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    3.
    发明专利
    未知

    公开(公告)号：DE50308661D1

    公开(公告)日：2008-01-03

    申请号：DE50308661

    申请日：2003-07-16

    Applicant: BASF AG

    Inventor： BONN JOHANN ,  LORENZ KLAUS ,  WEHRLE JOERG ,  MATZ MANFRED

    IPC: B01D19/04 ,  D21H21/12

    Abstract: A defoaming agent and/or deaerator for aqueous foamable media based on oil-in-water dispersions. The oil phase contains at least one compound from fatty alcohols, fatty acid monoglycerides, diglycerides, and triglycerides, fatty acid ester of fatty acids and monovalent to trivalent alcohols, 3-thiaalkane-1-ole, 3-thiaoxide alkane-1-ole, 3-thiadioxide-alkane-ole, and thiaalkane esters in combination with (i) at least one polyglycerine that is obtained by esterification of at least 20 percent of polyglycerine with 12 to 36 C carboxylic acid, and (ii) at least one bisamide consisting of ethylene diamine and 10 to 36 C atom carboxylic acids, while the aqueous phase thereof contains at least one stabilizer, water, and an optional thickener, for aqueous media that tend to foam. Also disclosed are methods of controlling foam by adding the dispersions to a process, particularly during cellulose boiling, cellulose washing, grinding of paper pulp, paper production, and dispersion of pigments used for paper production.

    5.
    发明专利
    未知

    公开(公告)号：DE50204270D1

    公开(公告)日：2005-10-20

    申请号：DE50204270

    申请日：2002-06-04

    Applicant: BASF AG

    Inventor： DYLLICK-BRENZINGER RAINER ,  KAMIETH MARKUS ,  BONN JOHANN ,  MATZ MANFRED ,  LORENZ KLAUS

    IPC: B01D19/04 ,  C09K23/00

    Abstract: An oil-in-water dispersion has an oil phase containing at least one amide compound having at least one reactive group comprising an alcoholic OH-group and amine NH- or NH2 groups, with at least one crosslinking compound having at least bifunctional reactivity and/or a reaction product of an amino group containing polymer with an aliphatic carboxylic acid R-COOH. An oil-in-water dispersion (I) has an oil phase comprising: (A) at least one water insoluble, room-temperature solid, oxygen containing organic substance comprising a long chain alcohol having at least one 12C atom hydrocarbon residue optionally containing S, SO or SO2, distillation residue arising from the production of aliphatic alcohols having at least 14C atoms, mono-, di or triglycerides of fatty acids, fatty acid esters of at least 12C aliphatic alcohols and/or fatty acid esters of 1-11C alcohols; (B) at least one amide compound of formula Z-X-B-N(R )-A-N(R )-C(=O)-R (1) and/or a product of the reaction of at least one amide compound of formula (1) having at least one reactive group (RG) comprising an alcoholic OH-group and amine NH- or NH2 groups, with at least one crosslinking compound having at least bifunctional reactivity with the groups (RG) and/or a reaction product of an amino group containing polymer with an aliphatic carboxylic acid R-COOH; and optionally (C) known defoaming agents; (D) at least one hydrocarbon having a b.pt. greater than 200 deg C (normal pressure). R = at least 14C aliphatic group optionally containing 1-2 hydroxyl groups, 1-2 double bonds and/or 1-2 triple bonds; A,B = 2-20C alkylene optionally containing 1-2 OH groups, 1-2 double and/or triple bonds and one or two non-neighboring oxygen atoms or 5-20C cycloalkylene optionally substituted by 1-2OH groups and/or 1-4 methyl groups and/or a carbonyl function as a ring member; R = H, 1-13C alkyl, 5-10C cycloalkyl, phenyl or (A -X )m-Z ; R = H, 1-13C alkyl, 5-10C cycloalkyl, phenyl, C(O)-R or (A -X )p-Z ; Z = H or (A -X )q-Z ; A -A = 2-3C alkylene; X -X = O or N-Ra; Ra = H, CH2CH2NH2, CH2CH2NHC(O)R, CH2CH2CH2NH2, CH2CH2CH2NHC(O)R or C(O)-R; Z -Z = H, CH2CH2NH2, CH2CH2NHC(O)R, CH2CH2CH2NH2, CH2CH2CH2NHC(O)R ; m,q = 1-20; n,p = 1-10; R with R or R with R and/or two of R ,R ,Ra are bonded by an alkylene unit bonded to nitrogen atoms, or are 1-4C alkylene optionally having a carbonyl function and/or is substituted by 1-3 methyl groups; B-X-Z=H when A is 6-20C alkylene containing one or two non-neighboring oxygen atoms or 5-20C cycloalkylene optionally substituted by 1 or 2 OH-groups and/or 1-4 methyl groups and/or a carbonyl function as a ring member.

    DEFOAMING AGENT AND/OR DEAERATOR FOR AQUEOUS MEDIA TENDING TO FOAM
    6.
    发明专利
    DEFOAMING AGENT AND/OR DEAERATOR FOR AQUEOUS MEDIA TENDING TO FOAM 未知

    公开(公告)号：AU2003250078A1

    公开(公告)日：2004-02-23

    申请号：AU2003250078

    申请日：2003-07-16

    Applicant: BASF AG

    Inventor： BONN JOHANN ,  LORENZ KLAUS ,  WEHRLE JORG ,  MATZ MANFRED

    IPC: B01D19/04 ,  D21H21/12

    Abstract: A defoaming agent and/or deaerator for aqueous foamable media based on oil-in-water dispersions. The oil phase contains at least one compound from fatty alcohols, fatty acid monoglycerides, diglycerides, and triglycerides, fatty acid ester of fatty acids and monovalent to trivalent alcohols, 3-thiaalkane-1-ole, 3-thiaoxide alkane-1-ole, 3-thiadioxide-alkane-ole, and thiaalkane esters in combination with (i) at least one polyglycerine that is obtained by esterification of at least 20 percent of polyglycerine with 12 to 36 C carboxylic acid, and (ii) at least one bisamide consisting of ethylene diamine and 10 to 36 C atom carboxylic acids, while the aqueous phase thereof contains at least one stabilizer, water, and an optional thickener, for aqueous media that tend to foam. Also disclosed are methods of controlling foam by adding the dispersions to a process, particularly during cellulose boiling, cellulose washing, grinding of paper pulp, paper production, and dispersion of pigments used for paper production.

    7.
    发明专利
    未知

    公开(公告)号：DE10233701A1

    公开(公告)日：2004-02-05

    申请号：DE10233701

    申请日：2002-07-24

    Applicant: BASF AG

    Inventor： BONN JOHANN ,  LORENZ KLAUS ,  WEHRLE JOERG ,  MATZ MANFRED

    IPC: B01D19/04 ,  D21H21/12

    Abstract: A defoaming agent and/or deaerator for aqueous foamable media based on oil-in-water dispersions. The oil phase contains at least one compound from fatty alcohols, fatty acid monoglycerides, diglycerides, and triglycerides, fatty acid ester of fatty acids and monovalent to trivalent alcohols, 3-thiaalkane-1-ole, 3-thiaoxide alkane-1-ole, 3-thiadioxide-alkane-ole, and thiaalkane esters in combination with (i) at least one polyglycerine that is obtained by esterification of at least 20 percent of polyglycerine with 12 to 36 C carboxylic acid, and (ii) at least one bisamide consisting of ethylene diamine and 10 to 36 C atom carboxylic acids, while the aqueous phase thereof contains at least one stabilizer, water, and an optional thickener, for aqueous media that tend to foam. Also disclosed are methods of controlling foam by adding the dispersions to a process, particularly during cellulose boiling, cellulose washing, grinding of paper pulp, paper production, and dispersion of pigments used for paper production.

    Oil-in-water dispersion, useful as a defoaming agent, has an oil phase containing an amide compound having at least one reactive group comprising an alcoholic OH-group and amine NH- or NH2 groups.
    8.
    发明专利
    Oil-in-water dispersion, useful as a defoaming agent, has an oil phase containing an amide compound having at least one reactive group comprising an alcoholic OH-group and amine NH- or NH2 groups. 未知

    公开(公告)号：DE10127245A1

    公开(公告)日：2002-12-12

    申请号：DE10127245

    申请日：2001-06-05

    Applicant: BASF AG

    Inventor： DYLLICK-BRENZINGER RAINER ,  KAMIETH MARKUS ,  BONN JOHANN ,  MATZ MANFRED ,  LORENZ KLAUS

    IPC: B01D19/04 ,  C09K23/00 ,  B01F17/00

    Abstract: An oil-in-water dispersion has an oil phase containing at least one amide compound having at least one reactive group comprising an alcoholic OH-group and amine NH- or NH2 groups, with at least one crosslinking compound having at least bifunctional reactivity and/or a reaction product of an amino group containing polymer with an aliphatic carboxylic acid R-COOH. An oil-in-water dispersion (I) has an oil phase comprising: (A) at least one water insoluble, room-temperature solid, oxygen containing organic substance comprising a long chain alcohol having at least one 12C atom hydrocarbon residue optionally containing S, SO or SO2, distillation residue arising from the production of aliphatic alcohols having at least 14C atoms, mono-, di or triglycerides of fatty acids, fatty acid esters of at least 12C aliphatic alcohols and/or fatty acid esters of 1-11C alcohols; (B) at least one amide compound of formula Z-X-B-N(R )-A-N(R )-C(=O)-R (1) and/or a product of the reaction of at least one amide compound of formula (1) having at least one reactive group (RG) comprising an alcoholic OH-group and amine NH- or NH2 groups, with at least one crosslinking compound having at least bifunctional reactivity with the groups (RG) and/or a reaction product of an amino group containing polymer with an aliphatic carboxylic acid R-COOH; and optionally (C) known defoaming agents; (D) at least one hydrocarbon having a b.pt. greater than 200 deg C (normal pressure). R = at least 14C aliphatic group optionally containing 1-2 hydroxyl groups, 1-2 double bonds and/or 1-2 triple bonds; A,B = 2-20C alkylene optionally containing 1-2 OH groups, 1-2 double and/or triple bonds and one or two non-neighboring oxygen atoms or 5-20C cycloalkylene optionally substituted by 1-2OH groups and/or 1-4 methyl groups and/or a carbonyl function as a ring member; R = H, 1-13C alkyl, 5-10C cycloalkyl, phenyl or (A -X )m-Z ; R = H, 1-13C alkyl, 5-10C cycloalkyl, phenyl, C(O)-R or (A -X )p-Z ; Z = H or (A -X )q-Z ; A -A = 2-3C alkylene; X -X = O or N-Ra; Ra = H, CH2CH2NH2, CH2CH2NHC(O)R, CH2CH2CH2NH2, CH2CH2CH2NHC(O)R or C(O)-R; Z -Z = H, CH2CH2NH2, CH2CH2NHC(O)R, CH2CH2CH2NH2, CH2CH2CH2NHC(O)R ; m,q = 1-20; n,p = 1-10; R with R or R with R and/or two of R ,R ,Ra are bonded by an alkylene unit bonded to nitrogen atoms, or are 1-4C alkylene optionally having a carbonyl function and/or is substituted by 1-3 methyl groups; B-X-Z=H when A is 6-20C alkylene containing one or two non-neighboring oxygen atoms or 5-20C cycloalkylene optionally substituted by 1 or 2 OH-groups and/or 1-4 methyl groups and/or a carbonyl function as a ring member.

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