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公开(公告)号：JPS61271247A
公开(公告)日：1986-12-01
申请号：JP10873386
申请日：1986-05-14
Applicant: BASF AG
Inventor： DIETRICH GERHARD , NESTLER GERHARD , RUCKH PETER , HERZOG REINHARD
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2.发明专利
公开(公告)号：DE3660807D1
公开(公告)日：1988-11-03
申请号：DE3660807
申请日：1986-05-15
Applicant: BASF AG
Inventor： DIETRICH GERHARD , NESTLER GERHARD , RUCKH PETER , HERZOG REINHARD
Abstract: Alkyl esters of alpha , beta -monoolefinically unsaturated monocarboxylic acids are prepared by esterifying the monocarboxylic acid with an alcohol of 6 to 20 carbon atoms in the presence of from 0.1 to 5% by weight, based on the reaction mixture, of a strong acid and in the presence of a polymerization inhibitor and an oxygen-containing gas, at from 80 DEG to 150 DEG C., by a process in which the molar ratio of the monocarboxylic acid to the alcohol is from 1:0.8 to 1:1.2, and the water of reaction is separated off from the reaction mixture while passing an inert gas containing from 1 to 20% by volume of oxygen through the reaction mixture.
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公开(公告)号：DE3518482A1
公开(公告)日：1986-11-27
申请号：DE3518482
申请日：1985-05-23
Applicant: BASF AG
Inventor： DIETRICH GERHARD , NESTLER GERHARD , RUCKH PETER , HERZOG REINHARD
Abstract: Alkyl esters of alpha , beta -monoolefinically unsaturated monocarboxylic acids are prepared by esterifying the monocarboxylic acid with an alcohol of 6 to 20 carbon atoms in the presence of from 0.1 to 5% by weight, based on the reaction mixture, of a strong acid and in the presence of a polymerization inhibitor and an oxygen-containing gas, at from 80 DEG to 150 DEG C., by a process in which the molar ratio of the monocarboxylic acid to the alcohol is from 1:0.8 to 1:1.2, and the water of reaction is separated off from the reaction mixture while passing an inert gas containing from 1 to 20% by volume of oxygen through the reaction mixture.
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