Method for Producing Acrylic Acid Polymers
    5.
    发明申请

    公开(公告)号:US20200299426A1

    公开(公告)日:2020-09-24

    申请号:US16074100

    申请日:2017-02-02

    Applicant: BASF SE

    Abstract: A process for producing aqueous solutions of acrylic acid polymers by polymerization of acrylic acid in feed operation with a free-radical starter in the presence of hypophosphite in water as solvent, which comprises (i) initially charging water and optionally acrylic acid in acidic, unneutralized form, optionally one or more ethylenicaliy unsaturated comonomers, optionally aqueous hypophosphite solution and optionally initiator, (ii) adding acrylic acid in acidic, unneutralized form, optionally one or more ethylenicaliy unsaturated comonomers, aqueous free-radical starter solution and aqueous hypophosphite solution, (iii) adding a base to the aqueous solution after termination of the acrylic acid feed, wherein the comonomer content does not exceed 30 wt % based on the total monomer content, wherein the acrylic acid, the aqueous free-radical starter solution and the aqueous hypophosphite solution are added such that the molar ratio x of acrylic acid to phosphorus-bound hydrogen [AA]/[P—H] over a time period in which at least 75% of the acrylic acid is converted has a value x which is constant to within ±0.5 and is in the range from 0.8 to 2.

    Process for cleaning dishware
    7.
    发明授权

    公开(公告)号:US09938489B2

    公开(公告)日:2018-04-10

    申请号:US14902776

    申请日:2014-06-24

    Applicant: BASF SE

    Abstract: Process for cleaning dishware soiled with fatty residue, characterized in that said process is carried out at a temperature in the range of from 45 to 65° C. and using at least one formulation, comprising (A) in the range of from 1 to 50% by weight of at least one complexing agent, selected from the alkali metal salts of citric acid, aminocarboxylic acids and from sodium tripolyphosphate, (B) in the range of from 2 to 8% by weight of at least one non-ionic surfactant of general formula (I) R1—CH(OH)—CH2—O-(AO)x—R2 (I) (C) in the range of from 0.25 to less than 4% by weight of a copolymer, being obtained from copolymerizing the following comonomers (a) at least one comonomer selected from ethylenically unsaturated C3-C4-carboxylic acids and ethylenically unsaturated C4-C8-dicarboxylic acids or their respective anhydrides, (b) at least one comonomer selected from isobutene, diisobutene, C2-C28-a-olefins, and C12-C24-alkyl esters of (meth)acrylic acid, (c) optionally, at least one further comonomer selected from non-ionic comonomers, the integers being defined as follows: R1 being selected from C4-C30-alkyl, straight-chain or branched, and from C4-C30-alkenyl, straight-chain or branched, with at least one C—C double bond, R2 being selected from C1-C30-alkyl, straight-chain or branched, and from C2-C30-alkenyl, straight-chain or branched, with at least one C—C double bond, x being selected from one to 100, AO being identical or different alkylene oxides, selected from CH2—CH2—O, (CH2)3—O, (CH2)4—O, CH2CH(CH3)—O, CH(CH3)—CH2—O— and CH2CH(n-C3H7)—O. R1—CH(OH)—CH2—O-(AO)x—R2  (I)

    FORMULATIONS, THE PRODUCTION AND USE THEREOF, AND SUITABLE COMPONENTS

    公开(公告)号:US20190136152A1

    公开(公告)日:2019-05-09

    申请号:US16096841

    申请日:2017-04-18

    Applicant: BASF SE

    Abstract: Described herein is a formulation including (A) citric acid or an alkali metal salt of citric acid, (B) at least one graft copolymer formed from (a) at least one graft base selected from nonionic monosaccharides, disaccharides, oligosaccharides and polysaccharides, and side chains, obtainable by grafting of (b) at least one ethylenically unsaturated mono- or dicarboxylic acid and (c) at least one compound of the general formula (I) where the variables are defined as follows: R1 is selected from methyl and hydrogen, A1 is selected from C2-C4-alkylene, R2 are the same or different and are selected from C1-C1-alkyl, X− is selected from halide, mono-C1-C4-alkylsulfate and sulfate, (C) a total of zero to 0.5% by weight of methylglycinediacetic acid (MGDA) and glutaminediacetic acid (GLDA) and alkali metal salts of MGDA and GLDA.

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