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公开(公告)号：JPH0841352A
公开(公告)日：1996-02-13
申请号：JP4456295
申请日：1995-03-03
Applicant: BASF AG
Inventor： MCKEE GRAHAM EDMUND , NIESSNER NORBERT , FISCH HERBERT
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2.发明申请THERMOPLASTIC MOLDING MATERIAL WITH REDUCED GLOSS SENSITIVITY AND IMPROVED ODOR CHARACTERISTICS AND PROCESS FOR THE PRODUCTION THEREOF 审中-公开热塑性成型材料具有降低的灵敏度和改善的气味特性及其生产工艺
公开(公告)号：WO2007017466A2
公开(公告)日：2007-02-15
申请号：PCT/EP2006065043
申请日：2006-08-03
Applicant: BASF AG , DUIJZINGS WIL , SUWIER DAVY ROGER , CZAUDERNA BERNHARD , NIESSNER NORBERT , SAUER MICHAEL , PEPERS MICHEL
Inventor： DUIJZINGS WIL , SUWIER DAVY ROGER , CZAUDERNA BERNHARD , NIESSNER NORBERT , SAUER MICHAEL , PEPERS MICHEL
IPC: C08F279/04 , C08F279/02 , C08L25/08 , C08L25/12 , C08L51/04 , C08L55/02
CPC classification number: C08L51/04 , C08F279/02 , C08F279/04 , C08L55/02 , C08L2666/02
Abstract: A thermoplastic molding composition having reduced gloss sensitivity and no unpleasant odor is produced from a graft copolymer and a thermoplastic polymer. The graft copolymer is produced from a soft elastomeric particulate graft base obtained by emulsion polymerization of a conjugated diene alone or with a small amount of a mono- ethylenically unsaturated monomer, using an inorganic radical generating substance and a limited amount of chain transfer agent, upon which is grafted a vinyl aromatic monomer and acrylonitrile and optionally another monoethylenically unsaturated monomer using an inorganic radical generating substance while the use of a chain transfer agent is excluded. The thermoplastic polymer is a copolymer of a vinyl aromatic monomer and acrylonitrile and optionally an additional monoethylenically unsaturated monomer. The thermoplastic molding composition has a low level of unpleasant odor coupled with reduced gloss sensitivity and good mechanical properties.
Abstract translation: 由接枝共聚物和热塑性聚合物制备具有降低的光泽灵敏度和无异味的热塑性模塑组合物。 接枝共聚物由柔软的弹性体颗粒接枝基质制备，所述柔性弹性体颗粒接枝基质通过使用无机自由基产生物质和有限量的链转移剂将共轭二烯单独或与少量的单烯属不饱和单体乳液聚合而获得， 其使用无机自由基产生物质接枝乙烯基芳族单体和丙烯腈以及任选地另外的单烯属不饱和单体，同时不使用链转移剂。 热塑性聚合物是乙烯基芳族单体和丙烯腈和任选的另外的单烯属不饱和单体的共聚物。 热塑性模塑组合物具有低水平的令人不愉快的气味，同时具有降低的光泽敏感性和良好的机械性能。
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公开(公告)号：WO2006114429A2
公开(公告)日：2006-11-02
申请号：PCT/EP2006061844
申请日：2006-04-26
Applicant: BASF AG , SCHNEIDER NORBERT , LIPPERT GERALD , LOCHTMAN RENE , MAAS HEIKO , PFISTER JUERGEN , SOBOTKA BETTINA , WAGNER NORBERT , NIESSNER NORBERT , SCHEIBITZ MATTHIAS , DAHLKE MICHAEL , WARZELHAN VOLKER
Inventor： SCHNEIDER NORBERT , LIPPERT GERALD , LOCHTMAN RENE , MAAS HEIKO , PFISTER JUERGEN , SOBOTKA BETTINA , WAGNER NORBERT , NIESSNER NORBERT , SCHEIBITZ MATTHIAS , DAHLKE MICHAEL , WARZELHAN VOLKER
CPC classification number: C08L51/003 , B29C47/0004 , B29C47/0011 , B29C47/0021 , B29C47/06 , B29C47/14 , B29C51/00 , B29K2105/0008 , B29K2105/0032 , B29K2105/0044 , B29K2105/005 , B29K2105/256 , B32B5/16 , B32B27/08 , B32B27/14 , B32B2255/10 , B32B2255/205 , B32B2260/025 , B32B2260/046 , B32B2264/105 , B32B2274/00 , B32B2307/202 , B32B2307/416 , B32B2307/546 , B32B2307/558 , B32B2307/7242 , B32B2419/00 , B32B2509/00 , B32B2605/00 , C08J5/18 , C08K3/08 , C08K2201/008 , C08L23/02 , C08L53/02 , C08L55/02 , C08L71/02 , C08L2205/16 , C23C18/54 , C25D5/56 , H01Q15/141 , H01Q17/008 , H05K9/0083 , Y10T156/10 , Y10T428/25 , Y10T428/256 , C08L2666/04 , C08L2666/02
Abstract: Films or plates made of a plastic mixture and capable of being metal-plated are disclosed, comprising, in relation to the total weight of components A, B, C and D, which add up to 100 % by weight: (a) 5-50 % by weight of a thermoplastic polymer as component A; (b) 50-95 % by weight of a metal powder having an average particle diameter ranging from 0.01-100 µm (determined by the method defined in the description), the metal having a more negative normal potential in an acid solution than silver, as component B; (c) 0-10 % by weight of a dispersant as component C; and (d) 0-40 % by weight fibrous or particulate fillers or their mixtures as component D. The elongation at tear of component A (determined by the method defined in the description) is 1.1-100 times higher than the elongation at tear of the plastic mixture comprising components A, B and optionally C and D (determined by the method defined in the description). The tensile strength of component A (determined by the method defined in the description) is 0.5-4 times higher than the tensile strength of the plastic mixture comprising components A, B and optionally C and D (determined by the method defined in the description). Also disclosed are thermoplastic moulding compounds for producing these films or plates that can be metal-plated, a granulate comprising these thermoplastic moulding compounds, stratified composite films or plates and mouldings comprising these films or plates, metal-plated polymer bodies comprising these films or plates, stratified composite films or plates and mouldings, processes for producing these objects, the use of these objects as EMI shieldings and absorbers, dampers or reflectors for electromagnetic radiation, oxygen scavengers, electroconducting components, gas barriers, and decorative elements comprising these objects.
Abstract translation: 本发明涉及由包含一塑料混合物的金属化薄膜或片材，基于组分A，B，C和D，其给出了一个总的100重量％，A）5〜50重量的热塑性聚合物作为组分％的总重量 A，b）50至95重量具有0.01至100微米的平均颗粒直径（根据说明书中所定义的方法测定），与具有比银的酸性溶液具有更负的标准电极电位的金属的金属粉末的％，作为组分 B，C）0至10重量的分散剂作为C成分的％，和d）0至40重量的纤维状或颗粒状填料或其混合物作为组分D的％，其中所述组分的断裂伸长率（根据中 在塑料混合物的断裂由1.1至100比伸长大的因子定义的方法）的描述，其包括组分A，B和，如果存在的话，C和D（如根据在说明书中确定的 定义的方法），并且其中，所述组分A的拉伸强度（根据由0.5至4倍于说明书中的定义）来确定是比塑料混合物的拉伸强度，包括更大的组分A，B和，如果存在的话，C和D（ 根据在描述中所定义的）来确定。 此外，本发明涉及热塑性模塑组合物用于制造这种金属化的薄膜或片材，颗粒涉及包括这种热塑性模塑材料，复合膜或片，和模制品包括这样的薄膜或片材，金属化聚合物，其包括板，这些膜或片材，复合膜或与模制部件，用于使方法 这些物品中，使用这些对象以及EMI屏蔽，作为吸收体，阻尼器，或用于电磁辐射，氧清除剂，导电部件，阻气性和包含这些对象装饰部件的反射器。
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4.发明申请THERMOPLASTIC MOLDING COMPOUNDS BASED ON ACRYLONITRILE, STYRENE, AND BUTADIENE 审中-公开热塑性模塑化合物基于丙烯腈，苯乙烯和丁二烯
公开(公告)号：WO2008020012A2
公开(公告)日：2008-02-21
申请号：PCT/EP2007058388
申请日：2007-08-14
Applicant: BASF AG , PEPERS MICHEL , MUEHLBACH KLAUS , HAEHNLEIN MARC , SAUER MICHAEL , MITULLA KONRAD , OEPEN SABINE , SUWIER DAVY ROGER , NIESSNER NORBERT
Inventor： PEPERS MICHEL , MUEHLBACH KLAUS , HAEHNLEIN MARC , SAUER MICHAEL , MITULLA KONRAD , OEPEN SABINE , SUWIER DAVY ROGER , NIESSNER NORBERT
IPC: C08L25/12 , C08C1/07 , C08F6/22 , C08F220/12 , C08L55/02
CPC classification number: C08L55/02 , C08C1/07 , C08F6/22 , C08F279/04 , C08L33/08 , C08L2666/04 , C08L25/12 , C08L53/02
Abstract: Disclosed is a method for producing a thermoplastic ABS molding compound. According to said method, the thermoplastic copolymer A is produced from acrylonitrile and styrene by means of bulk polymerization or solution polymerization, while graft copolymer B, which is composed of a graft base (B1) and a graft shell (B2), is produced by means of emulsion polymerization using a redox initiator system, whereupon the thermoplastic copolymer A, graft copolymer B, and additional optional components K and/or additional thermoplastic polymers (TP) are mixed.
Abstract translation: 基于由本体聚合或溶液聚合的丙烯腈和苯乙烯，使用氧化还原引发剂体系通过乳液聚合构成的接枝基体，接枝共聚物B的热塑性共聚物A制备的事实生产热塑性ABS模制组合物（B1）的方法，和接枝外壳（B2 ），制造，然后将热塑性共聚物A和接枝共聚物B和，如果合适的话，另外的部件K和/或其它热塑性聚合物（TP）被混合。
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公开(公告)号：WO0155234A3
公开(公告)日：2001-12-27
申请号：PCT/EP0100897
申请日：2001-01-26
Applicant: BASF AG , MC KEE GRAHAM EDMUND , GAUSEPOHL HERMANN , NIESSNER NORBERT
Inventor： MC KEE GRAHAM EDMUND , GAUSEPOHL HERMANN , NIESSNER NORBERT
IPC: C08F285/00 , C08L51/04
CPC classification number: C08F285/00 , C08L51/04 , C08L2666/02
Abstract: The invention relates to a method for producing impact resistant plastics on the basis of grafted cross-linked rubber particles. The invention further relates to an impact resistant plastic that is obtained using the inventive method. The method for producing the impact resistant plastic comprises the following steps: (a) producing particles of a cross-linked rubber from a first monomer mixture that has a diene composition content of
Abstract translation: 本发明涉及一种制备基于接枝的交联橡胶粒子的耐冲击的塑料和与所述过程schlagzäKen塑料的获得。 为了制造耐冲击树脂（a）的产生，其具有<50重量％，优选<5重量％，特别优选<2重量％的二烯化合物的含量的第一单体混合物的交联橡胶的颗粒。 橡胶与第二单体或单体混合物接枝verntzten（b）中所述颗粒上以形成接枝。 接枝交联橡胶（c）的颗粒加入到三分之一Momonerengemisch和第三单体混合物（d）的单体以形成聚合的矩阵。 本发明的方法是简单的执行并且导致耐冲击的塑料具有优异的机械性能，尤其是与风化更好的抵抗力。
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Patent Agency Ranking
公开(公告)号：WO9618672A2
公开(公告)日：1996-06-20
申请号：PCT/EP9504811
申请日：1995-12-07
Applicant: BASF AG , NIESSNER NORBERT , SKUPIN GABRIEL , DUESTER ERICH , LOTH WOLFGANG , DEN HOVE ARNOLD VAN , WILLENBACHER NORBERT , HENN ROLF
Inventor： NIESSNER NORBERT , SKUPIN GABRIEL , DUESTER ERICH , LOTH WOLFGANG , VAN DEN HOVE ARNOLD , WILLENBACHER NORBERT , HENN ROLF
CPC classification number: C08J9/122 , C08J2325/04
Abstract: The invention pertains to a styrene polymer foam produced from a styrene homo- or copolymer that is foamed by extrusion and optionally processed further and a foaming agent that consists essentially of carbon dioxide, and containing impact-resistant polystyrene.
Abstract translation: 从通过挤出发泡，以及任选地进一步加工苯乙烯均聚物或共聚物和发泡剂基本上由二氧化碳，包括冲击性聚苯乙烯泡沫状的苯乙烯聚合物。
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公开(公告)号：ES2233470T3
公开(公告)日：2005-06-16
申请号：ES00972785
申请日：2000-10-17
Applicant: BASF AG
Inventor： OEPEN SABINE , NIESSNER NORBERT , BREULMANN MICHAEL , GUNTHERBERG NORBERT , DUIJZINGS WIL
IPC: C08F279/04 , C08K5/54 , C08L9/02 , C08L51/04 , C08L55/02
Abstract: Empleo de 10 hasta 200 ppm, con relación a la masa de moldeo F, de al menos un poliorganosiloxano S para reducir las modificaciones de la tonalidad de color indeseadas, provocadas por las bajas temperaturas (Cold Stress Whitening) en masas de moldeo termoplásticas, resilientes, F que presentan al menos un polímero de injerto A caucho-elástico y al menos un polímero B termoplástico, que presenta un valor dE mayor que 3, determinado según DIN 5033.
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公开(公告)号：ES2228941T3
公开(公告)日：2005-04-16
申请号：ES01965130
申请日：2001-07-13
Applicant: BASF AG
Inventor： DUIJZINGS WIL , OEPEN SABINE , NIESSNER NORBERT , BREULMANN MICHAEL , KORB HARDY
IPC: C08C1/07
Abstract: Procedimiento para la aglomeración de al menos un caucho dispersado en fase acuosa (A) mediante adición de una dispersión de al menos un polímero de aglomeración (B) en fase acuosa, caracterizado porque se emplea como B un polímero de aglomeración, que no contiene esencialmente grupos ácidos libres, y se lleva a cabo la aglomeración en presencia de al menos un electrólito básico, empleándose como electrólito básico un hidróxido orgánico o inorgánico.
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公开(公告)号：ES2227174T3
公开(公告)日：2005-04-01
申请号：ES01925444
申请日：2001-03-14
Applicant: BASF AG
Inventor： GINTHERBERG NORBERT , CZAUDERNA BERNHARD , BREULMANN MICHAEL , OEPEN SABINE , DUIJZINGS WIL , NIESSNER NORBERT
Abstract: Procedimiento para la obtención de partículas de caucho K que contienen, en forma polimerizada A) un 80 a un 100 % en peso, referido a K, de butadieno o isopreno, o sus mezclas (monómeros diénicos A), y B) un 0 a un 20 % en peso, referido a K, de uno o varios comonómeros con insaturación monoetilénica B, por medio de polimerización en emulsión en presencia de un emulsionante, o una mezcla de diversos emulsionantes, seleccionados a partir del grupo de sales metálicas alcalinas de ácidos alquil- o alquiarilsulfónico, alquilsulfatos, sulfonatos de alcohol graso, sales de ácidos grasos superiores con 10 a 30 átomos de carbono, sulfosuccinatos, étersulfonatos y etapas resínicas, y un iniciador de polimerización, caracterizado porque 1) se dispone una mezcla en M1, que contiene, referido a M1, M1a)un 20 a un 100 % en peso de agua, que es necesaria para la obtención de emulsión (agua de emulsión), y M1b)un 0, 1 a un 100 % en peso de emulsionante, 2) después se añade una mezcla M2, que contiene, referido a M2, M2a)un 90 a un 100 % en peso de uno o varios monómeros seleccionados a partir de estireno, - metilestireno, butadieno, acrilato de n-butilo, metacrilato de metilo y acrilonitrilo, y M2b)un 0 a un 10 % en peso de uno o varios monómeros copolimerizables.
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公开(公告)号：DE50105198D1
公开(公告)日：2005-03-03
申请号：DE50105198
申请日：2001-01-26
Applicant: BASF AG
Inventor： MC KEE EDMUND , GAUSEPOHL HERMANN , NIESSNER NORBERT
IPC: C08F285/00 , C08L51/04
Abstract: The invention relates to a process for preparing an impact-modified plastic based on grafted crosslinked rubber particles, and also to an impact-modified plastic obtainable by the process. To prepare the impact-modified plastic, (a) particles of a crosslinked rubber are produced from a first monomer mixture which has a content of
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