Process for preparation of benzylic amides

    公开(公告)号:US10961213B2

    公开(公告)日:2021-03-30

    申请号:US16480407

    申请日:2018-01-16

    Applicant: BASF SE

    Abstract: The present invention relates to a process for preparing benzylic amides of formula I wherein the variables have the meaning as defined in the description, by reductive amidation of a nitrile of formula II wherein the variables have the meanings given for formula I, with an activated carbonyl compound of formula III, and which nitrile is obtained by reaction of a compound of formula IV with a halogen compound of formula V, wherein X is a halogen atom, preferably bromo, which halogen compound V in turn is obtained by Sandmeyer reaction of an aniline derivative of formula VI novel compounds of formula I, and processes for preparing compounds of formula XII wherein the variables have the meaning as defined in the description by condensing compounds of formula I with compounds of formula X and subjecting the resulting α,β-unsaturated ketone of formula XI to a reaction with hydroxylamine to yield compounds of formula XII.

    PESTICIDAL COMPOUNDS
    6.
    发明公开

    公开(公告)号:US20230157287A1

    公开(公告)日:2023-05-25

    申请号:US17920786

    申请日:2021-04-23

    Applicant: BASF SE

    CPC classification number: A01N43/40 A01N43/54 A01N43/58

    Abstract: The present application relates to the compounds of formula (I), and the N-oxides, stereoisomers, tautomers and agriculturally or veterinarily acceptable salts thereof wherein the variables are defined in the claims. The compounds of formula (I), as well as the N-oxides, stereoisomers tautomers and agriculturally or veterinarily acceptable salts thereof are useful for combating or controlling invertebrate pests, in particular arthropod pests and nematodes. The application also relates to a method for controlling invertebrate pests by using these compounds and to plant propagation material and to an agricultural and a veterinary composition comprising said compounds.

    Pesticidal compounds
    7.
    发明授权

    公开(公告)号:US11512054B2

    公开(公告)日:2022-11-29

    申请号:US16772286

    申请日:2018-12-11

    Applicant: BASF SE

    Abstract: The present invention relates to the compounds of formula (I), and the N-oxides, stereoisomers, tautomers and agriculturally or veterinarily acceptable salts thereof wherein the variables are defined according to the description, formula (I). The compounds of formula (I), as well as the N-oxides, stereoisomers, tautomers and agriculturally or veterinarily acceptable salts thereof, are useful for combating or controlling invertebrate pests, in particular arthropod pests and nematodes. The invention also relates to a method for controlling invertebrate pests by using these compounds and to plant propagation material and to an agricultural and a veterinary composition comprising said compounds.

    N-Thio-anthranilamide compounds and their use as pesticides
    9.
    发明申请
    N-Thio-anthranilamide compounds and their use as pesticides 有权
    N-硫代邻氨基苯甲酰胺化合物及其作为农药的用途

    公开(公告)号:US20150141243A1

    公开(公告)日:2015-05-21

    申请号:US14402509

    申请日:2013-05-07

    Applicant: BASF SE

    Abstract: The present invention relates to N-thioanthranilamide compounds of formula (I), and the stereoisomers, N-oxides and agriculturally or veterinarily acceptable salts thereof, wherein the substituents are as defined in the description.The present invention further relates to a method for combating or controlling invertebrate pests, to a method for protecting plant propagation material and/or the plants which grow therefrom, to plant propagation material comprising at least one compound according to the present invention, to a method for treating or protecting an animal from infestation or infection by parasites, to a process for the preparation of a composition for treating infested or infected animals and/or for protecting animals against infestation or infection by parasites, and to a compound according to the invention for use as a medicament.

    Abstract translation: 本发明涉及式(I)的N-硫代鸟氨酰胺化合物及其立体异构体N-氧化物及其农业或兽医学上可接受的盐,其中取代基如说明书中所定义。 本发明还涉及一种防治无脊椎害虫的方法,一种用于保护植物繁殖材料和/或从其生长的植物的方法,包括至少一种根据本发明的化合物的植物繁殖材料的方法, 用于治疗或保护动物免受寄生虫感染或感染,涉及制备用于治疗感染或感染的动物和/或保护动物免受寄生虫感染或感染的组合物的方法,以及根据本发明的化合物 用作药物。

    N-substituted hetero-bicyclic compounds and derivatives for combating animal pests II
    10.
    发明申请
    N-substituted hetero-bicyclic compounds and derivatives for combating animal pests II 有权
    N-取代杂双环化合物及其对抗动物害虫的衍生物II

    公开(公告)号:US20150105405A1

    公开(公告)日:2015-04-16

    申请号:US14387600

    申请日:2013-03-25

    Applicant: BASF SE

    CPC classification number: C07D471/04 A01N43/90 C07D487/04

    Abstract: The invention relates to N-substituted hetero-bicyclic compounds of formula (I), to the enantiomers, diastereomers and salts thereof and to compositions comprising such compounds. The invention also relates to methods and uses of these N-substituted hetero-bicyclic compounds, and of compositions comprising thereof, for combating and controlling animal pests. Furthermore the invention relates also to pesticidal methods of applying such N-substituted hetero-bicyclic compounds.The N-substituted hetero-bicyclic compounds of the present invention are defined by the following formula I: wherein A, B, X, Het, R1, R2, W1, W2, W3 and W4 are defined as in the description.

    Abstract translation: 本发明涉及式(I)的N-取代杂双环化合物,其对映异构体,非对映异构体和盐以及包含这些化合物的组合物。 本发明还涉及这些N-取代的杂双环化合物及其组合物的方法和用途,用于对抗和控制动物害虫。 此外,本发明还涉及施用这种N-取代的杂双环化合物的杀虫方法。 本发明的N-取代杂双环化合物由下式I定义:其中A,B,X,Het,R 1,R 2,W 1,W 2,W 3和W 4如在说明书中所定义。

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