordiethyl ether or sym-dichlordiethylthioether or tri-(chlorethyl)-amine with the appropriate lactams, or by reacting polyalkylene polyamines with the appropriate lactones or by reacting sodium sulphide with a lactam substituted on the nitrogen atom by a b -chlorethyl group or by reacting di-(7-aminopropyl)-ether with the appropriate lactone. Compounds containing more than two lactam groups may also be obtained by cyanoethylating all the nitrogen atoms of a polyalkylene polyamine, then hydrogenating the product to form the corresponding polyamine and finally reacting with the lactones. The carbon atoms of the lactam group may be substituted by alkyl groups and in the case of a nitrogen hetero atom in the chain, its third linkage may bear an aliphatic chain of 1-5 carbon atoms which may be further substituted by hydroxyl, ether, nitrile, amino or lactam radicals.ALSO:In the dyeing of textile materials with vat or sulphur dyestuffs level dyeings are obtained by using, as a levelling agent, a compound having a plurality of the same or different lactam groups, viz:-butyro-, valero- or caprolactam groups, each pair of lactam groups being connected through their nitrogen atoms by a carbon chain interrupted by one or more hetero atoms, viz:-nitrogen, oxygen or sulphur atoms, and the number of carbon atoms in the chain between a lactam nitrogen atom and the adjacent hetero atom being 2-6. The carbon atoms of the lactam group may be substituted by alkyl groups and in the case of a nitrogen hetero atom in the chain its third linkage may bear an aliphatic chain of 1-5 carbon atoms which may be further substituted by hydroxyl, ether, nitrile, amino or lactam radicals. Numerous levelling agents are specified and numerous examples of dyeing are given.

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