公开(公告)号：US3639375A

公开(公告)日：1972-02-01

申请号：US3639375D

申请日：1968-01-29

Applicant: BASF AG

Inventor： STAIGER GERHARD ,  STEDEFEDER JOACHIM

IPC: C08F10/00 ,  C08F1/56 ,  C08F3/10

CPC classification number: C08F10/00 ,  Y10S526/906 ,  C08F4/42

Abstract: POLYMERIZATION OF A -OLEFINS HAVING TWO TO EIGHT CARBON ATOMS IN THE PRESENCE OF A CATALYST CONSISTING OF A COMPLEX COMPOUND OF A TITANIUM (III) HALIDE AND AN ALUMINUM HALIDE AND AN ORGANOALUMINUM COMPOUND AND, OPTIONALLY, AN ORGANOZINC COMPOUND, PLUS A SECONDARY OR TERTIARY AMINE AND ALSO AN ORGANIC PHOSPHORUS COMPOUND OF THE FORMULA BELOW, SAID CATALYST BEING PRODUCED BY GRINDING AT LEAST SAID COMPLEX COMPOUND WITH ONE OR BOTH OF SAID AMINE AND SAID PHOSPHORUS COMPOUND.

公开(公告)号：AU3576184A

公开(公告)日：1985-05-30

申请号：AU3576184

申请日：1984-11-21

Applicant: BASF AG

Inventor： STAIGER GERHARD ,  GRUBER WOLFGANG

IPC: C08F4/10 ,  C08F4/16 ,  C08F4/64 ,  C08F10/00 ,  C08F4/66 ,  C08F110/06

公开(公告)号：NO771259L

公开(公告)日：1977-10-14

申请号：NO771259

申请日：1977-04-12

Applicant: BASF AG

Inventor： STAIGER GERHARD ,  BRONSTERT KLAUS

IPC: C08F4/60 ,  C08F4/00 ,  C08F4/64 ,  C08F10/00 ,  C08F

Abstract: A process for the manufacture of poly- alpha -olefins by polymerizing alpha -olefins by means of a catalyst system comprising (1) a titanium-containing component obtained from (1.1) a compound of the formula TiCl3.1/3AlCl3 and (1.2) an organic electron donor, containing phosphorus, nitrogen and/or oxygen atoms, which has been milled with the compound of the formula TiCl3.1/3AlCl3 (1.1), in order to form a complex compound, the milling being carried out without assistants or additives in a vibratory ball mill under specific acceleration conditions and at a temperature which is from 4 DEG to 10 DEG C. below the temperature at which the particles of the material being ground begin to agglomerate, and (2) an aluminum-containing component, in which process the titanium-containing component (1) of the catalyst system used is one which has been treated, after milling and before polymerization, with (i) titanium tetrachloride and (ii) an ether and/or an ester.

公开(公告)号：FR1369718A

公开(公告)日：1964-08-14

申请号：FR947980

申请日：1963-09-19

Applicant: BASF AG

Inventor： STAIGER GERHARD ,  FOERSTER GUENTER ,  HAMPRECHT GUENTHER

IPC: C08F10/00

公开(公告)号：CA593734A

公开(公告)日：1960-03-01

申请号：CA593734D

Applicant: BASF AG

Inventor： WEICKMANN AUGUST ,  STAIGER GERHARD ,  SPAENIG HERMANN ,  JAHRSTORFER MICHAEL

公开(公告)号：AU543049B2

公开(公告)日：1985-03-28

申请号：AU6835481

申请日：1981-03-13

Applicant: BASF AG

Inventor： STAIGER GERHARD ,  SCHWEIER GUENTHER

IPC: C08F4/64 ,  C08F10/00 ,  C08F4/66 ,  C08F110/06

公开(公告)号：AU2357777A

公开(公告)日：1978-09-28

申请号：AU2357777

申请日：1977-03-24

Applicant: BASF AG

Inventor： STAIGER GERHARD ,  BRONSTERT KLAUS

IPC: C08F4/00 ,  C08F4/60 ,  C08F4/64 ,  C08F10/00 ,  C08F110/02

Abstract: A process for the manufacture of poly- alpha -olefins by polymerizing alpha -olefins by means of a catalyst system comprising (1) a titanium-containing component obtained from (1.1) a compound of the formula TiCl3.1/3AlCl3 and (1.2) an organic electron donor, containing phosphorus, nitrogen and/or oxygen atoms, which has been milled with the compound of the formula TiCl3.1/3AlCl3 (1.1), in order to form a complex compound, the milling being carried out without assistants or additives in a vibratory ball mill under specific acceleration conditions and at a temperature which is from 4 DEG to 10 DEG C. below the temperature at which the particles of the material being ground begin to agglomerate, and (2) an aluminum-containing component, in which process the titanium-containing component (1) of the catalyst system used is one which has been treated, after milling and before polymerization, with (i) titanium tetrachloride and (ii) an ether and/or an ester.

公开(公告)号：AU565780B2

公开(公告)日：1987-09-24

申请号：AU3576184

申请日：1984-11-21

Applicant: BASF AG

Inventor： STAIGER GERHARD ,  GRUBER WOLFGANG

IPC: C08F4/10 ,  C08F4/16 ,  C08F4/64 ,  C08F10/00 ,  C08F4/66 ,  C08F110/06

公开(公告)号：ZA8405808B

公开(公告)日：1985-04-24

申请号：ZA8405808

申请日：1984-07-27

Applicant: BASF AG

Inventor： STAIGER GERHARD ,  GRUBER WOLFGANG

IPC: C08F4/10 ,  C08F4/12 ,  C08F4/16 ,  C08F10/00 ,  C08F

CPC classification number: C08F10/00 ,  C08F4/6465 ,  C08F4/6548

公开(公告)号：CA1079447A

公开(公告)日：1980-06-10

申请号：CA274601

申请日：1977-03-23

Applicant: BASF AG

Inventor： STAIGER GERHARD ,  BRONSTERT KLAUS

IPC: C08F4/00 ,  C08F4/60 ,  C08F4/64 ,  C08F10/00

Abstract: A process for the manufacture of poly-.alpha.-olefins by polymerizing .alpha.-olefins by means of a catalyst system comprising (1) a titanium-containing component obtained from (1.1) a compound of the formula TiCl3 . 1/3 AlCl3 and (1.2) an organic electron donor, containing phosphorus, nitrogen and/or oxygen atoms, which has been milled with the compound of the formula TiC13 . 1/3 AlCl3 (1.1), in order to form a complex compound, the milling being carried out without assistants or additives in a vibratory ball mill under specific acceleration conditions and at a temperature which is from 4 to 10.degree.C below the temperature at which the particles of the material being ground begin to agglomerate, and (2) an aluminum-containing component, in which process the titanium-containing component (1) of the catalyst system used is one which has been treated, after milling and before polymerization, with (i) titanium tetrachloride and (ii) an ether and/or an ester.