公开(公告)号：CA2576300A1

公开(公告)日：2006-03-23

申请号：CA2576300

申请日：2005-09-13

Applicant: BASF AG

Inventor： NEUNER BERNHARD ,  BECKER HEIKE

IPC: C11D3/37 ,  C11D1/72 ,  C11D3/33

Abstract: A phosphate-free detergent formulation for machine dishwashing comprising, as components: a) from 1 to 20% by weight of copolymers of a1) from 20 to 80% by weight, preferably from 30 to 70% by weight, of at least one monomer from the group consisting of monoethylenically unsaturated C3-C10-mono- or -dicarboxylic acids or anhydrides thereof, a2) from 0 to 80% by weight, preferably from 10 to 50% by weight, of at least one monomer of the general formula (I), where R1, R2 and R3 are each independently H, CH3 or C2H5, R4 is a linear, branched or cyclic radical having from 1 to 6 carbon atoms or an aromatic radical having from 6 to 12 carbon atoms, and a3) from 0 to 80% by weight, preferably from 5 to 20% by weight, of at least one further monomer selected from the group consisting of olefins having 10 or more carbon atoms or mixtures thereof and reactive polyisobutenes having on average from 12 to 100 carbon atoms, b) from 1 to 50% by weight of complexing agents, selected from the group consisting of nitrilotriacetic acid, hydroxyethylethylenediaminetriacetic acid, ethylenediaminetetraacetic acid, diethylenetriaminepentaacetic acid, methylglycinediacetic acid, glutaminicaciddiacetic acid, iminodisuccinic acid, hydroxyiminodisuccinic acid, ethylendiaminodisuccinic acid, asparaginicaciddiacetic acid and salts therof, c) from 1 to 15% by weight of low-foaming nonionic surfactants, d) from 0.1 to 30% by weight of bleaches and, if appropriate, bleach activators, e) from 0 to 60% by weight of further builders, f) from 0 to 8% by weight of enzymes, g) from 0 to 50% by weight of one or more further additives such as anionic or zwitterionic surfactants, bleach catalysts, alkali carriers, corrosion inhibitors, defoamers, dyes, fragrances, fillers, organic solvents and water, the sum of components a) to g) adding up to 100% by weight.

公开(公告)号：CA2576300C

公开(公告)日：2013-12-24

申请号：CA2576300

申请日：2005-09-13

Applicant: BASF AG

Inventor： BECKER HEIKE ,  NEUNER BERNHARD

IPC: C11D3/37 ,  C11D1/72 ,  C11D3/33

Abstract: The invention relates to a phosphate-free cleaning formulations for a dish cleaning machine containing the following components: (a) 1-20 % by weight hydrophobically modified polycarboxylate, (b) 1-50 % by weight complexing agent selected from a nitrile-triacetic acid, triacetic acid hydroxyethylethylendiamine, tetracetic acid ethylenediamine, pentacetic acid diethylenetriamine, diacetic acid methylglycyne, glutaminic acid diacetic acid, iminodisuccinic acid, iminodisuccinic acid hydroxymine, disuccinic acid ethylenediamine, asparaginic acid diacetic acid and salts thereof group, (c) 1-15 % by weight non-ionic low-foaming detergents, (d) 0.1-30 % by weight bleaching and optionally a bleaching activator, (e) 0-60 % by weight additional detergents, (f) 0-8 % by weight enzymes, (g) 0-50 % by weight one or several types of additives, wherein from (a) to (g) is equal to 100 % by weight.

公开(公告)号：DE102004044411A1

公开(公告)日：2006-03-30

申请号：DE102004044411

申请日：2004-09-14

Applicant: BASF AG

Inventor： BECKER HEIKE ,  NEUNER BERNHARD

IPC: C11D3/37

Abstract: A phosphate-free detergent formulation for machine dishwashing comprising, as components: a) from 1 to 20% by weight of copolymers of a1) from 20 to 80% by weight, preferably from 30 to 70% by weight, of at least one monomer from the group consisting of monoethylenically unsaturated C3-C10-mono- or -dicarboxylic acids or anhydrides thereof, a2) from 0 to 80% by weight, preferably from 10 to 50% by weight, of at least one monomer of the general formula (I), where R1, R2 and R3 are each independently H, CH3 or C2H5, R4 is a linear, branched or cyclic radical having from 1 to 6 carbon atoms or an aromatic radical having from 6 to 12 carbon atoms, and a3) from 0 to 80% by weight, preferably from 5 to 20% by weight, of at least one further monomer selected from the group consisting of olefins having 10 or more carbon atoms or mixtures thereof and reactive polyisobutenes having on average from 12 to 100 carbon atoms, b) from 1 to 50% by weight of complexing agents, selected from the group consisting of nitrilotriacetic acid, hydroxyethylethylenediaminetriacetic acid, ethylenediaminetetraacetic acid, diethylenetriaminepentaacetic acid, methylglycinediacetic acid, glutaminicaciddiacetic acid, iminodisuccinic acid, hydroxyiminodisuccinic acid, ethylendiaminodisuccinic acid, asparaginicaciddiacetic acid and salts therof, c) from 1 to 15% by weight of low-foaming nonionic surfactants, d) from 0.1 to 30% by weight of bleaches and, if appropriate, bleach activators, e) from 0 to 60% by weight of further builders, f) from 0 to 8% by weight of enzymes, g) from 0 to 50% by weight of one or more further additives such as anionic or zwitterionic surfactants, bleach catalysts, alkali carriers, corrosion inhibitors, defoamers, dyes, fragrances, fillers, organic solvents and water, the sum of components a) to g) adding up to 100% by weight.