-
公开(公告)号:DE50301117D1
公开(公告)日:2005-10-13
申请号:DE50301117
申请日:2003-01-30
Applicant: BASF AG
Inventor: LAUBENDER DR , GERST DR , RECK DR
IPC: C08F265/02 , C08F267/02 , D04H1/587 , C08L51/00 , D04H1/64
Abstract: Preparing an aqueous polymer dispersion comprises supplying at least one portion of ethylenically unsaturated monomers, a portion of water, at least one portion of polymer synthesized from ethylenically unsaturated monocarboxylic and/or dicarboxylic acid, ethylenically unsaturated compound(s) and further monomers, and at least portions of auxiliaries to a polymerization vessel together, without an emulsion being formed through a feed line. Preparing an aqueous polymer dispersion including dispersed polymer particles of addition polymer A1 obtainable by semi-continuous free-radical emulsion polymerization of ethylenically unsaturated monomers in the presence of an addition polymer A2 comprises supplying portion(s) of the ethylenically unsaturated monomers, a portion of water, portion(s) of the polymer A2 and, if desired, at least portions of further auxiliaries to the polymerization vessel together, without an emulsion being formed through a feed line. The addition polymer A2 is synthesized from 50-99.5 wt.% ethylenically unsaturated monocarboxylic and/or dicarboxylic acid, 0.5-50 wt.% ethylenically unsaturated compound(s) and up to 20 wt.% further monomer(s). The ethylenically unsaturated compound is ester of ethylenically unsaturated monocarboxylic acid or monoester and diester of ethylenically unsaturated dicarboxylic acid with an amine containing hydroxyl group(s).