TRICYCLIC CYCLOHEXANEDIONE DERIVATIVES
    7.
    发明申请
    TRICYCLIC CYCLOHEXANEDIONE DERIVATIVES 审中-公开
    三环环己二酮衍生物

    公开(公告)号:WO0059911A2

    公开(公告)日:2000-10-12

    申请号:PCT/EP0002565

    申请日:2000-03-23

    CPC classification number: C07D495/04 A01N43/90

    Abstract: The invention relates to tricyclic cyclohexanedione derivatives of formula (I) in which the substituents have the following meaning: R is hydrogen, C1-C6 alkyl, C1-C6 haloalkyl, C1-C6 alkoxy, C1-C6 haloalkoxy, C1-C6 alkylthio, C1-C6 haloalkylthio, C1-C6 alkylsulfinyl, C1-C6 haloalkylsulfinyl, C1-C6 alkylsulfonyl, C1-C6 haloalkylsulfonyl, halogen, cyano or nitro; X is O or NR ; R is hydrogen, C1-C6 alkyl, C1-C6 alkoxy, C1-C6 haloalkyl, C1-C6 haloalkoxy, phenyl that is optionally substituted with C1-C3 alkyl, halogen, cyano, nitro or C1-C3 alkylsulfonyl or phenylsulfonyl that is optionally substituted with C1-C3 alkyl, halogen, cyano or nitro; R , R is hydrogen, C1-C6 alkyl, C1-C6 haloalkyl, C1-C6 alkoxy, C1-C6 haloalkoxy, C1-C6 alkylthio, C1-C6 haloalkylthio, C1-C6 alkylsulfinyl, C1-C6 haloalkylsulfinyl, C1-C6 alkylsulfonyl, C1-C6 haloalkylsulfonyl, NR R , C2-C6 alkoxyalkyl, C1-C6 alkoxycarbonyl, C1-C6 alkylcarbonyl, halogen, cyano, nitro, phenyl that is optionally substituted with C1-C3 alkyl, halogen, cyano or nitro; R is hydrogen or C1-C4 alkyl; R is hydrogen, C1-C6 alkyl or halogen; R is hydrogen or C1-C6 alkyl; R is C1-C6 alkyl or C1-C6 alkoxy; 1 is 0, 1 or 2; n is 1 or 2; R is substituted (3-oxo-1-cyclohexene-2-yl)carbonyl or substituted (1,3-dioxo-2-cyclohexyl)methylidene. The invention also relates to the agriculturally useful salts of the compounds (I), to methods for producing said tricyclic cyclohexanedione derivatives and to the intermediates for their production. The invention encompasses agents containing the inventive compounds and the use of said derivatives or of agents containing them for weed control.

    Abstract translation: (I),式三环环己二酮衍生物,其中取代基具有以下含义:R t <1>为氢,C1-C6烷基,C1-C6卤代烷基,C1-C6-烷氧基,C1-C6卤代烷氧基,C1-C6 烷硫基,C1-C6卤代烷硫基,C1-C6烷基亚磺酰基,C1-C6卤代烷基亚磺酰,C 1 -C 6 - 烷基磺酰基,C1-C6卤代烷基磺酰基,卤素,氰基或硝基; X是O或NR <2>; [R <2>的氢,C1-C6烷基,C1-C6-烷氧基,C1-C6卤代烷基,C1-C6-卤代烷氧基,任选地被C1-C3烷基,卤素,氰基,硝基或C1-C3烷基磺酰基取代的取代的 苯基或任选地被C1-C3烷基,卤素,氰基或硝基取代的苯磺酰基; [R <3>,R <4>为氢,C1-C6烷基,C1-C6卤代烷基,C1-C6-烷氧基,C1-C6卤代烷氧基,C1-C6烷硫基,C1-C6卤代烷硫基,C1-C6 烷基亚磺酰基,C1-C6-卤代烷基亚磺酰,C 1 -C 6 - 烷基磺酰基,C1-C6卤代烷基磺酰基,NR <7> - [R <8>,C2-C6烷氧基烷基,C1-C6烷氧羰基,C1-C6烷基羰基,卤素, 氰基,硝基,任选地被C1-C3烷基,卤素,氰基或硝基取代; [R <5>是氢或C1-C4烷基; [R <6>为氢,C1-C6烷基或卤素; [R <7>是氢或C1-C6烷基; [R <8> C1-C6烷基或C1-C6烷氧基; 1 0,1或2; n是1或2; [R <9>取代的(3-氧代-1-环己烯-2-基)羰基,或取代的(1,3-二氧代-2-环己基)亚甲基; 和化合物(I)的可农用盐,用于制备三环环己二酮衍生物以及中间体其制备方法,含有它们的组合物,以及使用这些衍生物或组合物的包含它们的用于控制杂草的方法。

    TRICYCLIC BENZOYLCYCLOHEXANEDIONE DERIVATIVES
    8.
    发明申请
    TRICYCLIC BENZOYLCYCLOHEXANEDIONE DERIVATIVES 审中-公开
    三环benzoylcyclohexanedione衍生物

    公开(公告)号:WO0073311A3

    公开(公告)日:2001-04-19

    申请号:PCT/EP0004806

    申请日:2000-05-26

    CPC classification number: C07D495/04

    Abstract: The invention relates to tricyclic benzoylcyclohexanedione derivatives of formula (I), wherein the variables have the following meanings: X is oxygen, sulphur, S=O, S(=O)2, CR R , NR or a bond; y forms a saturated, partially saturated or unsaturated 5- or 6-membered heterocycle with the two carbons to which it is bonded; R , R , R , R is hydrogen, alkyl, alkyl halide, alkoxy or alkoxy halide; R is halogen, alkyl, alkyl halide, alkoxy or alkoxy halide; R is hydrogen, nitro, halogen, cyano, alkyl, alkyl halide, alkoxy, alkoxy halide, alkylthio, C1-C6- alkylthio halide, alkylsulfinyl, alkylsulfinyl halide, alkylsulfonyl, alkylsulfonyl halide, optionally substituted aminosulfonyl, or optionally substituted sulfonylamino; R is hydrogen, alkyl or halogen; m is 0, 1 or 2; R is hydrogen, alkyl, alkyl halide, alkylcarbonyl, formyl, alkoxycarbonyl, alkoxycarbonyl halide, alkylsulfonyl or alkylsulfonyl halide; and R is substituted (3-oxo-1-cyclohexen-2-yl)-carbonyl or substituted (1,3-dioxo-2-cyclohexyl)-methylidene; and to agriculturally useable salts thereof. The invention also relates to a method for producing the tricyclic benzoylcyclohexanedione derivatives, to products containing them and to the use of said derivatives or said products containing them for combating unwanted vegetation.

    Abstract translation: 式(I),其中各变量具有以下含义的三环benzoylcyclohexanedione衍生物:X是氧,硫,S = O,S(= O)2,CR <6> - [R <7>,NR <8>或键 ; Y共同与两个碳其所结合的,饱和,部分饱和或不饱和5或6元杂环; [R <1>,R <2>,R <6> - [R <7>是氢,烷基,卤代烷基,烷氧基或卤代烷氧基; [R <3>为卤素,烷基,卤代烷基,烷氧基或卤代烷氧基; [R <4>为氢,硝基,卤素,氰基,烷基,卤代烷基,烷氧基,卤代烷氧基,烷硫基,C1-C6卤代烷硫基,烷基亚磺酰基,卤代烷,烷基磺酰基,卤代烷基磺酰基,任选子氨基磺酰基,磺酰氨基或可能子..; [R <5>是氢,烷基或卤素; m是0,1或2; [R <8>是氢,烷基,卤代烷基,烷基羰基,甲酰基,烷氧基羰基,卤代烷氧基羰,烷基磺酰基或卤代烷基磺酰基; [R <9>取代的(3-氧代-1-环己烯-2-基) - 羰基,或取代的(1,3-二氧代-2-环己基)亚甲基; 及其可农用盐; 一种用于三环benzoylcyclohexanedione衍生物的制备方法; 含有它们并使用这些衍生物或包含它们用于控制不希望的植物的组合物的组合物。

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