Abstract:
Catalyst articles comprising palladium and related methods of preparation and use are disclosed. Disclosed is a catalyst article comprising a first catalytic layer formed on a substrate, wherein the first catalytic layer comprises palladium impregnated on a ceria-free oxygen storage component and platinum impregnated on a refractory metal oxide, and a second catalytic layer formed on the first catalytic layer comprising platinum and rhodium impregnated on a ceria-containing oxygen storage component. The palladium component of the catalyst article is present in a higher proportion relative to the other platinum group metal components. The catalyst articles provide improved conversion of carbon monoxide in exhaust gases, particularly under rich engine operating conditions.
Abstract:
Catalyst articles comprising substantially only a palladium precious metal component in a first catalytic layer and a rhodium component in a second catalytic layer and related methods of preparation and use are disclosed. Also disclosed is a catalyst article comprising a first layer formed on a carrier substrate, wherein the first layer comprises a refractory metal oxide and has a surface that is substantially uniform; a second layer formed on the first layer, wherein the second layer comprises i) an oxygen storage component that is about 50-90% by weight of the second layer and ii) a palladium component in an amount of about 2-5% by weight of the second layer, wherein the palladium component is substantially the only platinum group metal component, and a palladium-free third layer comprising a rhodium component supported on a thermostable oxygen storage component which is about 80-99% by weight of the second layer. One or more improved properties are exhibited by the catalyst article.
Abstract:
Catalyst articles comprising palladium and related methods of preparation and use are disclosed. Disclosed is a catalyst article comprising a first catalytic layer formed on a substrate, wherein the first catalytic layer comprises palladium impregnated on a ceria-free oxygen storage component and platinum impregnated on a refractory metal oxide, and a second catalytic layer formed on the first catalytic layer comprising platinum and rhodium impregnated on a ceria-containing oxygen storage component. The palladium component of the catalyst article is present in a higher proportion relative to the other platinum group metal components. The catalyst articles provide improved conversion of carbon monoxide in exhaust gases, particularly under rich engine operating conditions.
Abstract:
artigo catalisador para uso em um motor de combustão interna e métodos de tratar escapamento de motor e de fabricar um artigo catalisador. artigos catalisadores compreendendo paládio e método relacionados de preparação e uso são descritos. é divulgado um artigo catalisador que compreende uma primeira camada catalítica formada sobre um substrato, em que a primeira camada catalítica formada sobre um substrato, em que a primeira camada catalítica compreende paládio impregnado sobre um componente de armazenamento de oxigênio livre de céria e platina impregnada sobre um óxido de metal refratário, e uma segunda camada catalítica formada sobre a primeira camada catalítica compreendendo platina e ródio imrpegnados sobre um componente de armazenamento de oxigênio contendo céria. o componente de paládio do artigo catalisador está presente em uma proporção mais elevada em relação aos outros componentes do metal do grupo da platina. os artigos catalisadores proporcionam conversão melhorada de monóxido de carbono em gases de escapamento, particularmente sob condições ricas de operação do motor.
Abstract:
CATALYST ARTICLES COMPRISING PALLADIUM AND RELATED METHODS OF PREPARATION AND USE ARE DISCLOSED. DISCLOSED IS A CATALYST ARTICLE COMPRISING A FIRST CATALYTIC LAYER FORMED ON A SUBSTRATE, WHEREIN THE FIRST CATALYTIC LAYER COMPRISES PALLADIUM IMPREGNATED ON A CERIA-FREE OXYGEN STORAGE COMPONENT AND PLATINUM IMPREGNATED ON A REFRACTORY METAL OXIDE, AND A SECOND CATALYTIC LAYER FORMED ON THE FIRST CATALYTIC LAYER COMPRISING PLATINUM AND RHODIUM IMPREGNATED ON A CERIA-CONTAINING OXYGEN STORAGE COMPONENT. THE PALLADIUM COMPONENT OF THE CATALYST ARTICLE IS PRESENT IN A HIGHER PROPORTION RELATIVE TO THE OTHER PLATINUM GROUP METAL COMPONENTS. THE CATALYST ARTICLES PROVIDE IMPROVED CONVERSION OF CARBON MONOXIDE IN EXHAUST GASES, PARTICULARLY UNDER RICH ENGINE OPERATING CONDITIONS.
Abstract:
Provided herein are catalytic articles and methods of making same using a single coat process. The catalytic article comprises an elongated substrate monolith having a plurality of longitudinally extending passages, each passage having at least a first surface and a second surface opposite the first surface, the first and second surfaces coated with at least a first coating and a second coating, wherein the first coating comprises a first catalyst composition and overlies the second coating on the first surface, the second coating comprises a second catalyst composition and overlies the first coating on the second surface, and wherein the first catalyst composition and second catalyst composition have a difference in surface charge. The washcoat may be applied as one slurry, which then self-segregates into two coatings.
Abstract:
En la presente se proporcionan artículos catalíticos y métodos para fabricarlos usando un proceso de único recubrimiento. El artículo catalítico comprende un monolito de sustrato alargado que tiene múltiples pasajes que se extienden longitudinalmente, cada pasaje tiene al menos una primera superficie y una segunda superficie opuesta a la primera superficie, la primera y segunda superficies están recubiertas con al menos un primer recubrimiento y un segundo recubrimiento, donde el primer recubrimiento comprende una primera composición de catalizador y cubre el segundo recubrimiento en la primera superficie, el segundo recubrimiento comprende una segunda composición de catalizador y cubre el primer recubrimiento en la segunda superficie, y donde la primera composición de catalizador y la segunda composición de catalizador tienen una diferencia en la carga de superficie. El revestimiento se puede aplicar como una suspensión, que luego se autosegrega en dos recubrimientos.