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    1.
    发明专利
    未知

    公开(公告)号：ES2112001T3

    公开(公告)日：1998-03-16

    申请号：ES95114169

    申请日：1995-09-09

    Applicant: BASF AG

    Inventor： MARCZINKE BERND LOTHAR DR ,  SCHWAGER HARALD DR ,  SEILER ERHARD DR ,  HOFMANN JURGEN

    IPC: C08F255/00 ,  C08K5/3415 ,  C08L23/04 ,  C08L23/10 ,  C08L23/14

    Abstract: Partly crosslinked polyolefin mixt. consists of: (a) a polymer of 25-97 wt.% propylene polymer (IA) contg. 0-15 wt.% copolymerised 2-10C alk-l-ene cpds. (II) and 3-75 wt.% propylene polymer (IB) contg. 15-80 wt.% copolymerised (III); (b) a random ethylene copolymer with 5-20 wt.% copolymerised 3-10C alk-l-ene cpds. and a density of 0.890-0.930 g/cc at room temp.; (c) a homogeneous mixt. of a high mol. polyisobutylene (IV) with an Mn of at least 80,000 and a polyolefin; and (d) a bis-maleimido cpd. of formula (V). In (V): R = 1-20C alkyl, opt. with ether O atom(s) in the chain, 5-7C cycloalkyl or 6-15C aryl, opt. with 1-10C alkyl, 1-6C alkoxy and/or 1-4C dialkylamino substit(s).; or an R -Z-R gp.; R , R = 1-10C alkyl, 5-7C cycloalkyl or 6-10C aryl, opt. with 1-10C alkyl, 1-6C alkoxy and/or 1-4C dialkylamino substit(s).; Z = 1-10C alkyl, 1-4C dialkylamino, -O- or -SO2-. Also claimed are: (i) a method for producing the mixt.; and (ii) films, fibres, mouldings and foam made from the mixt.

    2.
    发明专利
    未知

    公开(公告)号：DE59501358D1

    公开(公告)日：1998-03-05

    申请号：DE59501358

    申请日：1995-09-09

    Applicant: BASF AG

    Inventor： MARCZINKE BERND LOTHAR DR ,  SCHWAGER HARALD DR ,  SEILER ERHARD DR ,  HOFMANN JUERGEN

    IPC: C08F255/00 ,  C08K5/3415 ,  C08L23/04 ,  C08L23/10 ,  C08L23/14

    Abstract: Partly crosslinked polyolefin mixt. consists of: (a) a polymer of 25-97 wt.% propylene polymer (IA) contg. 0-15 wt.% copolymerised 2-10C alk-l-ene cpds. (II) and 3-75 wt.% propylene polymer (IB) contg. 15-80 wt.% copolymerised (III); (b) a random ethylene copolymer with 5-20 wt.% copolymerised 3-10C alk-l-ene cpds. and a density of 0.890-0.930 g/cc at room temp.; (c) a homogeneous mixt. of a high mol. polyisobutylene (IV) with an Mn of at least 80,000 and a polyolefin; and (d) a bis-maleimido cpd. of formula (V). In (V): R = 1-20C alkyl, opt. with ether O atom(s) in the chain, 5-7C cycloalkyl or 6-15C aryl, opt. with 1-10C alkyl, 1-6C alkoxy and/or 1-4C dialkylamino substit(s).; or an R -Z-R gp.; R , R = 1-10C alkyl, 5-7C cycloalkyl or 6-10C aryl, opt. with 1-10C alkyl, 1-6C alkoxy and/or 1-4C dialkylamino substit(s).; Z = 1-10C alkyl, 1-4C dialkylamino, -O- or -SO2-. Also claimed are: (i) a method for producing the mixt.; and (ii) films, fibres, mouldings and foam made from the mixt.

    3.
    发明专利
    未知

    公开(公告)号：DE59202651D1

    公开(公告)日：1995-08-03

    申请号：DE59202651

    申请日：1992-02-26

    Applicant: BASF AG

    Inventor： BROSIUS SIBYLLE DR ,  SEILER ERHARD DR ,  SCHWAGER HARALD DR ,  KRESS GERHARD DR ,  SCHLEMMER LOTHAR

    IPC: C08F255/02

    Abstract: Partially crosslinked polymer composition containing a) a polymer comprising from 25 to 95% by weight of polypropylene and from 5 to 75% by weight of a propylene copolymer containing copolymerized C2-C10-alk-1-enes, where the comonomer content is from 1 to 45% by weight, based on the total polymer, b) a random ethylene copolymer containing from 5 to 20% by weight of copolymerized C3-C10-alk-1-enes and having a density at room temperature of from 0.89 to 0.925 g/cm and c) an organosilane compound of the formula (I> A4-n-SiRn (I> in which the A radicals are identical or different and are acrylates or methacrylates or vinyl groups, the R radicals are identical or different and are C1-C8-alkoxy or C1-C8-acetoxy groups, and n is the number 1, 2 or 3, obtainable by reacting a polymer mixture of the polymer a) and the random ethylene copolymer b) with the organosilane compound c) in the presence of a free-radical initiator and in the presence of a condensation catalyst, at temperatures of from 180 to 280 DEG C, pressures of from 1 to 100 bar and mean residence times of the reaction mixture of from 0.2 to 10 minutes.

    5.
    发明专利
    未知

    公开(公告)号：DE59001440D1

    公开(公告)日：1993-06-17

    申请号：DE59001440

    申请日：1990-10-19

    Applicant: BASF AG

    Inventor： SEILER ERHARD DR ,  RUEMPLER KLAUS-DIETER DR ,  JUNG NORBERT ,  HAARDT UDO ,  HENNING RAINER DR ,  HAMBRECHT JUERGEN DR

    IPC: B60R19/03 ,  B60R19/18 ,  B60R19/22

    Abstract: The invention relates to a polypropylene-based bumper system comprising a bumper support A (1) comprising glass fibre-reinforced polypropylene, an energy-absorbing foam core B (2) comprising foamed polypropylene, and a tough shell C (3) which comprises EP rubber-modified polypropylene and may, if desired, be painted. The bumper system can be recycled by mechanical comminution, extrusion and granulation. The granules can be used to produce injection mouldings having good mechanical properties.

    6.
    发明专利
    未知

    公开(公告)号：DE3880514D1

    公开(公告)日：1993-06-03

    申请号：DE3880514

    申请日：1988-01-22

    Applicant: BASF AG

    Inventor： TAUBITZ CHRISTOF DR ,  GAUSEPOHL HERMANN DR ,  SEILER ERHARD DR ,  BOEHLKE KLAUS DR ,  SCHLEMMER LOTHAR

    IPC: C08J3/20 ,  C08F283/08 ,  C08G65/48 ,  C08L71/12 ,  C08L77/00

    Abstract: Continuous prodn. of thermoplastic polyphenylene ether /polyamide moulding materials in an extruder comprises (1) reacting in a first zone at 240-350 deg.C (by wt. w.r.t. total components (a1)-(a5): (a1) 50-99.5% of a polyphenylene ether, (a2) 0-45% of a vinylaromatic polymer, (a3) 0.05-10% of (a31) an alpha-beta-unsatd. carboxylic acid of derivs. of this of formula R1-CO-C(R2)=C(R3)-CO-R4 (I) in which R1 and R4=OH, aryloxy, alkoxy, aralkoxy or cycloalkoxy gps. with up to 12C, or R1 and R4 together=-O- or -NR5-; R2 and R3=H, alkyl or cycloalkyl with up to 12C, aryl or Cl, or R2 and R3 may together form a 4-12C alkylene gp.; R5=alkyl, cycloalkyl, aralkyl or aryl gp. wit- up to 12C, which may be substd. with 1-4C alkyl or alkoxy gps., and/or (a32) a monomer contg. an amide gp. and a polymerisable double bond, and/or (a33) a monomer contg. a lactam gp. and a polymerisable double bond; and opt. (a4) 0-80% other monomers suitable for grafting and (a5) 0-20% radical initiators, for 0.1-15 mins. to give a modified polyphenylene ether A; and (2) subsequently introducing into a further zone of the extruder at 250-350 deg.C (by wt. w.r.t. total components A-F); (B) 5-95 wt.% of a polyamide, (C) 0-90 wt.% of an unmodified polyphenylene ether, (D) 0-45% of a vinyl aromatic polymer, (E) 0-40% of an impact-improving modifying rubber, (F) 0-60% additives and processing aids, and finally extruding the mixt..

    8.
    发明专利
    未知

    公开(公告)号：DE3871988D1

    公开(公告)日：1992-07-23

    申请号：DE3871988

    申请日：1988-02-24

    Applicant: BASF AG

    Inventor： TAUBITZ CHRISTOF DR ,  SEILER ERHARD DR ,  HECKMANN WALTER DR ,  THEYSOHN RAINER DR

    IPC: C08F279/02 ,  C08F285/00 ,  C08L51/04 ,  C08L77/00

    Abstract: Thermoplastics moulding compsn. contains (w.r.t. A+B) (A) 5-95 (wt.)% resin(s) consisting of (a1) 8-12C vinylaromatic monomer(s), (a2) alpha,beta-unsatd. dicarbonyl monomer(s) and (a3) elastomer(s) (rubber) and (B) 95-5% polyamide(s). The novelty is that resin (A) is obtd. by grafting (a1) to an unmodified resin in the presence of a3, then modification in the melt at 120-280 deg.C in the presence of a2, using the monomers in such amts. that A consists of 97-50% a1, 0.05-10% a2 and 3-50% a3.

    9.
    发明专利
    未知

    公开(公告)号：DE3936194A1

    公开(公告)日：1991-05-02

    申请号：DE3936194

    申请日：1989-10-31

    Applicant: BASF AG

    Inventor： SEILER ERHARD DR ,  RUEMPLER KLAUS-DIETER DR ,  JUNG NORBERT ,  HAARDT UDO ,  HENNING RAINER DR ,  HAMBRECHT JUERGEN DR

    IPC: B60R19/03 ,  B60R19/18 ,  B60R19/22

    Abstract: The invention relates to a polypropylene-based bumper system comprising a bumper support A (1) comprising glass fibre-reinforced polypropylene, an energy-absorbing foam core B (2) comprising foamed polypropylene, and a tough shell C (3) which comprises EP rubber-modified polypropylene and may, if desired, be painted. The bumper system can be recycled by mechanical comminution, extrusion and granulation. The granules can be used to produce injection mouldings having good mechanical properties.

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