公开(公告)号：US10370586B2

公开(公告)日：2019-08-06

申请号：US14774408

申请日：2014-03-11

Applicant: BASF SE

Inventor： Shawn Fitzgerald ,  Christopher M. Tanguay ,  Timothy D. Klots

IPC: C09K8/80 ,  C09K8/62

Abstract: A proppant includes a particle present in an amount of from 90 to 99.5 percent by weight and a polymeric coating disposed about the particle and present in an amount of from 0.5 to 10 percent by weight, based on the total weight of the proppant. The polymeric coating includes the reaction product of an acrylate copolymer and an isocyanate. The acrylate copolymer includes styrene units and has a hydroxyl number of from 20 to 500 mg KOH/g. A method of forming the proppant includes the steps of combining the acrylate copolymer and the isocyanate to react and form the polymeric coating and coating the particle with the polymeric coating to form the proppant.

公开(公告)号：US20130248759A1

公开(公告)日：2013-09-26

申请号：US13899202

申请日：2013-05-21

Applicant: BASF SE

Inventor： Christopher M. Tanguay ,  Patrick J. Watters ,  John P. Erickson ,  Eric W. Banks

IPC: C08G18/32

CPC classification number: C08G18/3203 ,  C08G18/3218 ,  C08G18/36 ,  C08G18/6696 ,  C08G18/7664 ,  C08G2101/0025 ,  C08G2101/0083

Abstract: A bioresin composition is used to form a rigid polyurethane article that includes a first and a second biopolyol and is substantially free of aprotic solvents that chemically decompose in the presence of water. The first biopolyol includes a natural oil component. The second biopolyol includes the reaction product of a natural carbohydrate and an alkylene oxide. The rigid polyurethane foam article includes the reaction product of the bioresin composition and an isocyanate which are reacted in the presence of a chemical blowing agent.

Abstract translation: 生物树脂组合物用于形成包含第一和第二生物多元醇的硬质聚氨酯制品，并且基本上不含在水存在下化学分解的非质子溶剂。 第一种生物多元醇包括天然油组分。 第二生物多元醇包括天然碳水化合物和烯化氧的反应产物。 硬质聚氨酯泡沫塑料制品包括生物树脂组合物与在化学发泡剂存在下反应的异氰酸酯的反应产物。

公开(公告)号：US09944845B2

公开(公告)日：2018-04-17

申请号：US14775905

申请日：2014-03-13

Applicant: BASF SE

Inventor： Christopher M. Tanguay ,  Yeonsuk Roh ,  Rajesh Kumar

IPC: C09K8/80 ,  C09K8/62

CPC classification number: C09K8/805 ,  C09K8/62

Abstract: A proppant includes a particle present in an amount of from 90 to 99.5 percent by weight and a polymeric coating disposed about the particle and present in an amount of from 0.5 to 10 percent by weight, based on the total weight of the proppant. The polymeric coating is formed from a curable composition comprising an isocyanate, an acrylate, and a polyol. A method of forming the proppant includes the steps of combining the isocyanate, the acrylate, and the polyol to form the curable composition, coating the particle with the curable composition, and curing the curable composition to form the polymeric coating.

公开(公告)号：US09714378B2

公开(公告)日：2017-07-25

申请号：US13678991

申请日：2012-11-16

Applicant: BASF SE

Inventor： Rajesh Kumar ,  Christopher M. Tanguay ,  Michael T. Yang

IPC: C09K8/80 ,  E21B43/267

CPC classification number: C09K8/805 ,  E21B43/267

Abstract: A proppant comprises a particle and a polycarbodiimide coating disposed on the particle. The polycarbodiimide coating comprises the reaction product of an isocyanate reacted in the presence of a phospholene oxide catalyst. A method of forming the proppant comprises the steps of providing the particle, providing the isocyanate, providing the phospholene oxide catalyst, reacting the isocyanate in the presence of the phospholene oxide catalyst to form the polycarbodiimide coating, and coating the particle with the polycarbodiimide coating.

公开(公告)号：US20160032178A1

公开(公告)日：2016-02-04

申请号：US14774408

申请日：2014-03-11

Applicant: BASF SE

Inventor： Shawn Fitzgerald ,  Christopher M. Tanguay ,  Timothy D. Klots

IPC: C09K8/80

CPC classification number: C09K8/805 ,  C09K8/62

Abstract: A proppant includes a particle present in an amount of from 90 to 99.5 percent by weight and a polymeric coating disposed about the particle and present in an amount of from 0.5 to 10 percent by weight, based on the total weight of the proppant. The polymeric coating includes the reaction product of an acrylate copolymer and an isocyanate. The acrylate copolymer includes styrene units and has a hydroxyl number of from 20 to 500 mg KOH/g. A method of forming the proppant includes the steps of combining the acrylate copolymer and the isocyanate to react and form the polymeric coating and coating the particle with the polymeric coating to form the proppant.

Abstract translation: 支撑剂包括存在量为90-99.5重量％的颗粒和围绕颗粒设置的聚合物涂层，其含量为基于支撑剂总重量的0.5-10重量％。 聚合物涂层包括丙烯酸酯共聚物和异氰酸酯的反应产物。 丙烯酸酯共聚物包括苯乙烯单元，羟值为20-500mg KOH / g。 形成支撑剂的方法包括以下步骤：将丙烯酸酯共聚物和异氰酸酯组合以反应并形成聚合物涂层，并用聚合物涂层涂覆颗粒以形成支撑剂。

公开(公告)号：US20160032179A1

公开(公告)日：2016-02-04

申请号：US14775905

申请日：2014-03-13

Applicant: BASF SE

Inventor： Christopher M. Tanguay ,  Yeonsuk Roh ,  Rajesh Kumar

IPC: C09K8/80

CPC classification number: C09K8/805 ,  C09K8/62

Abstract: A proppant includes a particle present in an amount of from 90 to 99.5 percent by weight and a polymeric coating disposed about the particle and present in an amount of from 0.5 to 10 percent by weight, based on the total weight of the proppant. The polymeric coating is formed from a curable composition comprising an isocyanate, an acrylate, and a polyol. A method of forming the proppant includes the steps of combining the isocyanate, the acrylate, and the polyol to form the curable composition, coating the particle with the curable composition, and curing the curable composition to form the polymeric coating.

Abstract translation: 支撑剂包括存在量为90-99.5重量％的颗粒和围绕颗粒设置的聚合物涂层，其含量为基于支撑剂总重量的0.5-10重量％。 聚合物涂层由包含异氰酸酯，丙烯酸酯和多元醇的可固化组合物形成。 形成支撑剂的方法包括将异氰酸酯，丙烯酸酯和多元醇组合以形成可固化组合物的步骤，用可固化组合物涂覆颗粒，并固化可固化组合物以形成聚合物涂层。

公开(公告)号：US20160024376A1

公开(公告)日：2016-01-28

申请号：US14774720

申请日：2014-03-14

Applicant: BASF SE

Inventor： Shawn Fitzgerald ,  Christopher M. Tanguay ,  Timothy D. Klots

IPC: C09K8/80

CPC classification number: C09K8/805 ,  C09K8/62 ,  E21B43/267

Abstract: A proppant comprises a particle present in an amount of from 90 to 99.5 percent by weight based on the total weight of the proppant, and a polymeric coating disposed about the particle and present in an amount of from 0.5 to 10 percent by weight based on the total weight of the proppant. The polymeric coating includes the reaction product of an acrylate copolymer comprising styrene units and having a hydroxyl number of from 20 to 500 mg KOH/g or an acid value of from 20 to 500 mg KOH/g, and an epoxy and/or a melamine.

Abstract translation: 支撑剂包含以占支撑剂总重量的90至99.5重量％的量存在的颗粒，以及围绕颗粒布置的聚合物涂层，其含量为基于所述载体的0.5至10重量％ 支撑剂的总重量。 聚合物涂层包括包含苯乙烯单元并且羟值为20-500mg KOH / g或酸值为20-500mg KOH / g的丙烯酸酯共聚物和环氧树脂和/或三聚氰胺的反应产物 。

公开(公告)号：US20150361331A1

公开(公告)日：2015-12-17

申请号：US14763851

申请日：2014-01-27

Applicant: BASF SE

Inventor： Christopher M. Tanguay ,  Fikri Emrah Alemdaroglu ,  Rajesh Kumar

IPC: C09K8/80 ,  E21B43/267 ,  E21B43/26

CPC classification number: C09K8/805 ,  C09K8/62 ,  E21B43/26 ,  E21B43/267

Abstract: A proppant comprises a particle and a polyoxazolidone isocyanurate coating disposed about the particle. The polyoxazolidone isocyanurate coating comprises the reaction product of a glycidyl epoxy resin and an isocyanate in the presence of a catalyst. A method of forming the proppant comprises the steps of providing the particle, providing the glycidyl epoxy resin, providing the isocyanate, and providing the catalyst. The method also includes the steps of combining the glycidyl epoxy resin and the isocyanate in the presence of the catalyst to react and form the polyoxazolidone isocyanurate coating and coating the particle with the polyoxazolidone isocyanurate coating to form the proppant.

Abstract translation: 支撑剂包括颗粒和围绕颗粒设置的聚恶唑烷酮异氰脲酸酯涂层。 聚恶唑烷酮异氰脲酸酯涂层包含缩水甘油基环氧树脂和异氰酸酯在催化剂存在下的反应产物。 形成支撑剂的方法包括提供颗粒，提供缩水甘油基环氧树脂，提供异氰酸酯和提供催化剂的步骤。 该方法还包括在催化剂存在下将缩水甘油基环氧树脂和异氰酸酯组合以反应并形成聚恶唑烷酮异氰脲酸酯涂层并用聚恶唑烷酮异氰脲酸酯涂层涂覆该颗粒以形成支撑剂的步骤。

公开(公告)号：US08784680B2

公开(公告)日：2014-07-22

申请号：US13899202

申请日：2013-05-21

Applicant: BASF SE

Inventor： Christopher M. Tanguay ,  Patrick J. Watters ,  John P. Erickson ,  Eric W. Banks

IPC: C08G18/28

CPC classification number: C08G18/3203 ,  C08G18/3218 ,  C08G18/36 ,  C08G18/6696 ,  C08G18/7664 ,  C08G2101/0025 ,  C08G2101/0083

Abstract: A bioresin composition is used to form a rigid polyurethane article that includes a first and a second biopolyol and is substantially free of aprotic solvents that chemically decompose in the presence of water. The first biopolyol includes a natural oil component. The second biopolyol includes the reaction product of a natural carbohydrate and an alkylene oxide. The rigid polyurethane foam article includes the reaction product of the bioresin composition and an isocyanate which are reacted in the presence of a chemical blowing agent.

Abstract translation: 生物树脂组合物用于形成包含第一和第二生物多元醇的硬质聚氨酯制品，并且基本上不含在水存在下化学分解的非质子溶剂。 第一种生物多元醇包括天然油组分。 第二生物多元醇包括天然碳水化合物和烯化氧的反应产物。 硬质聚氨酯泡沫塑料制品包括生物树脂组合物与在化学发泡剂存在下反应的异氰酸酯的反应产物。