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公开(公告)号:ZA200708352B
公开(公告)日:2009-07-29
申请号:ZA200708352
申请日:2007-10-01
Applicant: BASF AG
Inventor: STEFAN ENGEL , TANJA OBERDING
IPC: C07C20090101
Abstract: A process for preparing substituted biphenyls in which R1=nitro, amino or NHR3, R2=CN, NO2, halogen, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C1-C6-alkoxy, C1-C6-haloalkyl, C1-C6-alkylcarbonyl or phenyl, R3=C1-C4-alkyl, C2-C4-alkenyl or C2-C4-alkynyl, m=1 or 2; n=0 to 3, which comprises reacting a compound II in the presence of a base and of a palladium catalyst selected from the group of: a) palladium-triarylphosphine or -trialkylphosphine complex with palladium in the zero oxidation state, b) salt of palladium in the presence of triarylphospine or trialkylphosphine as a complex ligand or c) metallic palladium applied to support if appropriate, in the presence of triarylphosphine or trialkylphosphine, in a solvent, with a diphenylborinic acid (III)