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公开(公告)号:DE1116404B
公开(公告)日:1961-11-02
申请号:DEB0052032
申请日:1959-02-07
Applicant: BASF AG
Inventor: GOEBEL DR SIEBERT , HAEBERLE DR MANFRED , ZACHER DR WIELAND , SCHMIDT-THOMEE DR GEORG
IPC: C08F10/00
Abstract: In a process for the purification of polyethylene, obtained by polymerization at pressures above 500 excess atmospheres, by freeing it from gaseous and volatile non-gaseous constituents including unreacted monomer, in which the polyethylene, after reaction using a catalyst in a reaction vessel, is led therefrom first into a separator which is at a lower pressure than the reaction pressure, preferably less than 5 excess atmospheres and thence in finely divided form with a large surface area into a degasification chamber in which the polyethylene is subjected to vacuum treatment and thence to an extruder, provision being made to exclude air over the whole path of the polyethylene from the reaction vessel to the extruder, steam is introduced into the separator at a temperature of about 150 DEG C. and is discharged from the separator together with a part of the gaseous and volatile constituents. Further steam, water or an organic solvent may be added to the polyethylene after it leaves the separator and before it enters the degasification chamber. Polymers miscible with polyethylene may be added thereto in the separator and further processed therewith. Apparatus suitable for carrying out the process of the invention is described and illustrated.
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公开(公告)号:DE1220608B
公开(公告)日:1966-07-07
申请号:DEB0059393
申请日:1960-09-16
Applicant: BASF AG
Inventor: SCHMIDT-THOMEE DR GEORG , EILBRACHT DR HANS , KINKEL DR KLAUS , TRIESCHMANN DR HANS-GEORG , URBAN DR FRIEDRICH , ZOCHE DR GUENTHER
IPC: C08F10/00
Abstract: Polyethylene of density more than 0,924 and suitable for the production of film is produced by polymerizing ethylene in a tubular system in the presence of hydrogen as chain transfer agent and oxygen as catalyst, the polymerization being in the absence of solvents or diluents, at pressures between 2000 and 4000 atmospheres and at temperatures between 200 DEG and 300 DEG C., and the ethylene containing 0,05 to 2% of hydrogen and 5 to 20 p.p.m. of oxygen.
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公开(公告)号:DE1042584B
公开(公告)日:1958-11-06
申请号:DEB0031260
申请日:1954-06-02
Applicant: BASF AG
Inventor: PASEDACH DR HEINRICH , SCHMIDT-THOMEE DR GEORG , SEEFELDER DR MATTHIAS
IPC: C07F1/00
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公开(公告)号:DE1035644B
公开(公告)日:1958-08-07
申请号:DEB0038287
申请日:1955-12-13
Applicant: BASF AG
Inventor: PASEDACH DR HEINRICH , SCHMIDT-THOMEE DR GEORG
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公开(公告)号:DE1201552B
公开(公告)日:1965-09-23
申请号:DEB0057543
申请日:1960-04-21
Applicant: BASF AG
Inventor: BOEHM DR HANS , HENGLEIN DR FRIEDRICH , SCHMIDT-THOMEE DR GEORG , STAIGER DR GERHARD , WEBER DR HEINZ
IPC: C08F8/50
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