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公开(公告)号:DE3912531C2
公开(公告)日:1998-08-27
申请号:DE3912531
申请日:1989-04-17
Applicant: BASF AG
Inventor: HORN PETER DR , HECKMANN WALTER DR , RAMSTEINER FALKO DR , GEROLD FRIEDRICH
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公开(公告)号:ES2063212T3
公开(公告)日:1995-01-01
申请号:ES90115345
申请日:1990-08-10
Applicant: BASF AG
Inventor: HORN PETER DR , HINZ WERNER DR , HECKMANN WALTER DR , RAMSTEINER FALKO DR , GEROLD FRIEDRICH
IPC: A61L31/00 , A61L2/07 , A61L27/18 , A61L27/34 , A61L27/44 , B01D63/02 , B01D65/00 , C08G18/10 , C08G18/12 , C08G18/48 , C08G18/66 , C08G18/72 , C08G18/76
Abstract: The present invention relates to transparent essentially non-cellular polyurethane casting compositions that are sterilizable with superheated steam which are prepared by reacting: (A) modified diphenylmethane diisocyanates (A) liquid at 23 DEG C. obtained by reacting (A1) 4,4'-diphenylmethane diisocyanate or (A2) 2,4'-diphenylmethane diisocyanate or (A3) a diphenylmethane diisocyanate mixture with (A4) at least one polyoxypropylene polyol and/or (A5) at least one polyoxypropylene polyoxyethylene polyol containing 1 to 80 weight percent of ethylene oxide units whereby (A4) and (A5) have a functionality of 4 to 8 and a hydroxyl number of 150 to 500 and are obtained while using sucrose and/or preferably sorbitol as initiator molecules (A6) a mixture of (A4) and/or (A5) and at least one polyoxypropylene polyol and/or polyoxyethylene polyol initiated with glycerine and/or trimethylolpropane in a NCO:OH group ratio of 2.5:1 to 15:1 with (B) at least one compound having at least reactive hydrogen atoms which preferably contains no primary, secondary or tertiary amino groups in bonded form in the presence of or absence of (C) catalysts. The present invention also relates to a process for the preparation of polyurethane casting compositions and their use for medical-technical articles.
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公开(公告)号:DE4134693A1
公开(公告)日:1993-04-22
申请号:DE4134693
申请日:1991-10-21
Applicant: BASF AG
Inventor: HORN PETER DR , HINZ WERNER DR , KNOBLAUCH GEORG , RAMSTEINER FALKO DR , KNORR GOTTFRIED DR
IPC: A61L29/00 , A61F2/00 , A61L27/34 , A61M5/00 , B01D63/02 , C08G18/02 , C08G18/10 , C08G18/12 , C08G18/48 , C08G18/50 , C08G18/66 , C08G18/76
Abstract: The invention relates to transparent, autoclavable, non-cytotoxic, essentially compact polyurethane embedding compositions which are prepared by reacting a) modified diphenylmethane diisocyanates with b) compounds with at least two reactive hydrogens, which contain or are composed of b1) at least one polyether-polyol with an average functionality of from 3 to 8, a hydroxyl number of from 200 to 1000 and an alkali metal ion content of from 150 to 1200 ppm or, preferably, a mixture of (b1) and castor oil and/or at least one polyetherpolyol (b2) with a functionality of from 2 to 3, a hydroxyl number of from 90 to 200 and an alkali metal ion content of less than 10 ppm in the presence or absence of c) catalysts and to a process for preparing the polyurethane embedding compositions and to the use thereof for articles used in medicine.
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公开(公告)号:AT161859T
公开(公告)日:1998-01-15
申请号:AT92117083
申请日:1992-10-07
Applicant: BASF AG
Inventor: HORN PETER DR , HINZ WERNER DR , KNOBLAUCH GEORG , RAMSTEINER FALKO DR , KNORR GOTTFRIED DR
IPC: A61L29/00 , A61F2/00 , A61L27/34 , A61M5/00 , B01D63/02 , C08G18/02 , C08G18/10 , C08G18/12 , C08G18/48 , C08G18/50 , C08G18/66 , C08G18/76
Abstract: The invention relates to transparent, autoclavable, non-cytotoxic, essentially compact polyurethane embedding compositions which are prepared by reacting a) modified diphenylmethane diisocyanates with b) compounds with at least two reactive hydrogens, which contain or are composed of b1) at least one polyether-polyol with an average functionality of from 3 to 8, a hydroxyl number of from 200 to 1000 and an alkali metal ion content of from 150 to 1200 ppm or, preferably, a mixture of (b1) and castor oil and/or at least one polyetherpolyol (b2) with a functionality of from 2 to 3, a hydroxyl number of from 90 to 200 and an alkali metal ion content of less than 10 ppm in the presence or absence of c) catalysts and to a process for preparing the polyurethane embedding compositions and to the use thereof for articles used in medicine.
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公开(公告)号:ES2058395T3
公开(公告)日:1994-11-01
申请号:ES89110556
申请日:1989-06-10
Applicant: BASF AG
Inventor: HORN PETER DR , BLUM RAINER , REICH ERHARD DR , RAMSTEINER FALKO DR
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公开(公告)号:DE59005331D1
公开(公告)日:1994-05-19
申请号:DE59005331
申请日:1990-08-10
Applicant: BASF AG
Inventor: HORN PETER DR , HINZ WERNER DR , HECKMANN WALTER DR , RAMSTEINER FALKO DR , GEROLD FRIEDRICH
IPC: A61L31/00 , A61L2/07 , A61L27/18 , A61L27/34 , A61L27/44 , B01D63/02 , B01D65/00 , C08G18/10 , C08G18/12 , C08G18/48 , C08G18/66 , C08G18/72 , C08G18/76
Abstract: The present invention relates to transparent essentially non-cellular polyurethane casting compositions that are sterilizable with superheated steam which are prepared by reacting: (A) modified diphenylmethane diisocyanates (A) liquid at 23 DEG C. obtained by reacting (A1) 4,4'-diphenylmethane diisocyanate or (A2) 2,4'-diphenylmethane diisocyanate or (A3) a diphenylmethane diisocyanate mixture with (A4) at least one polyoxypropylene polyol and/or (A5) at least one polyoxypropylene polyoxyethylene polyol containing 1 to 80 weight percent of ethylene oxide units whereby (A4) and (A5) have a functionality of 4 to 8 and a hydroxyl number of 150 to 500 and are obtained while using sucrose and/or preferably sorbitol as initiator molecules (A6) a mixture of (A4) and/or (A5) and at least one polyoxypropylene polyol and/or polyoxyethylene polyol initiated with glycerine and/or trimethylolpropane in a NCO:OH group ratio of 2.5:1 to 15:1 with (B) at least one compound having at least reactive hydrogen atoms which preferably contains no primary, secondary or tertiary amino groups in bonded form in the presence of or absence of (C) catalysts. The present invention also relates to a process for the preparation of polyurethane casting compositions and their use for medical-technical articles.
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公开(公告)号:AT83791T
公开(公告)日:1993-01-15
申请号:AT89118473
申请日:1989-10-05
Applicant: BASF AG
Inventor: AYDIN ORAL DR , HUMMERICH RAINER DR , KROBB JOACHIM , PORTUGALL MICHAEL DR , RAMSTEINER FALKO DR , ZOSEL ALBRECHT DR
IPC: C08J3/03 , C08F2/24 , C08F246/00 , C09J11/00 , C09J11/06 , C09J133/06 , C09J143/04 , C09J157/00 , C09J157/04 , C09J201/00 , C09K3/10
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公开(公告)号:DE59010875D1
公开(公告)日:1999-08-12
申请号:DE59010875
申请日:1990-04-14
Applicant: BASF AG
Inventor: HORN PETER DR , HECKMANN WALTER DR , RAMSTEINER FALKO DR , GEROLD FRIEDRICH
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公开(公告)号:DE59209107D1
公开(公告)日:1998-02-12
申请号:DE59209107
申请日:1992-10-07
Applicant: BASF AG
Inventor: HORN PETER DR , HINZ WERNER DR , KNOBLAUCH GEORG , RAMSTEINER FALKO DR , KNORR GOTTFRIED DR
IPC: A61L29/00 , A61F2/00 , A61L27/34 , A61M5/00 , B01D63/02 , C08G18/02 , C08G18/10 , C08G18/12 , C08G18/48 , C08G18/50 , C08G18/66 , C08G18/76
Abstract: The invention relates to transparent, autoclavable, non-cytotoxic, essentially compact polyurethane embedding compositions which are prepared by reacting a) modified diphenylmethane diisocyanates with b) compounds with at least two reactive hydrogens, which contain or are composed of b1) at least one polyether-polyol with an average functionality of from 3 to 8, a hydroxyl number of from 200 to 1000 and an alkali metal ion content of from 150 to 1200 ppm or, preferably, a mixture of (b1) and castor oil and/or at least one polyetherpolyol (b2) with a functionality of from 2 to 3, a hydroxyl number of from 90 to 200 and an alkali metal ion content of less than 10 ppm in the presence or absence of c) catalysts and to a process for preparing the polyurethane embedding compositions and to the use thereof for articles used in medicine.
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公开(公告)号:DE3927244A1
公开(公告)日:1991-02-21
申请号:DE3927244
申请日:1989-08-18
Applicant: BASF AG
Inventor: HORN PETER DR , HINZ WERNER DR , HECKMANN WALTER DR , RAMSTEINER FALKO DR , GEROLD FRIEDRICH
IPC: A61L31/00 , A61L2/07 , A61L27/18 , A61L27/34 , A61L27/44 , B01D63/02 , B01D65/00 , C08G18/10 , C08G18/12 , C08G18/48 , C08G18/66 , C08G18/72 , C08G18/76
Abstract: The present invention relates to transparent essentially non-cellular polyurethane casting compositions that are sterilizable with superheated steam which are prepared by reacting: (A) modified diphenylmethane diisocyanates (A) liquid at 23 DEG C. obtained by reacting (A1) 4,4'-diphenylmethane diisocyanate or (A2) 2,4'-diphenylmethane diisocyanate or (A3) a diphenylmethane diisocyanate mixture with (A4) at least one polyoxypropylene polyol and/or (A5) at least one polyoxypropylene polyoxyethylene polyol containing 1 to 80 weight percent of ethylene oxide units whereby (A4) and (A5) have a functionality of 4 to 8 and a hydroxyl number of 150 to 500 and are obtained while using sucrose and/or preferably sorbitol as initiator molecules (A6) a mixture of (A4) and/or (A5) and at least one polyoxypropylene polyol and/or polyoxyethylene polyol initiated with glycerine and/or trimethylolpropane in a NCO:OH group ratio of 2.5:1 to 15:1 with (B) at least one compound having at least reactive hydrogen atoms which preferably contains no primary, secondary or tertiary amino groups in bonded form in the presence of or absence of (C) catalysts. The present invention also relates to a process for the preparation of polyurethane casting compositions and their use for medical-technical articles.
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