公开(公告)号：FR1282525A

公开(公告)日：1962-01-27

申请号：FR775669

申请日：1958-10-01

Applicant: BASF AG

Inventor： SCHICKH OTTO VON ,  METZGER HORST ,  OETTEL HEINZ ,  WILHELM GERTRUD

IPC: C07D203/14

公开(公告)号：GB860285A

公开(公告)日：1961-02-01

申请号：GB1219158

申请日：1958-04-17

Applicant: BASF AG

Inventor： DEMMLER KURT ,  GOELZ HORST ,  MEYER FERDINAND ,  OETTEL HEINZ ,  WILHELM GERTRUD

Abstract: The invention comprises ethylene imine compounds of the formula wherein X represents oxygen, sulphur or the group -NR-, R being hydrogen or an aliphatic, cycloaliphatic or aromatic hydrocarbon radical, R1 is a radical having an unsaturated chain of 3-5 carbon atoms, the unsaturated linkage being between carbon atoms 2 and 3, 3 and 4 or 4 and 5 (counting from X), and each of R2 and R3 is hydrogen or an aliphatic hydrocarbon radical or R2 and R3 together form an alkylene radical, and the preparation of these compounds by reacting a compound of the formula R1.XH with epichlorhydrin to give the corresponding substituted epoxide (or a halohydrin which is converted to the epoxide), which is treated with an ethylene imine, optionally bearing substituents R2 and R3. The reactant R.XH may be an alcohol such as allyl alcohol or a butanol or a corresponding mercaptan or an amine such as propenylamine, N-methyl propenylamine, N-phenyl butenylamine or N-cyclohexyl pentenylamine. 2 : 3-Epoxypropyl alkenyl ethers and the corresponding thioethers and amines such as 1-alkylthio-, 1-N-methyl-allylamino- and 1-a -methyallyl-oxy-2 : 3-epoxypropane are obtained as intermediates in the above process.

公开(公告)号：FR1429595A

公开(公告)日：1966-02-25

申请号：FR8776

申请日：1965-03-11

Applicant: BASF AG

Inventor： OETTEL HEINZ ,  FROHBERG HARALD ,  KOENIG KARL HEINZ

IPC: A01N31/12 ,  C05F11/10

Abstract: Wheat is treated with a mixture of chlorocholine salt and choline salt. The molar ratio of chlorocholine salt to choline salt may be 1 to 0.05-20. The mixture may be applied as a solid or in aqueous solution. A number of acid radicals including chloride are specified.

公开(公告)号：GB1092138A

公开(公告)日：1967-11-22

申请号：GB1052465

申请日：1965-03-12

Applicant: BASF AG

Inventor： OETTEL HEINZ ,  FROHBERG HARALD ,  KOENIG KARL-HEINZ

IPC: A01N31/12 ,  C05F11/10

Abstract: Wheat is treated with a mixture of chlorocholine salt and choline salt. The molar ratio of chlorocholine salt to choline salt may be 1 to 0.05-20. The mixture may be applied as a solid or in aqueous solution. A number of acid radicals including chloride are specified.

公开(公告)号：CA763893A

公开(公告)日：1967-07-25

申请号：CA763893D

Applicant: BASF AG

Inventor： OETTEL HEINZ ,  FROHBERG HARALD ,  KOENIG KARL-HEINZ

公开(公告)号：GB839305A

公开(公告)日：1960-06-29

申请号：GB3001958

申请日：1958-09-19

Applicant: BASF AG

Inventor： SCHICKH OTTO VON ,  METZGER HORST ,  OETTEL HEINZ ,  WILHELM GERTRUD

IPC: C07D203/14

Abstract: The invention comprises cytostatically active ethylene-imine compounds of the formula wherein R is hydrogen or an alkyl radical, and their preparation by heating 1-methyl-4-isopropenyl - cyclohexene - oxide - (1 : 2) (dipentene monoxide) with ethylene imine or a C-alkyl ethylene imine, optionally in the presence of a solvent, to give a mixture of the above two isomeric compounds.