Abstract:
Provided are exhaust systems and components suitable for use in conjunction with gasoline engines to capture particulates in addition to reducing gaseous emission such as hydrocarbons, nitrogen oxides, and carbon monoxides. Exhaust treatment systems comprising a three-way conversion (TWC) catalyst located on a particulate filters are provided. Coated particle filters having washcoat loadings in the range of 1 to 4 g/ft result in minimal impact on back pressure while simultaneously providing TWC catalytic activity and particle trapping functionality to meet increasingly stringent regulations such as Euro 6, Sufficient to high levels of oxygen storage components (OSC) are also delivered on and/or within the filter. The filters can have a coated porosity that is substantially the same as its uncoated porosity. The TWC catalytic material can comprise a particle size distribution such that a first set of particles has a first d90 particle size of 7.5 µ?? or less and a second set of particles has a second d90 particle size of more than 7.5 µ??. Methods of making and using the same are also provided.
Abstract:
Described is a catalyzed soot filter wherein the inlet coating of the filter comprises an oxidation catalyst comprising platinum (Pt) and optionally palladium (Pd), wherein the outlet coating of the filter comprises an oxidation catalyst comprising Pd and optionally Pt, wherein the Pt concentration in the outlet coating is lower than the Pt concentration in the inlet coating and wherein the weight ratio of Pt:Pd in the outlet coating is in the range of from 0:1 to 2:1; and wherein the inlet coating and the outlet coating are present on the wall flow substrate at a coating loading ratio in the range of from 0.5 to 1.5, calculated as ratio of the loading of the inlet coating (in g/inch3 (g/(2.54 cm)3)):loading of the outlet coating (in g/inch3 (g/(2.54 cm)3)). Systems include such catalyzed soot filters, methods of diesel engine exhaust gas treatment and methods of manufacturing catalyzed soot filters are also described.
Abstract:
Provided are exhaust systems and components suitable for use in conjunction with gasoline engines to capture particulates in addition to reducing gaseous emission such as hydrocarbons, nitrogen oxides, and carbon monoxides. Exhaust treatment systems comprising a three-way conversion (TWC) catalyst located on a particulate filters are provided. Coated particle filters having washcoat loadings in the range of 1 to 4 g/ft result in minimal impact on back pressure while simultaneously providing TWC catalytic activity and particle trapping functionality to meet increasingly stringent regulations such as Euro 6, Sufficient to high levels of oxygen storage components (OSC) are also delivered on and/or within the filter. The filters can have a coated porosity that is substantially the same as its uncoated porosity. The TWC catalytic material can comprise a particle size distribution such that a first set of particles has a first d90 particle size of 7.5 µ?? or less and a second set of particles has a second d90 particle size of more than 7.5 µ??. Methods of making and using the same are also provided.
Abstract:
Described is a process for the preparation of a catalyst comprising the steps of: (i) providing one or more support materials; (ii) providing one or more polymers on the support material; and (iii) providing one or more metals on the one or more supported polymers; wherein in step (ii) the one or more polymers do not comprise cross-linked polymers and/or polymers which have been reacted with a cross-linking agent. Also described is a catalyst obtained or obtainable according to said process, as well as the use of the catalyst, in particular in a method for the treatment of automobile engine exhaust gas.
Abstract:
Provided are catalyst composites whose catalytic material is effective to substantially simultaneously oxidize carbon monoxide and hydrocarbons and reduce nitrogen oxides. The catalyst composites have a two-metal layer on a carrier, the two-metal layer comprising a rhodium component supported by a first support comprising a refractory metal oxide component or a first ceria-zirconia composite; a palladium component supported by a second support comprising a second ceria-zirconia composite; one or more of a promoter, stabilizer, or binder; wherein the amount of the total of the first and second ceria-zirconia composites in the two-metal layer is equal to or greater than the amount of the refractory metal oxide component. Methods of making and using the same are also provided.
Abstract:
composição de moldagem termoplástica, uso das composições de moldagem termoplásticas, e, folha, ou peça de moldagem. um filtro de fusilagem catalisado é fornecido em que seu revestimento de entrada compreende um catalisador de oxidação que compreende platina (pt) e opcionalmente paládio (pd), e seu revestimento de saída compreende um catalisador de oxidação que compreende pd e opcionalmente pt. a concentração de pt no revestimento de saída é menor do que aquela no revestimento de entrada. a razão em peso de pt:pd no revestimento de saída é na faixa de 0:1 a 2:1. o revestimento de entrada e o revestimento de saída estão presentes no substrato de fluxo de parede em uma razão de carga de revestimento na faixa de 0,5 a 1,5 g/polegada ^ 3^ (30,5 a 61kg/cm ^ 3^), calculada como razão da carga do revestimento de entrada (e g/polegada ^ 3^ (1 g/polegada ^ 3^ = 61 kg/(cm)): carga o revestimento de saída (em g/polegada ^ 3^ (1 g/polegada ^ 3^ = 61kg/(cm ^ 3^)).
Abstract:
Un sistema de tratamiento de emisiones corriente abajo de un motor de inyección directa de gasolina para el tratamiento de una corriente de escape que comprende hidrocarburos, monóxido de carbono, óxidos de nitrógeno y material en partículas, donde el sistema de tratamiento de emisiones comprende un filtro de material en partículas catalizado que comprende: un material catalítico de conversión de tres vías (TWC) que está recubierto sobre o dentro de un filtro de material en partículas de flujo de pared que tiene una porosidad no recubierta de al menos 55%; en el que el filtro de material en partículas catalizado tiene una porosidad recubierta que está dentro del 7% de la porosidad no recubierta del filtro de material en partículas, caracterizado porque el filtro de material en partículas tiene una distribución de tamaño de poro con dos picos distintos que tienen un primer tamaño de poro promedio en el intervalo de 10-30 mm y un segundo tamaño de poro promedio en el intervalo de 31-100 mm, y el material catalítico TWC comprende una distribución de tamaño de partícula con dos picos distintos, de manera que un primer conjunto de partículas tiene un primer tamaño de partícula d90 en el intervalo de 1 a 7.5 mm y un segundo conjunto de partículas tiene un segundo tamaño de partícula d90 en el intervalo de 7.6 mm a 100 mm.
Abstract:
Provided are catalyst composites whose catalytic material is effective to substantially simultaneously oxidize carbon monoxide and hydrocarbons and reduce nitrogen oxides. The catalyst composites have a two-metal layer on a carrier, the two-metal layer comprising a rhodium component supported by a first support comprising a refractory metal oxide component or a first ceria-zirconia composite; a palladium component supported by a second support comprising a second ceria-zirconia composite; one or more of a promoter, stabilizer, or binder; wherein the amount of the total of the first and second ceria-zirconia composites in the two-metal layer is equal to or greater than the amount of the refractory metal oxide component. Methods of making and using the same are also provided.
Abstract:
Described is a process for the preparation of a catalyst comprising the steps of: (i) providing one or more support materials; (ii) providing one or more polymers on the support material; and (iii) providing one or more metals on the one or more supported polymers; wherein in step (ii) the one or more polymers do not comprise cross-linked polymers and/or polymers which have been reacted with a cross-linking agent. Also described is a catalyst obtained or obtainable according to said process, as well as the use of the catalyst, in particular in a method for the treatment of automobile engine exhaust gas.