PROCESS FOR THE PREPARATION OF HOMO- AND COPOLYMERS OF ALPHA-MONOOLEFINS

    公开(公告)号:DE2963015D1

    公开(公告)日:1982-07-22

    申请号:DE2963015

    申请日:1979-09-20

    Applicant: BASF AG

    Abstract: A process for the manufacture of homopolymers and copolymers of alpha -monoolefins by polymerizing the monomer or monomers at relatively low temperatures under relatively low pressures by means of a Ziegler-Natta catalyst comprising (I) a titanium chloride component and (II) an aluminumalkyl component, wherein the titanium chloride component (I) employed is obtained by exposing a conventional catalyst component consisting, or substantially consisting, of titanium trichloride or titanium tetrachloride, to a carbon dioxide atmosphere under specific conditions. Catalysts obtained from titanium chloride components (I) which have been treated in this way exhibit a relatively long induction period.

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