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公开(公告)号:DE4420783A1
公开(公告)日:1995-12-21
申请号:DE4420783
申请日:1994-06-15
Applicant: BASF AG
Inventor: SCHLUND RUEGER DR , LUX MARTIN DR , EDELMANN FRANK DR , KILIMANN ULRIKE
IPC: C08F4/74 , C08F4/76 , C08F4/78 , C08F10/00 , C08F110/02
Abstract: A catalyst system (I) for the polymerisation of olefinic hydrocarbons contains (A) a metal-amidinato complex of formula (A) and opt. (B) an acceptor cpd. for substit. X in (A) as activator; M = Sub-Gp. III, IV, V or VI metal or lanthanide metal; X = negative leaving atom or gp. (these can be identical or different if (n = m) is greater than 1); R -R = C-organic or Si-organic gps.; n = valency of M in complex (A); m = 1-5; n - m = O or more. Also claimed is a process for the prodn. of homo- or copolymers of ethylene and other olefins by insertion polymerisation using catalyst (I). Also claimed are polymers of ethylene and alkyl- and aryl-substd. olefins obtd. by this process.