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公开(公告)号:JPH0625064A
公开(公告)日:1994-02-01
申请号:JP8059893
申请日:1993-04-07
Applicant: BASF AG
Inventor: OIGEN GEERAA , BUORUFUGANGU HAADAA , KURAUSU EEBERU , YOHANNPEETAA MERUDAA , YOAKIMU HENRIKU TERESU
IPC: B01J31/02 , C07B61/00 , C07C45/75 , C07C47/19 , C07D233/88 , C07D249/14 , C07D277/42
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公开(公告)号:JPH06211723A
公开(公告)日:1994-08-02
申请号:JP22578693
申请日:1993-09-10
Applicant: BASF AG
Inventor: YOAKIMU HENRIKU TERESU , YOHANNPEETAA MERUDAA , OIGEN GEERAA , BUORUFUGANGU HAADAA , KURAUSU EEBERU , KARUSUTEN GUREENINGU , REGIINA MAIAA
IPC: B01J31/02 , C07B61/00 , C07C45/75 , C07C47/19 , C07C49/17 , C07D249/08 , C07D249/10 , C07D249/12 , C07D249/14 , C07D257/04 , C07D471/04 , C07D487/04
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公开(公告)号:JPH08243392A
公开(公告)日:1996-09-24
申请号:JP3975996
申请日:1996-02-27
Applicant: BASF AG
Inventor: YOHANNPEETAA MERUDAA , YOOAHIMU BURUFUUDEERINGU , FURANKU GUUCHIYOOBUEN , TOMU BUITSUTSUERU , BUORUFUGANGU HAADAA
IPC: C07D295/02 , B01J23/38 , B01J23/46 , B01J23/54 , B01J23/56 , B01J23/89 , C07B61/00 , C07C209/14 , C07C209/16 , C07C209/24 , C07C209/26 , C07C211/03 , C07C211/10 , C07C213/02 , C07C215/14
Abstract: PROBLEM TO BE SOLVED: To prevent a decrease in an operative life due to disintegration without nickel and cobalt by using a catalyst comprising ruthenium and a co-catalyst selected from the group consisting of rhodium, etc., in the respective specified weight ratios on a porous oxide. SOLUTION: Amination of alcohol, ketone or aldehyde is carried out by using a novel improved catalyst comprising 0.001-25 wt.% of ruthenium and 0-5 wt.% of a co-catalyst selected from the group consisting of iron, rhodium, palladium, platinum, iridium, osmium, copper, silver, gold, chromium, molybdenum, tungsten, rhenium, sodium, potassium, rubidium, cesium, phosphorus, arsenic, antimony, bismuth, tellurium, thallium and their mixtures. Such catalyst is used advantageously not only in amination of alcohol but also in reductive aminating reactions of ketone and aldehyde.
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