Di-imido-di-carbonyl chlorides prodn - via acid obtd from trimellitic anhydride and aromatic diamine in inert org suspension

    公开(公告)号:DE2425667A1

    公开(公告)日:1975-12-11

    申请号:DE2425667

    申请日:1974-05-28

    Applicant: BASF AG

    Abstract: Dicarbonyl chlorides (I) contg. imide gps. are produced by (a) suspending trimellitic anhydride (II) and aromatic diamines (III) of the formula H2N.C6H4.X.C6H4.NH2) (in which X is CH2, 0, S, SO2 or CO; the NH2 gps. can be in the o-, m- or p-position) in a high-boiling inert organic liquid (IV) and reacting to the diimido-dicarboxylic acid (V) and then (b) converting (V) to (I) with SOCL2 or COCL2. High temp. -resistant polymers and pigments are produced by reacting a suspension of (I) in PhNO2, without further purificn., with diphenols, diamines or aminophenols. (I) are obtd. in almost 100% yield and in high purity by a process suitable for technical operation.

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