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公开(公告)号:JP2008169221A
公开(公告)日:2008-07-24
申请号:JP2008035865
申请日:2008-02-18
Applicant: Basf Se , ビーエーエスエフ ソシエタス・ヨーロピアBasf Se
Inventor: BECKER RAINER , ELLER KARSTEN DR , LANGENSIEPEN HANS-WERNER DR , HESSE MICHAEL DR
IPC: C07C209/54 , C07C211/51 , A61K9/12 , B01J21/16 , C07B61/00 , C07C209/68 , C07C209/78 , C07C211/49 , C07C211/50 , C07C211/54
CPC classification number: C07C209/54 , B01J21/16 , C07C209/78 , C07C211/50 , C07C211/54
Abstract: PROBLEM TO BE SOLVED: To provide a catalyst having excellent characteristics, and to provide a production method of an aromatic polyamine mixture.
SOLUTION: The production method of an aromatic polyamine mixture comprises, for producing aromatic polyamine mixtures containing the compound of formula (I), reacting a compound of formula (IV) and/or a compound of formula (V) at 20-200°C in the presence of a heterogeneous inorganic catalyst selected from the following groups: (b) montmorillonite which is doped with at least one element of group 2, group 3, group 4, group 7 or group 13 or an oxide of lanthanide and may be acid-activated and (c) one or more sheet silicates having an acidity of ≥0.05 mmol/catalyst g at
p K
a =1.5 and selected from the group consisting of montmorillonite and sepiolite (these may be acid-activated) and attapulgite. Formula (I): H
2 N-A-CH
2 -B-NH
2 . Formula (IV): H-A-NH-CH
2 -HN-B-H. Formula (V): H-A-NH-CH
2 -B-NH
2 (Wherein, A and B are each independently a 1-4C phenylene group which may have 1-4 substituents selected from a 1-20C alkyl group and a halogen).
COPYRIGHT: (C)2008,JPO&INPITAbstract translation: 要解决的问题:提供具有优异特性的催化剂,并提供芳族多胺混合物的制备方法。 解决方案:芳族多胺混合物的制备方法包括,为了制备含有式(I)化合物的芳族多胺混合物,使式(IV)化合物和/或式(Ⅴ)化合物在20- 在选自以下组的非均相无机催化剂存在下,在200℃:(b)掺杂有第2族,第3族,第4族,第7族或第13族的至少一种元素的蒙脱石或镧系元素的氧化物, 可以被酸活化,和(c)一种或多种酸度为≥0.05mmol/催化剂g的片状硅酸盐,其选自以下组: 的蒙脱石和海泡石(这些可能是酸活化的)和绿坡缕石。 式(I):H-SB 2 N-A-CH
-B-NH SB 2。 式(IV):H-A-NH-CH 2 -SH-B-H。 式(Ⅴ):其中,A和B各自独立地为1-4C亚苯基,其可以具有1- 4个选自1-20C烷基和卤素的取代基)。 版权所有(C)2008,JPO&INPIT -
公开(公告)号:DE50312664D1
公开(公告)日:2010-06-10
申请号:DE50312664
申请日:2003-02-26
Applicant: BASF SE
Inventor: GUEMBEL HELMUT , KNEUPER HEINZ-JOSEF , BECKER RAINER , BERTLEIN GERHARD , DROEGEMUELLER MICHAEL
IPC: C07D251/54 , A61K8/00 , A61K8/49 , A61Q17/04 , C07D251/70
Abstract: Process for the preparation of the tautomeric form I of 2,4,6-trianilino-p-(carbo-2'-ethylhexyl-1'-oxy)-1,3,5-triazine by crystallization from a tautomer mixture in the presence of one or more solvents chosen from the group consisting of aliphatic alcohols having 2 to 8 carbon atoms, aliphatic carboxylic alkyl esters having a total of 3 to 10 carbon atoms, aromatic carboxylic alkyl esters having a total of 8 to 12 carbon atoms, aliphatic carbonic esters having a total of 3 to 9 carbon atoms, carbonitriles having a total of 2 to 8 carbon atoms, dialkyl ketones having a total of 3 to 6 carbon atoms and aliphatic sulfones having a total of 3 to 6 carbon atoms, where the solvent or the solvent mixture may additionally comprise up to 30% by weight of a hydrocarbon. I is used as light protection agent in cosmetic preparations.
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公开(公告)号:AT466001T
公开(公告)日:2010-05-15
申请号:AT03743330
申请日:2003-02-26
Applicant: BASF SE
Inventor: GUEMBEL HELMUT , KNEUPER HEINZ-JOSEF , BECKER RAINER , BERTLEIN GERHARD , DROEGEMUELLER MICHAEL
IPC: C07D251/54 , A61K8/00 , A61K8/49 , A61Q17/04 , C07D251/70
Abstract: Process for the preparation of the tautomeric form I of 2,4,6-trianilino-p-(carbo-2'-ethylhexyl-1'-oxy)-1,3,5-triazine by crystallization from a tautomer mixture in the presence of one or more solvents chosen from the group consisting of aliphatic alcohols having 2 to 8 carbon atoms, aliphatic carboxylic alkyl esters having a total of 3 to 10 carbon atoms, aromatic carboxylic alkyl esters having a total of 8 to 12 carbon atoms, aliphatic carbonic esters having a total of 3 to 9 carbon atoms, carbonitriles having a total of 2 to 8 carbon atoms, dialkyl ketones having a total of 3 to 6 carbon atoms and aliphatic sulfones having a total of 3 to 6 carbon atoms, where the solvent or the solvent mixture may additionally comprise up to 30% by weight of a hydrocarbon. I is used as light protection agent in cosmetic preparations.
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公开(公告)号:ES2343406T3
公开(公告)日:2010-07-30
申请号:ES03743330
申请日:2003-02-26
Applicant: BASF SE
Inventor: GUMBEL HELMUT , KNEUPER HEINZ-JOSEF , BECKER RAINER , BERTLEIN GERHARD , DROGEMULLER MICHAEL
IPC: C07D251/54 , A61K8/00 , A61K8/49 , A61Q17/04 , C07D251/70
Abstract: Procedimiento para la obtención de la forma tautómera I de 2,4,6-trianilino-p-(carbo-2''-etilhexil-1''-oxi)-1,3,5-triazina **(Ver fórmula)** mediante cristalización a partir de una mezcla de tautómeros en presencia de uno o varios disolventes, seleccionados a partir del grupo constituido por alcoholes alifáticos con 2 a 8 átomos de carbono, carboxilatos de alquilo alifáticos con un total de 3 a 10 átomos de carbono, carboxilatos de alquilo aromáticos con un total de 8 a 12 átomos de carbono, carbonatos alifáticos con un total de 3 a 9 átomos de carbono, nitrilos de ácido carboxílico con un total de 2 a 8 átomos de carbono, dialquilcetonas con un total de 3 a 6 átomos de carbono, y sulfonas alifáticas con un total de 3 a 6 átomos de carbono, pudiendo contener el disolvente o la mezcla de disolventes adicionalmente hasta un 30% en peso de un hidrocarburo.
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