-
公开(公告)号:DE50011721D1
公开(公告)日:2006-01-05
申请号:DE50011721
申请日:2000-04-06
Applicant: BASF AG
Inventor: SLANY DR , SCHULZ DR , SCHAEFER DR , ZELLER DR , EBEL DR
IPC: C07D263/08 , C07D233/76 , C07D263/44
Abstract: Preparation of hydantoins or aminoacid cyclic anhydrides (I) involves reacting an aldehyde (II) with carbon monoxide and a u or carbamate compound (III) in presence of a transition metal catalyst. Preparation of hydantoins or aminoacid cyclic anhydrides of formula (I) involves reacting an aldehyde RCHO (II) with carbon monoxide and a urea or carbamate compound of formula R3-NH-C(O)-R2 (III) in presence of a transition metal catalyst. X = O or NH; R = alkyl or aryl (both optionally substituted); R3 = H or as defined for R; R2 = group which reacts with the COOH group formed in the reaction under ring-closure to form (I).