Process for preparing hexagonal Me2Y ferrites

    公开(公告)号:DE3132681A1

    公开(公告)日:1983-03-17

    申请号:DE3132681

    申请日:1981-08-19

    Applicant: BASF AG

    Abstract: The invention relates to a process for preparing finely particulate hexagonal Me2Y ferrites of the general formula M2Me2Fe12O22, in which M is barium, strontium, calcium and/or lead, and Me is divalent manganese, copper, iron, cobalt, nickel, zinc, magnesium and/or equimolar amounts of lithium and trivalent iron, by mixing an M chloride or carbonate, an Me chloride or carbonate and iron(III) chloride together with sodium carbonate and/or potassium carbonate, heating the mixture obtained to a temperature of from 800 to 1050 DEG C, and then isolating the platelet-shaped (bladed) hexagonal Me2Y ferrite formed in the process by leaching with water from the sodium chloride and/or potassium chloride melt formed.

    Process for preparing isotropic ferrite powders having a spinel structure

    公开(公告)号:DE3132684A1

    公开(公告)日:1983-03-17

    申请号:DE3132684

    申请日:1981-08-19

    Applicant: BASF AG

    Abstract: The invention relates to a process for preparing isotropic ferrite powders having a spinel structure of the general formula MeFe2O4, in which Me = aMn + bNi + cZn + dCo + eFe(II), the atomic mass ratios a, b, c, d and e each being from 0 to 1 and their sum being equal to 1, by reacting an aqueous solution or suspension of one or more of the Me salts and an aqueous iron(III) chloride solution with an aqueous solution of sodium carbonate and/or potassium carbonate, drying the resulting mixture which consists of sparingly soluble MeCO3 and iron(III) carbonate in an alkali metal chloride solution, and then heating the salt mixture to a temperature above the melting point of the alkali metal chloride but not above 1200 DEG C, and isolating the octahedral ferrite of the composition MeFe2O4, which forms in the process, by leaching with water.

    5.
    发明专利
    未知

    公开(公告)号:DE3213683A1

    公开(公告)日:1983-10-27

    申请号:DE3213683

    申请日:1982-04-14

    Applicant: BASF AG

    Abstract: M-Type ferrites of the formula AFe12O19, Me2Y-type ferrites of the formula A2Me2Fe12O22 or spinel-type ferrites of the formula MeFe2O4, where A is Ba, Sr, Pb and/or Ca and Me is Zn, Mn, Co, Cu, Fe(II) and/or 1/2(Li(I)+Fe(III)), are prepared by a process wherein iron(II) sulfate hydrate is dehydrated and oxidized and then mixed with sodium carbonate and/or potassium carbonate and salts and/or oxides of other A and/or Me cations required in addition to Fe(III) for ferrite formation, the mixture is heated at from 700 DEG to 1,200 DEG C., and the resulting ferrite is isolated by leaching with water.

    Process for preparing hexagonal Me2Y ferrites

    公开(公告)号:DE3132680A1

    公开(公告)日:1983-03-17

    申请号:DE3132680

    申请日:1981-08-19

    Applicant: BASF AG

    Abstract: The invention relates to a process for preparing finely particulate hexagonal Me2Y ferrites of the general formula M2Me2Fe12O22, in which M is barium, strontium, calcium and/or lead, and Me is divalent manganese, copper, iron, cobalt, nickel, zinc, magnesium and/or equimolar amounts of lithium and trivalent iron, by reacting an aqueous solution or suspension of an M salt, an aqueous solution or suspension of an Me salt and an aqueous solution of an iron(III) salt with an aqueous sodium carbonate solution, drying the resulting mixed precipitate, heating the dry salt mixture to a temperature of from 800 DEG C to 1050 DEG C, and then isolating the platelet-shaped (bladed) Me2Y ferrite formed in the process from the Me2Y ferrite/sodium salt mixture by leaching with water.

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