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    POLYCYCLIC DITHIOPHENES
    1.
    发明申请
    POLYCYCLIC DITHIOPHENES 审中-公开
    多环十二烷

    公开(公告)号：WO2010136401A3

    公开(公告)日：2011-08-04

    申请号：PCT/EP2010057038

    申请日：2010-05-21

    Applicant: BASF SE ,  KIRNER HANS JUERG ,  CHEBOTAREVA NATALIA ,  AEBISCHER OLIVIER FREDERIC

    Inventor： KIRNER HANS JUERG ,  CHEBOTAREVA NATALIA ,  AEBISCHER OLIVIER FREDERIC

    IPC: C08G61/12 ,  C07D333/28 ,  C08F8/00 ,  H01L51/00

    CPC classification number: H01L51/0094 ,  C07D233/28 ,  C07D495/04 ,  C07D513/14 ,  C07F7/0814 ,  C08F128/06 ,  C08G61/122 ,  C08G61/123 ,  C08G61/126 ,  C08G75/06 ,  C08G75/32 ,  C08G2261/3241 ,  C08G2261/3243 ,  C08G2261/3247 ,  C08G2261/414 ,  C08G2261/92 ,  H01L51/0003 ,  H01L51/0036 ,  H01L51/0043 ,  H01L51/0071 ,  H01L51/0074 ,  H01L51/0545 ,  H01L51/0558 ,  Y02E10/549

    Abstract: The present invention relates to novel compounds of the formula (I) wherein R1 and R1' independently of each other are H or a substituent, halogen or SiR6R4R5; R2 and R2, may be the same or different and are selected from C1-C25alkyl, C3-C12cycloalkyl, C2-C25alkenyl, C2-C25alkynyl, C4-C25aryl, C5-C25alkylaryl or C5-C25aralkyl, each of which is unsubstituted or substituted, and under conditions as defined in claim 1, R2 and/or R2' may also be halogen or hydrogen; X is a divalent linking group selected from formula (Ia) and formula (Ib); Y and Y' independently are selected from formula (Ic), formula (Id), formula (Ie), formula (If), formula (Ig); n and p independently range from 0 to 6; where further symbols are as defined in claim 1, and to corresponding oligomers and (co)polymers. The compounds according to the invention are useful as semiconductors and have excellent solubility in organic solvents and excellent film-forming properties. In addition, high efficiency of energy conversion, excellent field-effect mobility, good on/off current ratios and/or excellent stability can be observed, when the polymers according to the invention are used in organic field effect transistors, organic photovoltaics (solar cells) and photodiodes.

    Abstract translation: 本发明涉及式（I）的新化合物，其中R1和R1'彼此独立地为H或取代基，卤素或SiR6R4R5; R2和R2可以相同或不同，并且选自C 1 -C 25烷基，C 3 -C 12环烷基，C 2 -C 25烯基，C 2 -C 25炔基，C 4 -C 25芳基，​​C 5 -C 25烷基芳基或C 5 -C 25芳烷基，其各自为未取代或取代的， 并且在权利要求1所定义的条件下，R 2和/或R 2'也可以是卤素或氢; X是选自式（Ia）和式（Ib）的二价连接基团; Y和Y'独立地选自式（Ic），式（Id），式（Ie），式（If），式（Ig）; n和p独立地为0至6; 其中符号如权利要求1中所定义，以及相应的低聚物和（共）聚合物。 根据本发明的化合物可用作半导体并且在有机溶剂中具有优异的溶解性和优异的成膜性能。 此外，当根据本发明的聚合物用于有机场效应晶体管，有机光伏（太阳能电池）中时，可以观察到高能量转换，优异的场效应迁移率，良好的开/关电流比和/或优异的稳定性 ）和光电二极管。

    POLYCYCLIC DITHIOPHENES
    3.
    发明申请
    POLYCYCLIC DITHIOPHENES 审中-公开
    多环十二烷

    公开(公告)号：WO2010136401A2

    公开(公告)日：2010-12-02

    申请号：PCT/EP2010057038

    申请日：2010-05-21

    Applicant: BASF SE ,  KIRNER HANS JUERG ,  CHEBOTAREVA NATALIA ,  AEBISCHER OLIVIER FREDERIC

    Inventor： KIRNER HANS JUERG ,  CHEBOTAREVA NATALIA ,  AEBISCHER OLIVIER FREDERIC

    IPC: C08G61/12

    CPC classification number: H01L51/0094 ,  C07D233/28 ,  C07D495/04 ,  C07D513/14 ,  C07F7/0814 ,  C08F128/06 ,  C08G61/122 ,  C08G61/123 ,  C08G61/126 ,  C08G75/06 ,  C08G75/32 ,  C08G2261/3241 ,  C08G2261/3243 ,  C08G2261/3247 ,  C08G2261/414 ,  C08G2261/92 ,  H01L51/0003 ,  H01L51/0036 ,  H01L51/0043 ,  H01L51/0071 ,  H01L51/0074 ,  H01L51/0545 ,  H01L51/0558 ,  Y02E10/549

    Abstract: The present invention relates to novel compounds of the formula (I) wherein R1 and R1' independently of each other are H or a substituent, halogen or SiR6R4R5; R2 and R2, may be the same or different and are selected from C1-C25alkyl, C3-C12cycloalkyl, C2-C25alkenyl, C2-C25alkynyl, C4-C25aryl, C5-C25alkylaryl or C5-C25aralkyl, each of which is unsubstituted or substituted, and under conditions as defined in claim 1, R2 and/or R2' may also be halogen or hydrogen; X is a divalent linking group selected from formula (Ia) and formula (Ib); Y and Y' independently are selected from formula (Ic), formula (Id), formula (Ie), formula (If), formula (Ig); n and p independently range from 0 to 6; where further symbols are as defined in claim 1, and to corresponding oligomers and (co)polymers. The compounds according to the invention are useful as semiconductors and have excellent solubility in organic solvents and excellent film-forming properties. In addition, high efficiency of energy conversion, excellent field-effect mobility, good on/off current ratios and/or excellent stability can be observed, when the polymers according to the invention are used in organic field effect transistors, organic photovoltaics (solar cells) and photodiodes.

    Abstract translation: 本发明涉及式（I）的新化合物，其中R1和R1'彼此独立地为H或取代基，卤素或SiR6R4R5; R2和R2可以相同或不同，并且选自C 1 -C 25烷基，C 3 -C 12环烷基，C 2 -C 25烯基，C 2 -C 25炔基，C 4 -C 25芳基，​​C 5 -C 25烷基芳基或C 5 -C 25芳烷基，其各自为未取代或取代的， 并且在权利要求1所定义的条件下，R 2和/或R 2'也可以是卤素或氢; X是选自式（Ia）和式（Ib）的二价连接基团; Y和Y'独立地选自式（Ic），式（Id），式（Ie），式（If），式（Ig）; n和p独立地为0至6; 其中符号如权利要求1中所定义，以及相应的低聚物和（共）聚合物。 根据本发明的化合物可用作半导体并且在有机溶剂中具有优异的溶解性和优异的成膜性能。 此外，当根据本发明的聚合物用于有机场效应晶体管，有机光伏（太阳能电池）中时，可以观察到高能量转换，优异的场效应迁移率，良好的开/关电流比和/或优异的稳定性 ）和光电二极管。

    ORGANIC LIGHT EMITTING SYSTEMS
    4.
    发明申请
    ORGANIC LIGHT EMITTING SYSTEMS 审中-公开
    有机发光系统

    公开(公告)号：WO2009092671A3

    公开(公告)日：2009-10-08

    申请号：PCT/EP2009050494

    申请日：2009-01-16

    Applicant: BASF SE ,  CHEBOTAREVA NATALIA ,  PRETOT ROGER ,  WOLLEB ANNEMARIE ,  WOLLEB HEINZ

    Inventor： CHEBOTAREVA NATALIA ,  PRETOT ROGER ,  WOLLEB ANNEMARIE ,  WOLLEB HEINZ

    IPC: C09K11/06 ,  C07F15/00 ,  H05B33/14

    CPC classification number: C09K11/06 ,  C07F15/0033 ,  H05B33/14 ,  H05B33/28

    Abstract: Novel electrophosphorescent copolymers of the composition [A1]x1, [A2]x2, [A3]x3, [A4]x4, [A5]x5 wherein the structural units A1, A2, A3, A4 and/or A5 are in blocks or at random, and the copolymer is linear or crosslinked, and A1 is an organic radical of a phosphorescent light emitting moiety; A2 is an organic radical providing host functionality; A3 is an organic radical providing electron transport functionality; A4 is an organic radical providing hole transport functionality; A5 is a radical derived from aliphatic or aromatic organic monomers; x1 is a number from 1 to about 1000; x2, x3, x4 and x5 independently are numbers from 0 to about 100 000, with the proviso that the sum (x1 + x2 + x3 + x4 + x5) is at least 5, especially greater than 9; are characterized in that A1 contains a metal benzotriazole complex moiety or A2 is selected from repeating unit(s) of the formulae (III), (IV), where the symbols are as defined in claim 1. The novel copolymers are useful as active materials e.g. in electroluminescent devices.

    Abstract translation: 组合物[A1] x1，[A2] x2，[A3] x3，[A4] x4，[A5] x5的新型电致磷光共聚物，其中结构单元A1，A2，A3，A4和/或A5是块或在 无规，共聚物是直链或交联的，A1是磷光发光部分的有机基团; A2是提供主体功能的有机基团; A3是提供电子传递功能的有机基团; A4是提供空穴传输功能的有机基团; A5是衍生自脂族或芳族有机单体的基团; x1是从1到约1000的数字; x2，x3，x4和x5独立地为0至约100000的数字，条件是（x1 + x2 + x3 + x4 + x5）之和至少为5，特别大于9; 其特征在于A1含有金属苯并三唑配合物部分或A2选自式（III），（IV）的重复单元，其中符号如权利要求1中所定义。新型共聚物可用作活性材料 例如 在电致发光器件中。

    7.
    发明专利
    未知

    公开(公告)号：AT492581T

    公开(公告)日：2011-01-15

    申请号：AT07704259

    申请日：2007-01-31

    Applicant: BASF SE

    Inventor： CHEBOTAREVA NATALIA ,  PRETAT ROGER ,  VAN DER SCHAAF PAUL ADRIAAN ,  SCHAEFER THOMAS ,  SCHMIDHALTER BEAT ,  MURER PETER

    IPC: C08G61/00

    Abstract: The present invention relates to novel polymers comprising a repeating unit of the formula (I) and their use in electronic devices. The polymers according to the invention have excellent solubility in organic solvents and excellent film-forming properties. In addition, high charge carrier mobilities and high stability of the emission color can be observed, if the polymers according to the invention are used in organic light emitting diodes (OLEDs).

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