公开(公告)号：DE102005028463A1

公开(公告)日：2006-12-28

申请号：DE102005028463

申请日：2005-06-17

Applicant: BASF AG

Inventor： PROELS JULIAN ,  BRAMNIK KIRILL ,  WAGNER NORBERT ,  NORDMANN GERO ,  HAMMERMANN MARKUS ,  BENOEHR ALEXANDER

IPC: C01F17/00 ,  C01B35/04 ,  C04B35/58

Abstract: The present invention relates to a process for preparing essentially isometric nanoparticulate lanthanide-boron compounds or solid mixtures comprising essentially isometric nanoparticulate lanthanide-boron compounds, which comprises a) mixing i) one or more lanthanide compounds selected from the group consisting of lanthanide hydroxides, lanthanide hydrides, lanthanide chalcogenides, lanthanide halides, lanthanide borates and mixed compounds of the lanthanide compounds mentioned, ii) one or more compounds selected from the group consisting of crystalline boron, amorphous boron, boron carbides, boron hydrides and boron halides and iii) if appropriate one or more reducing agents selected from the group consisting of hydrogen, carbon, organic compounds, alkaline earth metals and alkaline earth metal hydrides dispersed in an inlet carrier gas with one another, b) reacting the mixture of the components i), ii) and, if appropriate, iii) in the inert solvent by means of thermal treatment within a reaction zone, c) subjecting the reaction product obtained by means of thermal treatment in step b) to rapid cooling and d) subsequently separating off the reaction product which has been cooled in step c), with the cooling conditions in step c) being selected so that the reaction product consists of essentially isometric nanoparticulate lanthanide-boron compounds or comprises essentially isometric nanoparticulate lanthanide-boron compounds.

公开(公告)号：DE102004019649A1

公开(公告)日：2005-11-10

申请号：DE102004019649

申请日：2004-04-22

Applicant: BASF AG

Inventor： BARTENBACH BERND ,  PROELS JULIAN ,  SCHMITZ-BAEDER PETRA ,  WEICHERT CHRISTIAN ,  EHRHARDT KAI RAINER

IPC: C01B3/36 ,  C10G9/00 ,  C10G9/38 ,  C07C4/02 ,  C07C4/04 ,  C07C4/08 ,  C07C5/32 ,  C07C11/02 ,  C07C11/22 ,  C07C15/04 ,  C07C9/04 ,  C10J1/20 ,  C10G70/02 ,  C07B35/04 ,  C07B37/06

Abstract: Methods comprising: (a) providing a starting mixture comprising at least one hydrocarbon and at least one oxygen source, wherein the starting mixture has a fuel number of at least 4; (b) heating the starting mixture to a temperature of not more than 1400° C. and subjecting it to a single-stage, autothermal, uncatalyzed reaction to form a reaction gas; and (c) subjecting the reaction gas to rapid cooling to form at least one olefin and synthesis gas are described.

公开(公告)号：DE102004019650A1

公开(公告)日：2005-11-10

申请号：DE102004019650

申请日：2004-04-22

Applicant: BASF AG

Inventor： BARTENBACH BERND ,  PROELS JULIAN ,  EHRHARDT KAI RAINER

IPC: B01J12/00 ,  B01J19/00 ,  B01J19/24 ,  C01B3/36 ,  C01B3/38 ,  C01C3/02 ,  C07C4/02 ,  C10G9/38 ,  C07C4/04 ,  C07C4/08 ,  C07C5/32 ,  C07C11/02 ,  C07C11/22 ,  C07C15/04 ,  C07C9/04 ,  C10J1/20 ,  C10G70/02 ,  C07B35/04 ,  C07B37/06

Abstract: The present invention relates to a process for preparing thermodynamically unstable products of the oxidative gas-phase reaction of molecular compounds comprising hydrogen and at least one atom other than hydrogen by stabilized autothermal reaction in a porous medium.