公开(公告)号：DE1199738B

公开(公告)日：1965-09-02

申请号：DEB0074729

申请日：1963-12-19

Applicant: BASF AG

Inventor： MUELLER DR KARL-HEINZ ,  MINSINGER DR MANFRED ,  KLINGENSPOR DR HELMUT

IPC: B01J8/44

公开(公告)号：DE1141488B

公开(公告)日：1962-12-20

申请号：DEB0058831

申请日：1960-08-03

Applicant: BASF AG

Inventor： MINSINGER DR MANFRED ,  ADOLPHI DR HEINRICH ,  STUMMEYER DR HERBERT

公开(公告)号：DE1081875B

公开(公告)日：1960-05-19

申请号：DEB0037738

申请日：1955-11-02

Applicant: BASF AG

Inventor： MINSINGER DR MANFRED ,  FRIEDERICH DR HERBERT

IPC: C07C69/63

公开(公告)号：DE1064502B

公开(公告)日：1959-09-03

申请号：DEB0040592

申请日：1956-06-09

Applicant: BASF AG

Inventor： MINSINGER DR MANFRED ,  FRIEDERICH DR HERBERT

IPC: C07C69/653

公开(公告)号：DE1085511B

公开(公告)日：1960-07-21

申请号：DEB0051854

申请日：1959-01-24

Applicant: BASF AG

Inventor： MINSINGER DR MANFRED ,  FRIEDERICH DR HERBERT

IPC: C07C17/00

公开(公告)号：DE1082053B

公开(公告)日：1960-05-19

申请号：DEB0052237

申请日：1959-02-25

Applicant: BASF AG

Inventor： WILLERSINN DR HERBERT ,  MINSINGER DR MANFRED ,  FRIEDERICH DR HERBERT

IPC: C08F18/20 ,  C08F283/01

公开(公告)号：DE1079037B

公开(公告)日：1960-04-07

申请号：DEB0050465

申请日：1958-09-24

Applicant: BASF AG

Inventor： MINSINGER DR MANFRED ,  FRIEDERICH DR HERBERT

公开(公告)号：DE1076673B

公开(公告)日：1960-03-03

申请号：DEB0042675

申请日：1956-12-01

Applicant: BASF AG

Inventor： MINSINGER DR MANFRED ,  FRIEDERICH DR HERBERT

IPC: C07C69/653

公开(公告)号：DE1061769B

公开(公告)日：1959-07-23

申请号：DEB0036823

申请日：1955-08-11

Applicant: BASF AG

Inventor： FRIEDERICH DR HERBERT ,  MINSINGER DR MANFRED

IPC: C07C69/63

Abstract: a :b -Dichloropropionic acid esters (e.g. of saturated aliphatic, cycloaliphatic or araliphatic alcohols) are produced by treating acrylic acid esters with chlorine in the gas phase in the presence of a minor amount (preferably 0.1 to 5 per cent by weight of the amount of acrylic acid ester) of an N-substituted carboxylic acid amide or a primary, secondary or tertiary amine of the aliphatic, cycloaliphatic, araliphatic or aromatic series, or a mixture of these compounds. The amide or amine preferably has a boiling-point close to that of the acrylic acid ester, whereby the two compounds can be vaporized together, and there is preferably also present a polymerization retarder. A suitable amount of chlorine is 0.9-1.5 mols. per mol. of ester, and the preferred reaction temperatures lie in the range 80-200 DEG C. Examples describe the preparation of the methyl ester in the presence of hydroquinone and (1) methylpyrrolidone; (2) N:N-diethylformamide; (3) N:N-dimethylformamide; (4) dimethylamine; (5) diethylamine; (6) n-butylamine; (7) triethylamine; (8) monomethylformamide; (9) N:N-dibutylformamide; and (10) 2-ethylhexylamine-(1). Additional amides and amines are listed.

公开(公告)号：DE1131663B

公开(公告)日：1962-06-20

申请号：DEB0060759

申请日：1961-01-07

Applicant: BASF AG

Inventor： MINSINGER DR MANFRED

IPC: C07C17/23