1.
    发明专利
    未知

    公开(公告)号:ES2062265T3

    公开(公告)日:1994-12-16

    申请号:ES90121605

    申请日:1990-11-12

    Applicant: BASF AG

    Abstract: The novel catalyst for the preparation of high-molecular-weight homopolymers or copolymers of ethene is obtainable by (1) treating a silicon dioxide-based support with (2) chromium trioxide or a chromium compound which can be converted into chromium dioxide under the conditions of step (3), and then (3) heating the resultant intermediate in an oxygen-containing stream of gas, where the support (1) is a specific silicic acid xerogel obtainable by extracting a maximum of 30% of water from a silicic acid hydrogel by means of alkanols, alkanones or mixtures thereof, and subsequently drying, comminuting and fractionating the product.

    3.
    发明专利
    未知

    公开(公告)号:DE3938723A1

    公开(公告)日:1991-05-29

    申请号:DE3938723

    申请日:1989-11-23

    Applicant: BASF AG

    Abstract: The novel catalyst for the preparation of high-molecular-weight homopolymers or copolymers of ethene is obtainable by (1) treating a silicon dioxide-based support with (2) chromium trioxide or a chromium compound which can be converted into chromium dioxide under the conditions of step (3), and then (3) heating the resultant intermediate in an oxygen-containing stream of gas, where the support (1) is a specific silicic acid xerogel obtainable by extracting a maximum of 30% of water from a silicic acid hydrogel by means of alkanols, alkanones or mixtures thereof, and subsequently drying, comminuting and fractionating the product.

    MANUFACTURE OF ETHYLENE POLYMERS IN AN AUTOCLAVE REACTOR

    公开(公告)号:CA1077195A

    公开(公告)日:1980-05-06

    申请号:CA269026

    申请日:1976-12-31

    Applicant: BASF AG

    Abstract: Ethylene polymers are manufactured by polymerizing ethylene under high pressure at high temperatures in an autoclave reactor. The heat of reaction generated by the polymerization is removed, within the reactor, by a cooling system in which the cooling medium is ethylene; the pressure of the monomer in the cooling system should differ by from 0 to 200 bars from the pressure prevailing in the polymerization system, and the temperature of the monomer on entering the cooling system is at least 40.degree.C lower than the temperature prevailing in the autoclave. The process permits an increase in the conversion achieved in the polymerization reaction.

    5.
    发明专利
    未知

    公开(公告)号:DE59005190D1

    公开(公告)日:1994-05-05

    申请号:DE59005190

    申请日:1990-11-12

    Applicant: BASF AG

    Abstract: The novel catalyst for the preparation of high-molecular-weight homopolymers or copolymers of ethene is obtainable by (1) treating a silicon dioxide-based support with (2) chromium trioxide or a chromium compound which can be converted into chromium dioxide under the conditions of step (3), and then (3) heating the resultant intermediate in an oxygen-containing stream of gas, where the support (1) is a specific silicic acid xerogel obtainable by extracting a maximum of 30% of water from a silicic acid hydrogel by means of alkanols, alkanones or mixtures thereof, and subsequently drying, comminuting and fractionating the product.

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