公开(公告)号：WO2014199306A2

公开(公告)日：2014-12-18

申请号：PCT/IB2014062121

申请日：2014-06-11

Applicant: BASF SE ,  BASF CHINA CO LTD

Inventor： BLANK DR BENOIT ,  KINDLER DR ALOIS ,  BASSLER DR PETER ,  PIEPENBRINK DR MARKUS ,  LANG ORTMUND ,  FELDNER CARMEN

CPC classification number: C07D307/46 ,  B01D3/009 ,  C07D307/48 ,  Y02P20/127

Abstract: A process is described for the preparation of 5-hydroxymethylfurfural (HMF), which comprises the following steps: provision or preparation of a starting mixture, comprising one, two or more starting compounds selected from the group consisting of hexoses, oligosaccharides comprising hexose units, and polysaccharides comprising hexose units, one, two or more organic salts with a melting point 200°C at 1013.25 hPa, optionally additionally one or more catalysts for the conversion of the one starting compound or at least one of the two or more starting compounds to 5-hydroxymethylfurfural (HMF), optionally water, optionally further substances, adjustment of reaction conditions such that an amount of the starting compound or starting compounds converts to HMF.

Abstract translation: 的方法是用于制备描述5-羟甲基糠醛（HMF），该方法包括以下步骤：提供或产生起始混合物包含选自由己糖，寡糖包括己糖单元组成的组中选择的一种，两种或更多种的起始化合物和多糖包括 己糖单元，一个具有熔点<180℃，沸点>在1013.25百帕200℃，任选地在加入两种或更多种有机盐为起始化合物的反应的一种或多种催化剂或两者中的至少一个或 更多的起始化合物为5-羟甲基糠醛（HMF），任选的水，任选的另外的物质， - 的反应条件的设定，从而使起始化合物或起始化合物的量反应，HMF。

公开(公告)号：HUE033363T2

公开(公告)日：2017-11-28

申请号：HUE12808306

申请日：2012-12-11

Applicant: BASF SE

Inventor： BACKES RENE ,  BLANK BENOIT ,  KINDLER ALOIS ,  FELDNER CARMEN

公开(公告)号：IN4393CHN2014A

公开(公告)日：2015-09-04

申请号：IN4393CHN2014

申请日：2014-06-13

Applicant: BASF SE

Inventor： BACKES RENÉ ,  BLANK BENOIT ,  KINDLER ALOIS ,  FELDNER CARMEN

IPC: C07D307/46

Abstract: A process for preparing 5 hydroxymethylfurfural (HMF) characterized in that a) solutions (called starting solution hereinafter) comprising one or more saccharides and an organic solvent having a boiling point greater than 200°C (at standard pressure) (called high boiler for short) and water and a solvent having a boiling point greater than 60°C and less than 200°C (at standard pressure called low boiler for short) are supplied to a reaction vessel b) a conversion of the hexose to HMF in the presence of steam with simultaneous distillative removal of the HMF is effected in the reaction vessel and c) the distillate obtained is an aqueous HMF containing solution (called distillate hereinafter).

公开(公告)号：CA2856864C

公开(公告)日：2021-05-25

申请号：CA2856864

申请日：2012-12-11

Applicant: BASF SE

Inventor： BACKES RENE ,  BLANK BENOIT ,  KINDLER ALOIS ,  FELDNER CARMEN

IPC: C07D307/46

Abstract: A process for preparing 5-hydroxymethylfurfural (HMF), characterized in that a) solutions (called starting solution hereinafter) comprising a hexose and an organic solvent having a boiling point greater than 200°C (at standard pressure) (called high boilers for short) and steam are supplied to a reaction vessel, b) a conversion of the hexose to HMF in the presence of steam with simultaneous distillative removal of the HMF is effected in the reaction vessel and c) the distillate obtained is an aqueous, HMF-containing solution (called distillate hereinafter).

公开(公告)号：HUE034627T2

公开(公告)日：2018-02-28

申请号：HUE12799184

申请日：2012-12-11

Applicant: BASF SE

Inventor： BACKES RENE ,  BLANK BENOIT ,  KINDLER ALOIS ,  FELDNER CARMEN

公开(公告)号：CA2856173A1

公开(公告)日：2013-06-20

申请号：CA2856173

申请日：2012-12-07

Applicant: BASF SE

Inventor： BOHLING RALF ,  BLANK BENOIT ,  KINDLER ALOIS ,  FELDNER CARMEN ,  UMLAUF SANDRA

IPC: C07D307/46

Abstract: A process for preparing solutions which comprise 5-hydroxymethylfurfural (HMF) and have reduced content of starting materials from the HMF synthesis or a reduced content of by-products of the HMF synthesis (called product solution hereinafter), characterized in that solutions comprising HMF starting materials or by-products of the HMF synthesis and an organic solvent having at least two ether groups (polyether for short) (called starting solution hereinafter) are treated with steam in an evaporator.

公开(公告)号：ES2648908T3

公开(公告)日：2018-01-08

申请号：ES12799184

申请日：2012-12-11

Applicant: BASF SE

Inventor： BACKES RENÉ ,  BLANK BENOIT ,  KINDLER ALOIS ,  FELDNER CARMEN

IPC: C07D307/46

Abstract: Procedimiento para la preparación de 5-hidroximetilfurfural (HMF), que se caracteriza porque a un recipiente de reacción se introducen a) soluciones acuosas (en lo sucesivo llamadas solución inicial) que contienen -una o varias hexosas y - un disolvente orgánico con un punto de ebullición superior a 200 °C (a presión normal) (llamado sustancia con un alto punto de ebullición) y - agua y un disolvente con un punto de ebullición superior a 60 °C e inferior a 200 °C (a presión normal, llamado sustancia con un punto bajo de ebullición), b) en el recipiente de reacción se efectúa una conversión de la hexosa en HMF en presencia de vapor de agua y simultáneamente una separación por destilación del HMF y c) como destilado se obtiene una solución acuosa que contiene HMF (en lo sucesivo llamada destilado).

公开(公告)号：ES2626835T3

公开(公告)日：2017-07-26

申请号：ES12808306

申请日：2012-12-11

Applicant: BASF SE

Inventor： BACKES RENÉ ,  BLANK BENOIT ,  KINDLER ALOIS ,  FELDNER CARMEN

IPC: C07D307/46

Abstract: Procedimiento para la preparación de 5-hidroximetilfurfural (HMF), caracterizado porque a) a un recipiente de reacción se introducen soluciones (en lo sucesivo llamadas solución de partida), que contienen - una hexosa y - un disolvente orgánico con un punto de ebullición mayor de 200 °C (a presión atmosférica) (llamado componente con alto punto de ebullición), y vapor de agua, b) en el recipiente de reacción se efectúa una conversión de la hexosa en HMF en presencia de vapor de agua durante la separación simultánea por destilación del HMF y c) como destilado se obtiene una solución acuosa que contiene HMF (en lo sucesivo llamada destilado).

公开(公告)号：CA2914308A1

公开(公告)日：2014-12-18

申请号：CA2914308

申请日：2014-06-11

Applicant: BASF SE

Inventor： BLANK BENOIT ,  KINDLER ALOIS ,  BASSLER PETER ,  PIEPENBRINK MARKUS ,  LANG ORTMUND ,  FELDNER CARMEN

IPC: C07D307/46

Abstract: A process is described for the preparation of 5-hydroxymethylfurfural (HMF), which comprises the following steps: provision or preparation of a starting mixture, comprising one, two or more starting compounds selected from the group consisting of hexoses, oligosaccharides comprising hexose units, and polysaccharides comprising hexose units, one, two or more organic salts with a melting point 200°C at 1013.25 hPa, optionally additionally one or more catalysts for the conversion of the one starting compound or at least one of the two or more starting compounds to 5-hydroxymethylfurfural (HMF), optionally water, optionally further substances, adjustment of reaction conditions such that an amount of the starting compound or starting compounds converts to HMF.

公开(公告)号：CA2856864A1

公开(公告)日：2013-06-20

申请号：CA2856864

申请日：2012-12-11

Applicant: BASF SE

Inventor： BACKES RENE ,  BLANK BENOIT ,  KINDLER ALOIS ,  FELDNER CARMEN

IPC: C07D307/46

Abstract: A process for preparing 5-hydroxymethylfurfural (HMF), characterized in that a) solutions (called starting solution hereinafter) comprising a hexose and an organic solvent having a boiling point greater than 200°C (at standard pressure) (called high boilers for short) and steam are supplied to a reaction vessel, b) a conversion of the hexose to HMF in the presence of steam with simultaneous distillative removal of the HMF is effected in the reaction vessel and c) the distillate obtained is an aqueous, HMF-containing solution (called distillate hereinafter).