公开(公告)号：WO2014167014A1

公开(公告)日：2014-10-16

申请号：PCT/EP2014/057181

申请日：2014-04-09

Applicant: BASF SE

Inventor： BÖRNER, Armin ,  HOLZ, Jens

IPC: C07C45/62

CPC classification number: C07C45/62 ,  C07C47/21

Abstract: Die vorliegende Erfindung betrifft ein Verfahren zur Herstellung von Citronellal durch homogene Rh-katalysierte Hydrierung von Neral und/oder Geranial.

Abstract translation: 本发明涉及一种通过橙花醛和/或香叶的均相铑催化氢化制备香茅醛的方法。

公开(公告)号：EP2057109A2

公开(公告)日：2009-05-13

申请号：EP07821593.6

申请日：2007-10-19

Applicant: BASF SE

Inventor： RUDOLPH, Jens ,  PACIELLO, Rocco ,  JÄKEL, Christoph ,  HETTCHE, Frank ,  BÖRNER, Armin ,  DUBROVINA, Natalia ,  BIRKHOLZ, Mandy-Nicole ,  BREIT, Bernhard

IPC: C07B37/02 ,  C07C29/16 ,  C07C45/50 ,  B01J31/18 ,  C07D211/76

CPC classification number: C07C45/50 ,  B01J31/1845 ,  B01J31/2409 ,  B01J31/2438 ,  B01J31/2452 ,  B01J31/2466 ,  B01J31/2471 ,  B01J2231/32 ,  B01J2231/321 ,  B01J2231/323 ,  B01J2231/325 ,  B01J2231/326 ,  B01J2231/342 ,  B01J2231/44 ,  B01J2231/52 ,  B01J2231/543 ,  B01J2231/645 ,  B01J2531/0266 ,  B01J2531/0291 ,  B01J2531/821 ,  B01J2531/822 ,  B01J2531/842 ,  B01J2531/847 ,  B01J2531/94 ,  C07B53/00 ,  C07B2200/07 ,  C07C45/505 ,  C07C45/72 ,  C07C67/303 ,  C07C231/12 ,  C07F9/65683 ,  C07F15/0073 ,  C07C69/34 ,  C07C233/47

Abstract: The present invention relates to a method for reacting compounds, comprising at least one carbon-carbon or carbon-heteroatom double bond, by 1,2-addition in the presence of a catalyst, comprising at least one transition metal complex having at least two ligands, which each have a pnicogen atom-containing group and at least one functional group enable to form intermolecular, non-covalent bonds, in the presence of a halogenated solvent, which has at least one heteroatom different from halogen. The present invention further relates to a method for producing chiral compounds in the presence of the above-described catalysts and solvents, and to the use of these catalysts in the presence of such solvents.