公开(公告)号：DE1918695A1

公开(公告)日：1970-10-15

申请号：DE1918695

申请日：1969-04-12

Applicant: BASF AG

Inventor： WALTER HIMMELE DR ,  WERNER AQUILA DR ,  RICHARD PRINZ DR

IPC: C11B9/00 ,  C07C69/02

Abstract: 1299243 Carboxylic esters of 3-formylbuten- (3)-ol-(1) BADISCHE ANILIN & SODA FABRIK AG 10 April 1970 [12 April 1969] 17096/70 Heading C2C Carboxylic esters of 3-formylbuten-(3)-ol-(1) of general formula where R denotes alkyl 1-18C or a phenyl which may bear one or two alkoxy or alkyl groups (1-4C), chlorine atoms, amino groups or into groups as substituents are prepared by reacting a bismonocarboxylic ester of butene-(2)-diol-(1,4) with carbon monoxide and hydrogen in the presence of a carbonyl complex of rhodium at 50 to 110‹ C. and 300 to 1000 atmospheres. Modifying agents such as phosphites of alkanols, cycloalkanols or phenols, or tri-substituted phosphines may be used and the reaction may be in an inert solvent. Examples describe the preparation of butene-(2)-diol-(1,4) diacetate and dipropionate.

公开(公告)号：DE1918694A1

公开(公告)日：1970-10-15

申请号：DE1918694

申请日：1969-04-12

Applicant: BASF AG

Inventor： WALTER HIMMELE DR ,  WERNER AQUILA DR ,  RICHARD PRINZ DR

IPC: C07C27/22 ,  C07C47/02 ,  E02D29/14 ,  E03F5/06 ,  C07C69/14