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公开(公告)号：US20250025864A1
公开(公告)日：2025-01-23
申请号：US18713203
申请日：2022-11-29
Applicant: BASF SE
Inventor： Andrei-Nicolae PARVULESCU , Natalia TRUKHAN , Trees Maria DE BAERDEMAEKER , Joaquim Henrique TELES , Jaroslaw Michael MORMUL , Christophe COPERET , Lukas LAETSCH
Abstract: The present invention relates to a catalyst for hydrogen peroxide activation, wherein the catalyst comprises Ti, Si, and O, wherein the catalyst displays a water adsorption (W), a concentration (C) of bridging μ2 η2-peroxo species per Ti in the H2O2-activated catalyst as determined by quantitative 17O NMR spectroscopy, and a specific activation factor (A) according to formula I, wherein in accordance with formula I, the activation factor is the multiplication product of the water adsorption and the concentration of bridging μ2 η2-peroxo species per Ti in the H2O2-activated catalyst: A=W×C (I). The present invention further relates to a method for the preparation of a catalyst molding as well as to a catalyst molding comprising a catalyst for hydrogen peroxide activation obtainable or obtained by said process. Yet further, the present invention relates to a process for the activation of hydrogen peroxide, and to the use of the inventive catalyst or of the inventive catalyst molding in a reaction involving C—C bond formation and/or conversion.
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公开(公告)号：US20240279194A1
公开(公告)日：2024-08-22
申请号：US18569645
申请日：2022-06-14
Applicant: BASF SE , Dow Global Technologies LLC
Inventor： Dominic RIEDEL , Maria Angel SAN PIO BORDEJE , Joaquim Henrique TELES , Andrei-Nicolae PARVULESCU , Dylan SEGERS , Meinolf WEIDENBACH , Franciscus Johannes Robertus VAN NEER , Massimo BERGAMO
IPC: C07D303/04
CPC classification number: C07D303/04
Abstract: In a first aspect, the present invention relates to a shutdown method for a process for preparing an olefin oxide comprising a normal run stage, wherein the normal run stage comprises providing olefin, hydrogen peroxide and organic solvent into an epoxidation zone comprising an heterogeneous epoxidation catalyst, so that a reaction mixture comprising olefin, hydrogen peroxide and organic solvent is formed and subjecting the reaction mixture to epoxidation reaction conditions in the epoxidation zone, thereby obtaining a mixture comprising olefin oxide and organic solvent; wherein the shutdown method comprises (a) providing olefin and organic solvent for a period of time t1 to the epoxidation zone, so that a mixture is formed, which is essentially free of hydrogen peroxide; (b) contacting the mixture from (a) over t1 under epoxidation reaction conditions in the epoxidation zone with the heterogeneous epoxidation catalyst; (c) removing during t1 an effluent stream from the epoxidation zone, the effluent stream comprising olefin and organic solvent. In a second aspect, the present invention relates to a process for preparing an olefin oxide comprising a normal run stage and a shutdown stage, wherein the normal run stage comprises (A) providing olefin, hydrogen peroxide, water and organic solvent into an epoxidation zone comprising an heterogeneous epoxidation catalyst, so that a reaction mixture comprising olefin, hydrogen peroxide, water and organic solvent is formed; (B) subjecting the reaction mixture from (I) to epoxidation reaction conditions in the epoxidation zone, thereby obtaining a mixture comprising olefin oxide, water and organic solvent; (C) removing an effluent stream from the epoxidation zone, comprising olefin oxide, water and organic solvent; wherein the shutdown stage comprises steps (a), (b) and (c) as described with respect to the first aspect.
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公开(公告)号：US20210346942A1
公开(公告)日：2021-11-11
申请号：US17283975
申请日：2019-10-09
Applicant: BASF SE
Inventor： Andrei-Nicolae PARVULESCU , Hans-Juergen LUETZEL , Ulrich MUELLER , Dominic RIEDEL , Joaquim Henrique TELES , Markus WEBER
Abstract: A molding, comprising a zeolitic material having framework type MFI wherein from 98 to 100 weight-% of the zeolitic material consist of Ti, Si, O, and H, and wherein the zeolitic material having framework type MFI exhibits a type IV nitrogen adsorption/desorption isotherm, the molding further comprising a silica binder, wherein the molding has a pore volume of at least 0.8 mL/g.
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公开(公告)号：US20200376472A1
公开(公告)日：2020-12-03
申请号：US16997038
申请日：2020-08-19
Applicant: BASF SE
Inventor： Andrei-Nicolae PARVULESCU , Ulrich MUELLER , Hans-Juergen LUETZEL , Joaquim Henrique TELES , Dominic RIEDEL , Daniel URBANCZYK , Ulrike WEGERLE , Markus WEBER , Nicolai Tonio WOERZ , Christian MUELLER
Abstract: A process for preparing a molding comprising zinc and a titanium-containing zeolitic material having framework type MWW, comprising (i) providing a molding comprising a titanium-containing zeolitic material having framework type MWW; (ii) preparing an aqueous suspension comprising a zinc source and the molding comprising a titanium-containing zeolitic material having framework type MWW prepared in (i); (iii) heating the aqueous suspension prepared in (ii) under autogenous pressure to a temperature of the liquid phase of the aqueous suspension in the range of from 100 to 200° C., obtaining an aqueous suspension comprising a molding comprising zinc and a titanium-containing zeolitic material having framework type MWW; (iv) separating the molding comprising zinc and a titanium-containing zeolitic material having framework type MWW from the liquid phase of the suspension obtained in (iii).
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公开(公告)号：US20200339430A1
公开(公告)日：2020-10-29
申请号：US16330592
申请日：2017-09-05
Applicant: BASF SE
Inventor： Andrei-Nicolae PARVULESCU , Ulrich MUELLER , Stefan MAURER , Yu DAI , Feng-Shou XIAO , Xiangju MENG , Yeqing WANG
IPC: C01B37/00 , B01J20/10 , B01J20/30 , B01J29/86 , B01J37/04 , B01J37/00 , B01J37/03 , B01J37/08 , B01J37/06 , B01J37/30 , B01J37/02
Abstract: Described herein is a process for producing a zeolitic material having an MWW framework structure containing YO2 and B2O3, in which Y stands for a tetravalent element. The process includes the steps of (i) preparing a mixture containing one or more sources for YO2, one or more sources for B2O3, one or more organotemplates, and seed crystals, (ii) crystallizing the mixture obtained in (i) for obtaining a layered precursor of the MWW framework structure, and (iii) calcining the layered precursor obtained in (ii) for obtaining the zeolitic material having an MWW framework structure. Also disclosed herein are synthetic boron-containing zeolites obtain by the process and uses thereof.
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Patent Agency Ranking
公开(公告)号：US20200308083A1
公开(公告)日：2020-10-01
申请号：US16765620
申请日：2018-12-20
Applicant: BASF SE
Inventor： Robert MCGUIRE , Andrei-Nicolae PARVULESCU , Ulrich MUELLER , Dirk DE VOS , Patrick TOMKINS
Abstract: Disclosed is a process for the alkylation of an aliphatic organic compound comprising: (a) providing a catalyst comprising one or more zeolitic materials having a BEA framework structure, wherein the BEA framework structure comprises YO2 and optionally comprises X2O3, wherein Y is a tetravalent element, and X is a trivalent element, (b) contacting the catalyst with one or more aliphatic organic compounds in the presence of one or more alkylating agents in one or more reactors for obtaining one or more alkylated organic compounds, wherein the one or more zeolitic materials are obtainable from a synthetic process which does not employ an organotemplate as structure directing agent.
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公开(公告)号：US20200283304A1
公开(公告)日：2020-09-10
申请号：US16759491
申请日：2018-11-22
Applicant: BASF SE
Inventor： Christian RIEMANN , Andrei-Nicolae PARVULESCU , Ralf BOEHLING , Ulrich MUELLER , Hans-Juergen LUETZEL , Stefanie CLADE , Christoph SCHAPPERT
Abstract: The present invention relates to a process for the preparation of a zeolitic material, as well as to a catalyst per se as obtainable or obtained according to said process. Furthermore, the present invention relates to the use of the zeolitic material, in particular as a catalyst.
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公开(公告)号：US20190389794A1
公开(公告)日：2019-12-26
申请号：US16464894
申请日：2017-11-29
Applicant: BASF SE
Inventor： Andrei-Nicolae PARVULESCU , Alvaro GORDILLO , Marie Katrin SCHROETER , Johann-Peter MELDER , Juergen BECHTEL , Thomas HEIDEMANN , Stephan A. SCHUNK , Ulrich MÜLLER
Abstract: The present invention relates to a process for the conversion of 2-aminoethanol to ethane-1,2-diamine and/or linear polyethylenimines of the formula H2N—[CH2CH2NH]n—CH2CH2NH2 wherein n≥1 comprising: (i) providing a catalyst comprising a zeolitic material having the MOR framework structure comprising YO2 and X2O3, wherein Y is a tetravalent element and X is a trivalent element, said zeolitic material containing copper as extra-framework ions; (ii) providing a gas stream comprising 2-aminoethanol and ammonia; (iii) contacting the catalyst provided in (i) with the gas stream provided in (ii) for converting 2-aminoethanol to ethane-1,2-diamine and/or linear polyethylenimines.
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公开(公告)号：US20180362353A1
公开(公告)日：2018-12-20
申请号：US16060260
申请日：2016-12-07
Applicant: BASF SE
Inventor： NIcolas VAUTRAVERS , Joaquim Henrique TELES , Ralf PELZER , Daniel SCHNEIDER , Florian GARLICHS , Andreas KELLER , Andrei-Nicolae PARVULESCU , Ulrich MÜLLER , Sumana ROY
Abstract: An incipient wetness impregnation method for preparing a tin-containing zeolitic material having framework type BEA, a novel tin-containing zeolitic material having framework type BEA and its use.
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公开(公告)号：US20180170850A1
公开(公告)日：2018-06-21
申请号：US15571107
申请日：2016-05-04
Applicant: BASF SE
Inventor： Nicolas VAUTRAVERS , Joaquim TELES , Ralf PELZER , Daniel SCHNEIDER , Florian GARLICHS , Andreas KELLER , Andrei-Nicolae PARVULESCU , Ulrich MÜLLER
Abstract: A process for preparing 2,6-dimethyl-5-heptenal, comprising oxidizing citral of which more than 50% are present as geranial with hydrogen peroxide in the presence of a catalyst comprising a Baeyer-Villiger oxidation catalyst, preferably a tin-containing molecular sieve.
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