公开(公告)号：DE2334378A1

公开(公告)日：1975-01-16

申请号：DE2334378

申请日：1973-07-06

Applicant: BASF AG

Inventor： HOFFMANN WERNER DIPL-CHEM DR ,  PAUST JOACHIM DIPL-CHEM DR ,  VON DIPL-CHEM DR FRAUNBERG KAR

IPC: C07D319/06 ,  C11B9/00

公开(公告)号：DE2334928A1

公开(公告)日：1975-01-30

申请号：DE2334928

申请日：1973-07-10

Applicant: BASF AG

Inventor： HOFFMANN WERNER DIPL-CHEM DR

IPC: C07C35/08

公开(公告)号：DE2340812A1

公开(公告)日：1975-02-27

申请号：DE2340812

申请日：1973-08-11

Applicant: BASF AG

Inventor： AQUILA WERNER DIPL-CHEM DR ,  HOFFMANN WERNER DIPL-CHEM DR ,  HIMMELE WALTER DIPL-CHEM DR ,  SIEGEL HARDO DIPL-CHEM DR

IPC: B01J31/20 ,  B01J31/24 ,  C07C45/49 ,  C07C45/50 ,  C07C47/228 ,  C07C47/235 ,  C07C47/24 ,  C07C47/277 ,  C11B9/00 ,  C07C45/10 ,  C07C47/48

公开(公告)号：DE2336980A1

公开(公告)日：1975-02-27

申请号：DE2336980

申请日：1973-07-20

Applicant: BASF AG

Inventor： HOFFMANN WERNER DIPL-CHEM DR ,  SIEGEL HARDO DIPL-CHEM DR ,  WETZEL BERND DIPL-CHEM DR

IPC: C07D309/12 ,  C07C43/14 ,  C07C69/02

Abstract: Alkoxy- and carbalkoxy-alkenes, having pleasant characteristic odours, of formula CH2=CR1-CH2-(CH2CH2-CR3=CH)-n ch2-chr4-cr5r6-or7 (i) (where n is 0 or 1; R1 and R5 are Me; R2, R3 and R4 are H or Me; R6 is 1-4C alkyl; R7 is 1-6C alkyl or cycloalkyl opt. contg. O as an ether- or keto gp. at C atom adjacent to ether-O) are used in perfumery and cosmetics and for improving odour of industrial prods., e.g. washing powders, glues, plastic dispersions. They are starting matls. for aldehydes used in perfumery. 6-Methoxy-2, 6-dimethyl-1-heptene is used as a starting matl. in the synthetic prepn. of hormone-active insecticide "Endocon" (RTM) by hydroformylation, condensn. of 7-methoxy-3, 7-dimethyl-octan-1-al with acetone and reaction of 10-methoxy-6, 10-dimethyl-oct-3-en-2-one with carbaion of isopropoxy-carbonylmethyl-dialkyl phosphonates. (I) are prepd. by reacting an alkenone with an organo-metallic cpd. and converting the inter. obtd. directly to (I) or opt. hydrolysing the inter. to the alcohol. The alcohol is then alkylated or reacted with an enol ether or acid chloride.

公开(公告)号：DE2314697A1

公开(公告)日：1974-10-03

申请号：DE2314697

申请日：1973-03-24

Applicant: BASF AG

Inventor： HOFFMANN WERNER DIPL-CHEM DR

IPC: C07C215/08 ,  C07C91/04

Abstract: Cpds. of formula R1-CH2-C(OH)Me-CH2-CH2-CHR2-CHMe-CH2CH2-NH2 (I) (where R1 and R2 are H or Me), pref. cpds. (i) where R1 = R2 = H, (ii) R1 = Me and R2 = H and (iii) R1 = H and R2 = Me, are useful for prepdn. of fragrant Schiff's bases for use in prefumery. (I) are prepd. by catalytically hydrogenating a mixt. of a hydroxyaldehyde R1-CH2-C(OH)Me-CH2CH2-CHR2-CHMe-CH2-CHO (II) and NH3 at raised temp. and press., e.g. 40-200 (50-120) degrees C under 10-150 (50-120) atmos. for 0.5-40 hrs., opt. in a solvent.