Carrying out photochemical reactions

    公开(公告)号:GB1136116A

    公开(公告)日:1968-12-11

    申请号:GB1549866

    申请日:1966-04-07

    Applicant: BASF AG

    Abstract: 1,136,116. Photochemical reactors. BADISCHE ANILIN-& SODA-FABRIK A.G. 7 April, 1966 [9 April, 1965], No. 15498/66. Heading B1X. A photochemical liquid phase reactor, which is especially suitable for use in the production of oximes from cycloalkanes in the presence of a solvent, has a central stirrer around which is a plurality of lamps, the diameter of a lamp being D, the inter-lamp separation is 0.3-2D, the lamp-stirrer separation is 0.05-0.5D, and the separation between the lamps and the wall is at least 0.5D. The reactor may be cylindrical with the stirrer at the axis and the lamps disposed on a circle about the axis. The stirrer may be rectangular (7 in Fig. 1, not shown), or anchor shaped (Fig. 3, not shown), and generally operates at 40-200 rpm. The cell may be cooled by elements 8, coils 10, or a cooling jacket 9 (Fig. 4, not shown). In Figs. 5 and 6 (not shown) are shown arrangements having a plurality of cells in series. In the reactor of Fig. 5, liquid flows in the direction of the arrows through cells 11 having perforate partitions 14 and stirrers 12. In the arrangement of Fig. 6, liquid flows to reactors 15, 17, 19, 21, 23, and 25 through coolers 16, 18, 20, 22, 24, and 26.

    3.
    发明专利
    未知

    公开(公告)号:NL147043B

    公开(公告)日:1975-09-15

    申请号:NL6604549

    申请日:1966-04-05

    Applicant: BASF AG

    Abstract: 1,136,116. Photochemical reactors. BADISCHE ANILIN-& SODA-FABRIK A.G. 7 April, 1966 [9 April, 1965], No. 15498/66. Heading B1X. A photochemical liquid phase reactor, which is especially suitable for use in the production of oximes from cycloalkanes in the presence of a solvent, has a central stirrer around which is a plurality of lamps, the diameter of a lamp being D, the inter-lamp separation is 0.3-2D, the lamp-stirrer separation is 0.05-0.5D, and the separation between the lamps and the wall is at least 0.5D. The reactor may be cylindrical with the stirrer at the axis and the lamps disposed on a circle about the axis. The stirrer may be rectangular (7 in Fig. 1, not shown), or anchor shaped (Fig. 3, not shown), and generally operates at 40-200 rpm. The cell may be cooled by elements 8, coils 10, or a cooling jacket 9 (Fig. 4, not shown). In Figs. 5 and 6 (not shown) are shown arrangements having a plurality of cells in series. In the reactor of Fig. 5, liquid flows in the direction of the arrows through cells 11 having perforate partitions 14 and stirrers 12. In the arrangement of Fig. 6, liquid flows to reactors 15, 17, 19, 21, 23, and 25 through coolers 16, 18, 20, 22, 24, and 26.

    4.
    发明专利
    未知

    公开(公告)号:AT266792B

    公开(公告)日:1968-11-25

    申请号:AT334566

    申请日:1966-04-07

    Applicant: BASF AG

    Abstract: 1,136,116. Photochemical reactors. BADISCHE ANILIN-& SODA-FABRIK A.G. 7 April, 1966 [9 April, 1965], No. 15498/66. Heading B1X. A photochemical liquid phase reactor, which is especially suitable for use in the production of oximes from cycloalkanes in the presence of a solvent, has a central stirrer around which is a plurality of lamps, the diameter of a lamp being D, the inter-lamp separation is 0.3-2D, the lamp-stirrer separation is 0.05-0.5D, and the separation between the lamps and the wall is at least 0.5D. The reactor may be cylindrical with the stirrer at the axis and the lamps disposed on a circle about the axis. The stirrer may be rectangular (7 in Fig. 1, not shown), or anchor shaped (Fig. 3, not shown), and generally operates at 40-200 rpm. The cell may be cooled by elements 8, coils 10, or a cooling jacket 9 (Fig. 4, not shown). In Figs. 5 and 6 (not shown) are shown arrangements having a plurality of cells in series. In the reactor of Fig. 5, liquid flows in the direction of the arrows through cells 11 having perforate partitions 14 and stirrers 12. In the arrangement of Fig. 6, liquid flows to reactors 15, 17, 19, 21, 23, and 25 through coolers 16, 18, 20, 22, 24, and 26.

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