公开(公告)号：WO2008009675A2

公开(公告)日：2008-01-24

申请号：PCT/EP2007057367

申请日：2007-07-17

Applicant: BASF AG ,  UNIV DUESSELDORF H HEINE ,  ERNST HANSGEORG ,  KOCK SEBASTIAN ,  MARTIN HANS-DIETER ,  SCHERRERS ROGER

Inventor： ERNST HANSGEORG ,  KOCK SEBASTIAN ,  MARTIN HANS-DIETER ,  SCHERRERS ROGER

IPC: C09K15/08 ,  C07C39/21 ,  C07C403/24

CPC classification number: C09K15/08 ,  A61K8/347 ,  A61K8/355 ,  A61K2800/522 ,  A61Q1/02 ,  A61Q5/02 ,  A61Q5/06 ,  A61Q5/12 ,  A61Q17/04 ,  A61Q19/00 ,  A61Q19/002 ,  A61Q19/004 ,  A61Q19/04 ,  A61Q19/10 ,  C07C403/24

Abstract: The invention relates to antioxidants, mixtures, preparations, dyes, vesicles, carotinoid formulations, dermocosmetic products, pharmaceuticals, food and fodder, and other solids or liquids or the mixtures thereof, which contain 3,3'-dihydroxyisorenieratene, isorenieratene-3,3'-diquinone, 2,2',4,4'-tetra-tert-butylisorenieratene-3,3'-diquinone, 3,3'-dihydroxy-2,2',4,4'-tetra-tert-butylisorenieratene or related isorenieratene compounds, or have been produced using said compounds, or by means of a method which uses said compounds.

Abstract translation: 本发明涉及抗氧化剂，它们的混合物，制剂，着色剂，囊泡，类胡萝卜素制剂，皮肤美容化妆，医药，食品和饲料以及其它固体或液体或其混合物，3,3'- Dihydroxyisorenieratene，Isorenieratin -3,3'- 二醌，2,2”，4,4'-四 - 叔butylisorenieratin -3,3'-二醌，3,3'-二羟基-2,2' ，4,4'-四 - 叔butylisorenieratin或相关Isorenieratin 包括这样的化合物或用这些化合物或通过包括使用这些化合物的方法制备。

公开(公告)号：WO9217549A3

公开(公告)日：1992-11-26

申请号：PCT/EP9200693

申请日：1992-03-28

Applicant: BASF AG

Inventor： ALBERT BERNHARD ,  KESSEL KNUT ,  MARTIN HANS-DIETER ,  SILBER STEFAN

IPC: B41M5/26 ,  A61K41/00 ,  C07D209/12 ,  C07D209/92 ,  C07D213/50 ,  C07D215/06 ,  C07D219/02 ,  C07D263/56 ,  C07D277/64 ,  C07D277/84 ,  C07D309/34 ,  C07D339/06 ,  C07D401/08 ,  C07D409/08 ,  C07D413/08 ,  C07D417/08 ,  C08F2/50 ,  C08K5/3412 ,  C08K5/3417 ,  C09B23/00 ,  C09B23/01 ,  C09B23/10 ,  G03G5/06 ,  G03G5/09 ,  G11B7/244 ,  G11B7/247 ,  A61K49/00 ,  G11B7/24

CPC classification number: G11B7/247 ,  A61K41/0042 ,  A61K41/0057 ,  C09B23/0066 ,  C09B23/0091 ,  C09B23/10 ,  G03G5/0672 ,  G03G5/0674

Abstract: Methine dyes have the polyketone grouping (I), in which the variables have the following meaning: A represents (a) or (b); R1 represents a 5 or 6-membered cycloaliphatic residue with one or two heteroatoms from the group -NR4-, -O- and -S-, that can be annelated with an iso-or heteroaromatic group, whereas R4 represents C¿5?-C7 cycloalkyl or phenyl, that can carry as substituents halogen, C1-C4 alkyl or C1-C4 alkoxy; C1-C20 alkyl, the C chain of which can be interrupted by one to five ether function oxygen atoms and that can carry the following substituents: hydroxyl, phenyl, 1,3-dioxan-2-yl, 1,3 dioxolan-2-yl, -NHR?5¿, -NHCOR5, -CONHR5, -OCONHR?5, -N+(R5)¿3.An-, -SO3H or -SO3-Ka+, where R5 represents one of the unsubstituted or hydroxyl- or phenyl-substituted alkyl residues R4 or phenyl, whereas the residues R5 may be different or the same when they represent -N+(R5)3, and An- is an anion equivalent and Ka+ is cation equivalent; R2, R3 can be different or identical C¿1?-C10 alkyl groups or can form together a residue R?1¿; m, n identical or different integers from 0 to 3. These dyes are useful as medicaments, for generating singlet oxygen, as sensitizers in electrophotographic layers and for photopolymerizations, and as laser light-sensitive dyes in optical recording media; also disclosed are new triketomethine and tetraketomethine dyes.

公开(公告)号：DE102006034320A1

公开(公告)日：2008-01-24

申请号：DE102006034320

申请日：2006-07-21

Applicant: BASF AG ,  UNIV DUESSELDORF H HEINE

Inventor： ERNST HANSGEORG ,  KOCK SEBASTIAN ,  MARTIN HANS-DIETER ,  SCHERRERS ROGER

IPC: C09K15/14 ,  A61K8/33 ,  A61K31/07 ,  A61K31/122 ,  A61P9/00 ,  A61P25/28 ,  A61P27/02 ,  A61Q1/00 ,  A61Q17/00 ,  A61Q19/00 ,  C07C39/21

Abstract: Antioxidant comprises at least an isorenieratene compound (I). Antioxidant comprises at least an isorenieratene compound of formula (I). R1>H or easily splittable protecting group; and R2>-R4>1-3C-alkyl. Independent claims are included for: (1) mixture (M1) comprising at least (I) and 3,3'-dihydroxyisorenieratene-1-quinone (II) and/or 3,3'-dihydroxy-2,2',4,4'-tetra-tert-butylisorenieratene-1-quinone (III); (2) mixture (M2) comprising 3,3'-dihydroxy-2,2',4,4'-tetra-tert-butylisorenieratene (IV) and at least (I) or (M1); (3) preparation (V) comprising (I), (II), (III) and/or (IV); (4) dermocosmetic, pharmaceutical and nutrient or feedstuff comprising (V); (5) solid material and/or liquid comprising (V); (6) coloring agent (A) comprising (II) or (III) or (IV) or (M1) or (M2); (7) coloring agent (B) comprising (V) in the form of H- or J-aggregate; (8) dermocosmetic, pharmaceutical, and nutrient or feedstuff comprising (A) or (B); (9) solid or liquid material comprising (A) or (B); (10) vesicle comprising (V); (11) dermocosmetic, pharmaceutical and nutrient- or feed stuff comprising the vesicle; (12) solid or liquid material comprising the vesicle; (13) carotenoid-formulation comprising (V); (14) preparation (VI)comprising the carotenoid formulation or (V); (15) dermocosmetic, pharmaceutical and nutrient or feedstuff comprising the carotenoids formulation or (V); (16) gelatin capsule comprising the carotenoids-formulation or (V); and (17) preparation of antioxidant, (M1) or (M2), (V), (A), vesicle, carotenoid-formulation, dermocosmetic, pharmaceutical, nutrient- or feedstuff, gelatin capsule or solid or liquid material comprising mixing (V), antioxidant, (M1) or (M2), (VI), (A), vesicle or carotenoid formulation. [Image].

公开(公告)号：DE59200703D1

公开(公告)日：1994-12-01

申请号：DE59200703

申请日：1992-03-28

Applicant: BASF AG

Inventor： ALBERT BERNHARD ,  KESSEL KNUT ,  MARTIN HANS-DIETER ,  SILBER STEFAN

IPC: B41M5/26 ,  A61K41/00 ,  A61K49/00 ,  C07D209/12 ,  C07D209/92 ,  C07D213/50 ,  C07D215/06 ,  C07D219/02 ,  C07D263/56 ,  C07D277/64 ,  C07D277/84 ,  C07D309/34 ,  C07D339/06 ,  C07D401/08 ,  C07D409/08 ,  C07D413/08 ,  C07D417/08 ,  C08F2/50 ,  C08K5/3412 ,  C08K5/3417 ,  C09B23/00 ,  C09B23/01 ,  C09B23/10 ,  G03G5/06 ,  G03G5/09 ,  G11B7/24 ,  G11B7/244 ,  G11B7/247

Abstract: PCT No. PCT/EP92/00693 Sec. 371 Date Sep. 27, 1993 Sec. 102(e) Date Sep. 27, 1993 PCT Filed Mar. 28, 1992 PCT Pub. No. WO92/17549 PCT Pub. Date Oct. 15, 1992.Methine dyes with a polyketo group I I where A is R1 is a 5- or 6-membered cycloaliphatic radical which contains one or two hetero atoms from the group -NR4-, -O- and -S- and which may be fused to an isoaromatic or heteroaromatic group, R2 and R3 are identical or different C1-C10-alkyl groups or together one of the radicals R1, and m and n are identical or different integers from 0 to 3, are useful as drugs, for producing singlet oxygen, as sensitizers in electrophotographic layers and for photopolymerizations and as laser light sensitive dyes in optical recording media; also novel triketo- and tetraketomethine dyes.