Abstract:
PROBLEM TO BE SOLVED: To provide a properly substituted perylene-3,4-dicarboxylic monoimide having advantageous application character, not only applicable by incorporating easily into a specific application vehicle but also capable of absorbing and radiating light with shorter wavelength than representative known compounds, e.g., in a yellow color region of electromagnetic spectrum. SOLUTION: There is provided a 9-cyano substituted perylene-3,4-dicarboxylic monoimide represented in Fig.I, [the variables are defined as follows: X has a specific meaning, Y is a functional group Y' or a polymerizable group P, or X-Y together form an R group, Y' is has a specific meaning. P is a group represented in Fig.II, A, B are each independently hydrogen, 1-6C alkyl or phenyl, or are together a cyclopentene or cyclohexene ring which contains the double bond to which A and B are bonded, Q, n and R each has a specific meaning]. COPYRIGHT: (C)2010,JPO&INPIT
Abstract:
A process for preparing perylene-3,4:9,10-tetracarboxylic dianhydride, comprising: dimerizing a naphthalene-1,8-dicarboximide of the formula IIa; reoxidizing the resulting alkali metal salt of the leuco form of the perylene-3,4:9,10-tetracarboxylic diimide of the formula Ia; hydrolyzing the diimide to the tetraalkali metal salt of perylene-3,4:9,10-tetracarboxylic acid in the presence of an inert organic solvent, of an alkali metal base and of water; and subjecting the tetraalkali metal salt of perylene-3,4:9,10-tetracarboxylic acid to the action of an aqueous inorganic acid to convert it into perylene-3,4:9,10-tetracarboxylic dianhydride; wherein R3 is cyclohexyl or phenyl which may each be substituted by up to three C1-C4-alkyl radicals, and the dimerizing is in a substantially homogeneous reaction medium consisting essentially of an apolar aprotic organic solvent and an alkali metal base.
Abstract:
A process for preparing terylene-3,4:11,12-tetracarboximides I where the variables are each defined as follows: R, R' are each independently hydrogen; if desired substituted alkyl or cycloalkyl; R 1 is hydrogen or alkyl; R 2 is hydrogen; alkyl; if desired substituted aryl or hetaryl, by reacting a perylene-3,4-dicarboximide II in the presence of a base-stable, high-boiling organic solvent and of an alkali metal or alkaline earth metal base, with a naphthalene-1,8-dicarboximide III in which X is hydrogen, bromine or chlorine.