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    POLYMERIC HAIR DYES
    1.
    发明申请
    POLYMERIC HAIR DYES 审中-公开
    聚合物染发剂

    公开(公告)号：WO2011006946A3

    公开(公告)日：2011-03-31

    申请号：PCT/EP2010060175

    申请日：2010-07-15

    Applicant: BASF SE ,  CREMER CHRISTIAN ,  BECHERER OLIVER ,  FROEHLING BEATE

    Inventor： CREMER CHRISTIAN ,  BECHERER OLIVER ,  FROEHLING BEATE

    IPC: C09B26/04 ,  A61Q5/00 ,  C09B69/10

    CPC classification number: C09B26/04 ,  A61K8/84 ,  A61K2800/4324 ,  A61Q5/10 ,  C09B69/109

    Abstract: Disclosed are polymeric dyes of formula (1a), (1b), or (1c); wherein A and B, independently from each other represent a polymer backbone; X1 and X2 independently from each other are a linkage group selected from -S-, -S-S-, -N-, - N=-, -N(R5)-, -S(O)-, -SO2-, -(CH2CH2-O)1-5-, -(CH2CH2CH2-O)1-5-, -C(O)-, -C(O)O-,-OCO-, (formula II) -CON(R1)-, -C(NR1R2)2-, -(R1)NC(O)-, -C(S)R1-; which may be interrupted and/or terminated at one or both ends by one or more than one -C1C30alkylene- or -C2-C12alkenylene-; or an optionally substituted, saturated or unsaturated, fused or non-fused aromatic or nonaromatic (heterocyclic) bivalent radical optionally comprising at least one heteroatom; a saturated or unsaturated, fused or non-fused aromatic or nonaromatic bivalent radical comprising at least one heteroatom, which is optionally substituted by C1-C30alkyl, C1-C30alkoxy, C2-C12alkenyl, C5-C10aryl, C5-C10cycloalkyl, C1- C10alkyl(C5-C10arylene), hydroxy or halogen; R1 and R2 independently from each other are hydrogen; unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted C1- C14alkyl; C2-C14alkenyl; C6-C10aryl; C6-C10aryl- C1-C10alkyl; or C5-C10alkyl(C5-C10aryl); Y1 and Y2 independently from each other are a residue of an organic dye selected from hydrazone dyes of formula (1d), wherein Z1, Z2 and Z3, independently from each other are -CR8- or -NR9+-; and at least one of Z1, Z2 or Z3 is -NR9+-; wherein at least one of Y1 and Y2 is a residue of an organic dye; R, R3, R4, R5, R6, R7, R8 and R9 independently from each other are hydrogen; hydroxy; C1- C5alkyl; hydroxy-C1C5alkyl; C1C5alkoxy; -NO2; -Cl; -Br; -COOH; -SO3H; -CN; NH2; or CH3-CO-NH-; An1, An2 and An3, independently from each other are an anion; a and b independently from each other are a number from 1 to 3; m is a number from 0 to 5000; n is a number from 0 to 5000; and p is a number from 1 to 5000; wherein the sum of m + n + p = 3. The dyes are distinguished by their depth of shade and their good fastness properties to washing, such as, for example, fastness to light, shampooing and rubbing.

    Abstract translation: 公开了式（1a），（1b）或（1c）的聚合染料; 其中A和B彼此独立地表示聚合物主链; X1和X2彼此独立地是选自-S - ， - S - ， - N - ， - N = - ， - N（R5） - ， - S（O） - ， - SO2-， - （ CH 2 CH 2 -O）1-5 - ， - （CH 2 CH 2 CH 2 -O）1-5 - ， - C（O） - ， - C（O）O - ， - OCO-，（式II）-CON -C（NR 1 R 2）2 - ， - （R 1）NC（O） - ， - C（S） 其可以在一个或两个末端被一个或多于一个-C 1 -C 30亚烷基 - 或-C 2 -C 12亚烯基 - 或任选包含至少一个杂原子的任选取代的，饱和或不饱和的稠合或非稠合芳族或非芳族（杂环）二价基团; 饱和或不饱和的，稠合或非稠合的芳族或非芳族二价基团，其包含至少一个杂原子，其任选被C 1 -C 30烷基，C 1 -C 30烷氧基，C 2 -C 12烯基，C 5 -C 10芳基，C 5 -C 10环烷基，C 1 -C 10烷基 C5-C10亚芳基），羟基或卤素; R1和R2彼此独立地是氢; 未取代或取代的直链或支链，单环或多环，中断或不间断C 1 -C 14烷基; C2-C14alkenyl; C6-C10芳基; C 6 -C 10芳基-C 1 -C 10烷基; 或C 5 -C 10烷基（C 5 -C 10芳基）; Y1和Y2彼此独立地是选自式（1d）的腙染料的有机染料的残基，其中Z 1，Z 2和Z 3彼此独立地是-CR 8 - 或-NR 9 + - ; 并且Z 1，Z 2或Z 3中的至少一个为-NR 9 +。 其中Y 1和Y 2中的至少一个是有机染料的残基; R，R 3，R 4，R 5，R 6，R 7，R 8和R 9彼此独立地为氢; 羟基; C 1-5烷基; 羟基C1C5alkyl; C1C5alkoxy; NO 2; -Cl; -Br; -COOH; -SO3H; -CN; NH2; 或CH 3 -CO-NH-; An1，An2和An3彼此独立地为阴离子; a和b彼此独立，为1-3; m是从0到5000的数字; n是从0到5000的数字; p是从1到5000的数字; 其中m + n + p = 3的总和。这些染料的特征在于它们的色调深度和它们对洗涤的良好牢度性质，例如，耐光牢度，洗发剂和摩擦性。

    POLYMERIC HAIR DYES
    2.
    发明申请
    POLYMERIC HAIR DYES 审中-公开
    聚合物染发剂

    公开(公告)号：WO2011006946A2

    公开(公告)日：2011-01-20

    申请号：PCT/EP2010060175

    申请日：2010-07-15

    Applicant: BASF SE ,  CREMER CHRISTIAN ,  BECHERER OLIVER ,  FROEHLING BEATE

    Inventor： CREMER CHRISTIAN ,  BECHERER OLIVER ,  FROEHLING BEATE

    IPC: C09B26/04 ,  A61Q5/00 ,  C09B69/10

    CPC classification number: C09B26/04 ,  A61K8/84 ,  A61K2800/4324 ,  A61Q5/10 ,  C09B69/109

    Abstract: Disclosed are polymeric dyes of formula (1a), (1b), or (1c); wherein A and B, independently from each other represent a polymer backbone; X1 and X2 independently from each other are a linkage group selected from -S-, -S-S-, -N-, - N=-, -N(R5)-, -S(O)-, -SO2-, -(CH2CH2-O)1-5-, -(CH2CH2CH2-O)1-5-, -C(O)-, -C(O)O-,-OCO-, (formula II) -CON(R1)-, -C(NR1R2)2-, -(R1)NC(O)-, -C(S)R1-; which may be interrupted and/or terminated at one or both ends by one or more than one -C1C30alkylene- or -C2-C12alkenylene-; or an optionally substituted, saturated or unsaturated, fused or non-fused aromatic or nonaromatic (heterocyclic) bivalent radical optionally comprising at least one heteroatom; a saturated or unsaturated, fused or non-fused aromatic or nonaromatic bivalent radical comprising at least one heteroatom, which is optionally substituted by C1-C30alkyl, C1-C30alkoxy, C2-C12alkenyl, C5-C10aryl, C5-C10cycloalkyl, C1- C10alkyl(C5-C10arylene), hydroxy or halogen; R1 and R2 independently from each other are hydrogen; unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted C1- C14alkyl; C2-C14alkenyl; C6-C10aryl; C6-C10aryl- C1-C10alkyl; or C5-C10alkyl(C5-C10aryl); Y1 and Y2 independently from each other are a residue of an organic dye selected from hydrazone dyes of formula (1d), wherein Z1, Z2 and Z3, independently from each other are -CR8- or -NR9+-; and at least one of Z1, Z2 or Z3 is -NR9+-; wherein at least one of Y1 and Y2 is a residue of an organic dye; R, R3, R4, R5, R6, R7, R8 and R9 independently from each other are hydrogen; hydroxy; C1- C5alkyl; hydroxy-C1C5alkyl; C1C5alkoxy; -NO2; -Cl; -Br; -COOH; -SO3H; -CN; NH2; or CH3-CO-NH-; An1, An2 and An3, independently from each other are an anion; a and b independently from each other are a number from 1 to 3; m is a number from 0 to 5000; n is a number from 0 to 5000; and p is a number from 1 to 5000; wherein the sum of m + n + p = 3. The dyes are distinguished by their depth of shade and their good fastness properties to washing, such as, for example, fastness to light, shampooing and rubbing.

    Abstract translation: 公开了式（1a），（1b）或（1c）的聚合物染料; 其中A和B彼此独立地表示聚合物骨架; X1和X2彼此独立地为选自-S - ， - SS - ， - N - ， - N = - ， - N（R5） - ， - S（O） - ， - SO2 - ， - （O） - ， - C（O）O - ， - OCO-，（式II）-CON（R 1） - ， -C（NR 1 R 2）2 - ， - （R 1）NC（O） - ， - C（S）R 1 - 其可以在一个或两个末端被一个或多个-C 1 -C 30亚烷基 - 或-C 2 -C 12亚烯基中断和/或终止; 或任选地包含至少一个杂原子的任选取代的饱和或不饱和的稠合或非稠合的芳族或非芳族（杂环）二价基团; 包含至少一个任选被C 1 -C 30烷基，C 1 -C 30烷氧基，C 2 -C 12烯基，C 5 -C 10芳基，C 5 -C 10环烷基，C 1 -C 10烷基（C 1 -C 10）烷基， C5-C10亚芳基），羟基或卤素; R1和R2彼此独立地为氢; 未取代或取代的直链或支链，单环或多环，间断或不间断的C 1 -C 14烷基; C2-C14alkenyl; C6-C10芳基; C 6 -C 10芳基-C 1 -C 10烷基; 或C 5 -C 10烷基（C 5 -C 10芳基）; 其中Z 1，Z 2和Z 3彼此独立地是-CR 8 - 或-NR 9 - ; - 并且Z 1，Z 2或Z 3中的至少一个是-NR 9 + - ; 其中Y 1和Y 2中的至少一个是有机染料的残基; R，R 3，R 4，R 5，R 6，R 7，R 8和R 9彼此独立地为氢; 羟基; C1-C5烷基; 羟基C1C5alkyl; C1C5alkoxy; NO 2; -Cl; -Br; -COOH; -SO3H; -CN; NH2; 或CH 3 -CO-NH-; An1，An2和An3彼此独立地是阴离子; a和b彼此独立地是1至3的数字; m是从0到5000的数字; n是从0到5000的数字; p是1至5000的数字; 其中m + n + p = 3的总和。染料的特征在于它们的色调深度和它们对洗涤的良好牢度性质，例如耐光性，洗发和摩擦。

    6.
    发明专利
    未知

    公开(公告)号：AT550416T

    公开(公告)日：2012-04-15

    申请号：AT06763545

    申请日：2006-06-07

    Applicant: BASF SE

    Inventor： HOCHBERG ROBERT ,  BECHERER OLIVER ,  SCHULTZ BERNARD ,  SCHEFFLER GOETZ ,  SCHLATTER RENE

    IPC: C11D3/37 ,  C07D251/68 ,  C11D3/22 ,  C11D3/34 ,  C11D3/42 ,  D06L4/75 ,  D06M13/358

    Abstract: The present invention relates to the use of a combination of a free fluorescent whitening agent and cationic polymer as a brightening agent for a synthetic single or blended textile, especially polyester textile, and to a corresponding brightening agent as well as a laundering process for brightening a synthetic, single or blended textile, which is characterized by a) preparing a composition by contacting a free fluorescent whitening agent with a cationic polymer, and b) treating said synthetic, single or blended textile with the composition prepared in step a).

    Colorantes capilares poliméricos
    8.
    发明专利
    Colorantes capilares poliméricos 未知

    公开(公告)号：ES2436469T3

    公开(公告)日：2014-01-02

    申请号：ES10732373

    申请日：2010-07-15

    Applicant: BASF SE

    Inventor： CREMER CHRISTIAN ,  BECHERER OLIVER ,  FROEHLING BEATE

    IPC: C09B26/04 ,  A61Q5/00 ,  C09B69/10

    Abstract: Colorante polimérico de fórmula **Fórmula** o **Fórmula** en las que A y B, representan independientemente el uno del otro un esqueleto de polímero; X1 y X2 son independientemente el uno del otro un grupo de unión seleccionado entre -S-, -S-S-, -N-, -N>=-, -N(R5)-, -S(O) -, -SO2-, -(CH2CH2-O)1-5-, -(CH2CH2CH2-O)1-5-, -C(O) -, -C(O)O-, -OCO-, -CON(R1)-, -C(NR1R2)2-, -(R1)NC(O)-, -C(S)R1-; que pueden estar interrumpidos y/o terminados en uno o ambosextremos con uno o más de un -alquileno C1-C30- o -alquenileno C2-C12-; o un radical divalente (heterocíclico)aromático o no aromático, condensado o no condensado, saturado o insaturado, opcionalmente sustituido quecomprende opcionalmente al menos un heteroátomo; un radical divalente aromático o no aromático, condensadoo no condensado, saturado o insaturado que comprende al menos un heteroátomo, que está opcionalmentesustituido con alquilo C1-C30, alcoxi C1-C30, alquenilo C2-C12, arilo C5-C10, cicloalquilo C5-C10, alquilo C1-C10(arileno C5-C10), hidroxi o halógeno; R1 y R2 son independientemente el uno del otro hidrógeno; alquilo C1-C14 interrumpido o no interrumpido,monocíclico o policíclico, de cadena lineal o ramificado, sin sustituir o sustituido; alquenilo C2-C14; arilo C6-C10;arilo C6-C10-alquilo C1-C10; o alquilo C5-C10 (arilo C5-C10); Y1 e Y2 son independientemente el uno del otro un residuo de un colorante orgánico seleccionado entrecolorantes de hidrazona de fórmula.

    10.
    发明专利
    未知

    公开(公告)号：AT483011T

    公开(公告)日：2010-10-15

    申请号：AT07729075

    申请日：2007-05-14

    Applicant: BASF SE

    Inventor： BECHERER OLIVER ,  HOCHBERG ROBERT ,  MERKLE GERHARD ,  SCHULTZ BERNARD ,  CHANDAK PURUSHOTTAM JUGALKISHOR

    IPC: C11D3/42 ,  D06L4/40

    Abstract: A detergent composition comprising i) 1-70% of an anionic or nonionic surfactant, ii) 1-75% of a builder, iii) 0.001-5% of at least one compound of Formula (1) wherein R represents a C1-C4alkyl residue and M represents hydrogen or an alkali metal cation, optionally with further FWA's, iv) 0-30% of a peroxide, v) 0-10% of a peroxide activator, vi) 0-5% of a bleaching catalyst and vii) 0-5% of an enzyme, each component by weight, based on the total weight of the detergent composition, use thereof for domestic washing of textile fibre materials and a process for the fluorescent whitening of textile materials.

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