公开(公告)号：US20130253089A1

公开(公告)日：2013-09-26

申请号：US13787949

申请日：2013-03-07

Applicant: BASF SE

Inventor： Faissal-Ali El-Toufaili ,  Michaela Heussler ,  Christian Schwede ,  Aaron Flores-Figueroa ,  Rainer Dobrawa ,  Dieter Boeckh ,  Wolfgang Loth ,  Gerd Konrad

IPC: C08F2/01

CPC classification number: C08F2/01 ,  C08F283/06 ,  C08F218/08

Abstract: The invention relates to a continuous process for the preparation of amphiphilic graft polymers, wherein a vinyl ester component (B) composed of vinyl acetate and/or vinyl propionate (B1) and, if desired, a further ethylenically unsaturated monomer (B2), is polymerized in the presence of a polyalkylene oxide (A), a free radical-forming initiator (C) and, if desired, an additive (D), at a mean polymerization temperature at which the initiator (C) has a decomposition half-time of from 1 to 500 min, in at least one tubular reactor segment with a feed side and an outlet side, through which the reaction mixture comprising at least a part of component (A) to (C), and if desired (D), streams, a tubular reactor segment and the use of the inventive amphiphilic graft polymer. The invention further relates to an inventive amphiphilic graft polymer and the use thereof.

Abstract translation: 本发明涉及制备两亲性接枝聚合物的连续方法，其中由乙酸乙烯酯和/或丙酸乙烯酯（B1）组成的乙烯基酯组分（B）和如果需要，另外的烯键式不饱和单体（B2）是 在聚亚烷基氧化物（A），自由基形成引发剂（C）和根据需要的情况下，在引发剂（C）具有分解半衰期的平均聚合温度下，如果需要，添加剂 在至少一个具有进料侧和出口侧的管状反应器段中，反应混合物通过该混合物至少包含组分（A）至（C）和（如果需要的话）（D）， 流，管式反应器段和本发明的两亲接枝聚合物的用途。 本发明还涉及本发明的两亲性接枝聚合物及其用途。

公开(公告)号：US09068023B2

公开(公告)日：2015-06-30

申请号：US13787949

申请日：2013-03-07

Applicant: BASF SE

Inventor： Faissal-Ali El-Toufaili ,  Michaela Heussler ,  Christian Schwede ,  Aaron Flores-Figueroa ,  Rainer Dobrawa ,  Dieter Boeckh ,  Wolfgang Loth ,  Gerd Konrad

IPC: C08F283/06 ,  C08F2/01 ,  B01J19/24

CPC classification number: C08F2/01 ,  C08F283/06 ,  C08F218/08

Abstract: The invention relates to a continuous process for the preparation of amphiphilic graft polymers, wherein a vinyl ester component (B) composed of vinyl acetate and/or vinyl propionate (B1) and, if desired, a further ethylenically unsaturated monomer (B2), is polymerized in the presence of a polyalkylene oxide (A), a free radical-forming initiator (C) and, if desired, an additive (D), at a mean polymerization temperature at which the initiator (C) has a decomposition half-time of from 1 to 500 min, in at least one tubular reactor segment with a feed side and an outlet side, through which the reaction mixture comprising at least a part of component (A) to (C), and if desired (D), streams, a tubular reactor segment and the use of the inventive amphiphilic graft polymer. The invention further relates to an inventive amphiphilic graft polymer and the use thereof.

Abstract translation: 本发明涉及制备两亲性接枝聚合物的连续方法，其中由乙酸乙烯酯和/或丙酸乙烯酯（B1）组成的乙烯基酯组分（B）和如果需要，另外的烯键式不饱和单体（B2）是 在聚亚烷基氧化物（A），自由基形成引发剂（C）和根据需要的情况下，在引发剂（C）具有分解半衰期的平均聚合温度下，如果需要，添加剂 在至少一个具有进料侧和出口侧的管状反应器段中，反应混合物通过该混合物至少包含组分（A）至（C）和（如果需要的话）（D）， 流，管式反应器段和本发明的两亲接枝聚合物的用途。 本发明还涉及本发明的两亲性接枝聚合物及其用途。