9-CYANO-SUBSTITUTED PERYLENE-3,4-DICARBOXYLIC ACID MONOIMIDES AS DYESTUFFS
    2.
    发明申请
    9-CYANO-SUBSTITUTED PERYLENE-3,4-DICARBOXYLIC ACID MONOIMIDES AS DYESTUFFS 审中-公开
    9-氰基取代的苝-3,4-二酰亚胺染料

    公开(公告)号:WO2004029028A3

    公开(公告)日:2005-04-21

    申请号:PCT/EP0309946

    申请日:2003-09-08

    Abstract: The invention relates to 9-cyano-substituted perylene-3,4-dicarboxylic acid monoimides (I) where the variables have the following meanings: X = a chemical bond, optionally substituted C1-C30 alkylenes, C5-C8 cycloalkylenes, arylenes, heteroarylenes, C1-C20 alkylarylenes, C1-C20 alkylheteroarylenes, aryl- or heteroaryl-C1-C20 alkylenes, Y = a functional group Y', or a polymerisable group P, or X-Y together = a group R, Y' = amino, hydroxy, -COOH, -SO3H, chlorine or bromine, P = a group (II), A, B independently = H, C1-C6 alkyl, phenyl, or together form a cyclopentene or cyclohexene ring, which comprise the double bond to which A and B are bonded, Q = a chemical bond, a -O-, -NR -, -S-, -OCO-, -OCOO-, -OCONR -, -NR CO-, -NR COO-, -NR CONR -, -CO-, -COO-, -CONR -, -SO2-O-, -SO2NR -, -O-SO2- or -NR SO2- group, n = 0, 1, 2 or 3 and R = H, optionally-substituted C1-C30 alkyl, C5-C8 cycloalkyl, aryl or heteroaryl.

    Abstract translation: 9-氰基取代的苝-3,4-二酰亚胺(I)与所述变量的含义如下:X为化学键; 任选取代的C1-C30亚烷基,C5-C8亚环烷基,亚芳基,hetarylene,C1-C20-烷基亚芳,C1-C20-Alkylhetarylen,芳基或杂芳基C1-C20亚烷基; Y是官能团Y“或可聚合 基团P; 或X-Y一起形成基团R; Y“是氨基,羟基,-COOH,-SO 3 H,氯或溴; P表示(II)中,A,B独立地是氢,C1-C6烷基,苯基或一起形成环戊烯 或含有双键环己烯环结合到A和B; Q为化学键; 一个-O - , - NR <2> - , - S - , - OCO - , - OCOO - , - OCONR <3> - , - NR <3> CO-,-NR <3> COO - , - NR <3> CONR <4> - , - CO - , - COO - , - CONR <3> - ,-SO 2 - O-,-SO 2 <3> - , - O-SO 2或NR <3> SO2 ; n为0,1,2或3; R是氢; 任选取代的C1-C30烷基,C5-C8环烷基,芳基或杂芳基。

    8.
    发明专利
    未知

    公开(公告)号:DE102005018241A1

    公开(公告)日:2006-10-26

    申请号:DE102005018241

    申请日:2005-04-19

    Applicant: BASF AG

    Abstract: Rylenetetracarboximides of the general formula I in which the variables are defined as follows: R are identical or different radicals: hydrogen; alkyl, cycloalkyl, aryl or hetaryl, each substituted if desired; R′ are identical or different radicals: hydrogen; aryloxy, arylthio, hetaryloxy or hetarylthio, each substituted if desired; n is 1 or 2, and also a process for preparing the rylenetetracarboximides I and their use for coloring high molecular weight organic and inorganic materials, for preparing aqueous polymer dispersions which absorb in the near infrared region of the electromagnetic spectrum, for producing markings and inscriptions which absorb infrared light and are invisible to the human eye, as infrared absorbers for heat management, as IR laser beam-absorbing materials in fusion treatment of plastics parts, and also as active components in photovoltaics.

    Production of polymethylenamine, e.g. cationic fixative, dehydrating agent, flocculant or retention aid for paper industry, involves free radical polymerization of imidazol(in)e or 1,3,2-diazasilacyclo-pent(adi)ene and optional hydrolysis

    公开(公告)号:DE10305807A1

    公开(公告)日:2004-08-26

    申请号:DE10305807

    申请日:2003-02-12

    Abstract: Production of polymethylenamine (I) uses an educt comprising an optionally substituted imidazol(in)e or 1,3,2-diazasilacyclo-pentene or -pentadiene compound (II); and involves free radical polymerization of (II), using a free radical initiator with a half life of 5-30 minutes at the selected reaction temperature and hydrolysis of the resultant polymer if necessary. Production of polymethylenamine (I) uses an educt comprising an optionally substituted imidazol(in)e or 1,3,2-diazasilacyclo-pentene or -pentadiene compound of formula (II); and involves free radical polymerization of (II), using a free radical initiator with a half life of 5-30 minutes at the selected reaction temperature and hydrolysis of the resultant polymer if necessary: [Image] Q : C or Si, with the broken line indicating an optional double bond; R1>, R2>H, R, formyl; (un)saturated, linear or branched, optionally aryl-substituted aliphatic 1-40 C acyl, R', R5>OCO(O), -C(O)NR6>R7> or -C(O)XR8>; R : (un)saturated, linear or branched, optionally aryl-substituted 1-40 C alkyl or optionally alkyl-substituted 5-6 C aryl; R' : optionally alkyl-substituted aromatic 5-6 C acyl; R5>R; R6>, R7>H, R or R'; X : O or S; R8>H or R; R3>, R4>H, R, OR or OH or together =O or =S. An independent claim is also included for process for hydrolysis of poly(1,3-diacyl-4-imidazolidin-2-(thi)one using strong alkali(ne earth) metal base in combination of compounds or ions that break hydrogen bridges, preferably lithium (Li+>), magnesium (Mg2>+>), urea, substituted urea or urea derivatives.

    10.
    发明专利
    未知

    公开(公告)号:DE19940708A1

    公开(公告)日:2001-03-01

    申请号:DE19940708

    申请日:1999-08-27

    Applicant: BASF AG

    Abstract: The invention relates to rylene dyes of the general formula (I), wherein the variables have the following meanings: R represents hydrogen; optionally substituted C1-C30 alkyl-C5-C8-cycloalkyl, aryl or hetaryl; R'represents optionally substituted C2-C30 alkyl or C5-C8 cycloalkyl, substituted methyl; and n is 0 or 1. The invention also relates to the preparation and use of said dyes for coloring highly molecular organic and inorganic materials and to 9-amino-perylene-3,4-dicarboxylic acid imides (Va) as their intermediate products.

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