AQUEOUS DISPERSIONS FOR COATING COMPOSITIONS
    1.
    发明申请
    AQUEOUS DISPERSIONS FOR COATING COMPOSITIONS 审中-公开
    涂料组合物的均匀分散体

    公开(公告)号:WO02059219A3

    公开(公告)日:2003-01-23

    申请号:PCT/US0148628

    申请日:2001-12-17

    CPC classification number: C09D5/027 C08J3/03 C09D201/025

    Abstract: The invention provides curable coating compositions comprising an aqueous dispersion comprising a stabilizing resin (P1) and a compound (P2) comprising functional groups reactable with a crosslinking agent. Compound (P2) is dispersed into stabilizing resin (P1). The coating compositions of the invention may further comprise an optional crosslinking agent (P3) which may or may not be dispersed into stabilizing resin (P1). In a particularly preferred embodiment, both the stabilizing resin (P1) and compound (P2) will comprise functional groups which are carbamate or are convertible to carbamate.

    Abstract translation: 本发明提供了包含包含稳定树脂(P1)的水分散体和包含可与交联剂反应的官能团的化合物(P2)的可固化涂料组合物。 化合物(P2)分散在稳定树脂(P1)中。 本发明的涂料组合物可以进一步包含任选的交联剂(P3),其可以分散或不分散在稳定树脂(P1)中。 在特别优选的实施方案中,稳定树脂(P1)和化合物(P2)都将包含氨基甲酸酯或可转化为氨基甲酸酯的官能团。

    FUNCTIONAL ADDITION POLYMERS AND A METHOD FOR THEIR PREPARATION
    5.
    发明申请
    FUNCTIONAL ADDITION POLYMERS AND A METHOD FOR THEIR PREPARATION 审中-公开
    功能性加成聚合物及其制备方法

    公开(公告)号:WO2006039122A3

    公开(公告)日:2006-07-20

    申请号:PCT/US2005033201

    申请日:2005-09-16

    Abstract: Disclosed is a method for making nongelled functional addition polymers from linear unsaturated anhydrides. The method subjects a linear unsaturated anhydride compound, an active hydrogen compound, and an epoxide compound to reaction conditions such that each of the following three reactions occur: (i) polymerization of polymerizable C=C bonds, (ii) ring opening of an anhydride functional group of the linear unsaturated anhydride compound by the active hydrogen compound to create an acid functional group, and (iii) reaction of the acid functional group resulting from the anhydride ring opening with the epoxide compound. At the time of reaction (iii), the acid functional group resulting from the anhydride ring opening may be selected from an ethylenically unsaturated monomer, a polymer, or both. In one embodiment, the method does not include the physical removal of any acid functional monomers or polymerization products. Also disclosed are a curable coating composition and a coated substrate.

    Abstract translation: 公开了由线性不饱和酸酐制备非胶凝功能加成聚合物的方法。 该方法使直链不饱和酸酐化合物,活性氢化合物和环氧化合物发生反应条件,使得发生以下三种反应中的每一种:(i)可聚合的C = C键的聚合,(ii)酸酐的开环 通过活性氢化合物形成直链不饱和酸酐化合物的官能团以产生酸官能团,和(iii)由酸酐开环得到的酸官能团与环氧化合物反应。 在反应(iii)时,由酸酐开环得到的酸官能团可以选自烯属不饱和单体,聚合物或两者。 在一个实施方案中,该方法不包括任何酸官能单体或聚合产物的物理去除。 还公开了一种可固化涂料组合物和涂覆的基材。

    METHOD FOR IMPROVING ENVIRONMENTAL DURABILITY OF MATERIALS
    6.
    发明申请
    METHOD FOR IMPROVING ENVIRONMENTAL DURABILITY OF MATERIALS 审中-公开
    改善材料环境耐久性的方法

    公开(公告)号:WO2005123782A3

    公开(公告)日:2006-05-04

    申请号:PCT/US2005020610

    申请日:2005-06-10

    Abstract: Disclosed is a method of making an environmentally durable material, the method requiring providing a material comprising at least one functional group Fc, and subjecting the material to a free radical source such that substantially all functional groups Fc are eliminated but the material is not polymerized. In one embodiment, the functional group Fc is at least one of a nonaromatic carbon-carbon double bond, a hydrogen atom alpha to an aromatic ring, a hydrogen atom alpha to a carbon-carbon double bond, or a hydrogen atom attached to a tertiary substituted carbon. In another embodiment, functional group Fc is present in the material as a contaminant. In one exemplary embodiment, the material comprises from 0.05 to less than 15 % by weight of functional group Fc, based on the total weight of the material.

    Abstract translation: 公开了一种制备环境耐久材料的方法,该方法需要提供包含至少一个官能团Fc的材料,并使材料经受自由基源,使得基本上所有的官能团Fc都被去除,但是材料没有聚合。 在一个实施方案中,官能团Fc是非芳族碳 - 碳双键,芳族环中的α,氢原子,碳 - 碳双键的氢原子或连接到第三个碳原子上的氢原子中的至少一个 取代碳。 在另一个实施方案中,官能团Fc作为污染物存在于材料中。 在一个示例性实施方案中,基于材料的总重量,该材料包含0.05至小于15重量%的官能团Fc。

    WATERBORNE COATING COMPOSITIONS CONTAINING CROSSLINKABLE MONOMERIC DIFUNCTIONAL COMPOUNDS HAVING AT LEAST THIRTY CARBON ATOMS
    7.
    发明申请
    WATERBORNE COATING COMPOSITIONS CONTAINING CROSSLINKABLE MONOMERIC DIFUNCTIONAL COMPOUNDS HAVING AT LEAST THIRTY CARBON ATOMS 审中-公开
    含有最少三碳化碳的可交联单体二官能化合物的水性涂料组合物

    公开(公告)号:WO2004031310A8

    公开(公告)日:2005-03-17

    申请号:PCT/US0320855

    申请日:2003-07-01

    Abstract: The invention provides curable waterborne coating compositions comprising an aqueous dispersion (A) comprising an organic binder component (A1) comprising at least 5% by weight of a reactive component (a), based on the total weight of organic binder component (A1), and at least one crosslinking component (B). The reactive component (a) is substantially free of any heteratoms and is a not a crystalline solid at room temperature and comprises from (i) 12 to 72 carbon atoms, and (ii) at least two functional groups. The curable waterborne coating compositions of the invention show significantly improved pop resistance while also providing improved chip resistance, weathering resistance, flexibility, and/or scratch & mar resistance.

    Abstract translation: 本发明提供可固化的水性涂料组合物,其包含基于有机粘合剂组分(A1)的总重量的包含至少5重量%的反应性组分(a)的有机粘合剂组分(A1)的水性分散体(A) 和至少一种交联组分(B)。 反应性组分(a)基本上不含任何杂原子,并且在室温下不是结晶固体,并包含(i)12至72个碳原子,和(ii)至少两个官能团。 本发明的可固化水性涂料组合物显示出显着改善的弹性阻力,同时还提供改进的耐碎屑性,耐候性,柔韧性和/或抗划痕性。

    METHOD FOR OBTAINING COATING COMPOSITIONS HAVING REDUCED VOC
    10.
    发明申请
    METHOD FOR OBTAINING COATING COMPOSITIONS HAVING REDUCED VOC 审中-公开
    用于获得具有降低VOC的涂料组合物的方法

    公开(公告)号:WO2005123787A3

    公开(公告)日:2006-05-04

    申请号:PCT/US2005020611

    申请日:2005-06-10

    Abstract: Disclosed is a method of making reduced VOC polymers and coating compositions containing polymers. Provided is a mixture (I) comprising a reactant mixture (a) of polymerizable components and a nonvolatile solvent (bnv) that (i) is not a crystalline solid at 25°C, (ii) is nonvolatile, (iii) comprises at least one functional group (F1) and (iv) is a fluid solid. Reactant mixture (a) is polymerized to provide a polymer (a'). At least one functional group (F1) of nonvolatile solvent (bnv) is reacted with one or more reactants (e) to obtain a nonvolatile solvent (b'nv) comprising at least two functional groups (F2). Obtained is a mixture (II) comprising polymer (a') in nonvolatile solvent (b'nv) comprising at least two functional groups (F2). The at least one functional group (F1) is substantially nonreactive: (1) with the components of reactive mixture (a), (2) under the polymerization conditions which polymerize reactant mixture (a), and (3) with polymer (a').

    Abstract translation: 公开了一种制备含有聚合物的VOC聚合物和涂料组合物的方法。 提供了包含可聚合组分的反应物混合物(a)和不挥发性溶剂(bnv)的混合物(I),(i)在25℃下不是结晶固体,(ii)是非挥发性的,(iii)至少包含 一个官能团(F1)和(iv)是流体固体。 将反应物混合物(a)聚合以提供聚合物(a')。 将不挥发性溶剂(bnv)的至少一个官能团(F1)与一种或多种反应物(e)反应,得到包含至少两个官能团(F2)的非挥发性溶剂(b'nv)。 获得的是包含至少两个官能团(F2)的非挥发性溶剂(b'nv)中的聚合物(a')的混合物(II)。 至少一个官能团(F1)基本上是非反应性的:(1)在反应混合物(a)和(3)与聚合物(a')聚合的聚合条件下,反应混合物(a),(2) )。

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