公开(公告)号：US20200231528A1

公开(公告)日：2020-07-23

申请号：US16639174

申请日：2018-08-16

Applicant: BASF SE

Inventor： Mathieu BLANCHOT ,  Uwe MEISENBURG ,  Steffen MAURER ,  Jochen PETZOLDT ,  Tobias HOEFENER ,  Boris BREITSCHEIDEL ,  Andrea MISSKE ,  Friederike FLEISCHHAKER ,  Martin KALLER ,  Christoph FLECKENSTEIN ,  Ulrik STENGEL ,  Ritesh NAIR

IPC: C07C67/24

Abstract: A process for preparing an ester of (meth)acrylic acid or a derivative thereof comprises reacting (meth)acrylic acid or a derivative thereof with glycerol carbonate at a reaction temperature of 10 to 150° C. without a solvent in the presence of at least one enzyme catalyzing the esterification reaction.

公开(公告)号：US20150274629A1

公开(公告)日：2015-10-01

申请号：US14737889

申请日：2015-06-12

Applicant: BASF SE

Inventor： Volker SCHLIEPHAKE ,  Klaus BOTT ,  Rolf-Dieter BECHER ,  Klaus Joachim MUELLER-ENGEL ,  Jochen PETZOLDT ,  Ulrich CREMER ,  Andreas RAICHLE

IPC: C07C51/25 ,  C07C45/35

CPC classification number: C07C51/252 ,  B01J8/0045 ,  B01J8/06 ,  B01J2208/00761 ,  B08B9/0436 ,  C07C45/35

Abstract: A process for recharging the reaction tubes of a tube bundle reactor with a new fixed catalyst bed, in which a heterogeneously catalyzed partial gas phase oxidation of an organic compound had been performed beforehand in a preceding fixed catalyst bed comprising Mo-comprising multielement oxide active compositions to form a steam-comprising product gas mixture, in which, before the recharge, solid deposit which had been deposited on the tube inner walls and comprises molybdenum oxide and/or molybdenum oxide hydrate is brushed away with the aid of a brush.

Abstract translation: 一种用新的固定催化剂床对管束反应器的反应管进行再充电的方法，其中在先前的包含含钼的多元素氧化物活性组合物的固定催化剂床中预先进行了有机化合物的非均相催化的部分气相氧化 以形成含蒸汽的产物气体混合物，其中在再充电之前，已经沉积在管内壁上并且包含氧化钼和/或氧化钼水合物的固体沉积物借助于刷子被刷洗掉。

公开(公告)号：US20140135523A1

公开(公告)日：2014-05-15

申请号：US14038972

申请日：2013-09-27

Applicant: BASF SE

Inventor： Ulrich JAEGER ,  Volker SCHLIEPHAKE ,  Ortmund LANG ,  Jochen PETZOLDT ,  Tobias Johannes KORN ,  Virginie BETTE ,  Claus HECHLER

IPC: C07C67/28 ,  C07C67/62

CPC classification number: C07C67/62 ,  C07C67/08 ,  C07C67/54 ,  C07C69/52 ,  C07C69/54

Abstract: A continuous process for preparing (meth)acrylates of C10-alcohol mixtures by reaction of glacial (meth)acrylic acid with an isomer mixture of C10-alcohols composed of 2-propylheptanol as the main isomer and at least one of the C10-alcohols 2-propyl-4-methylhexanol, 2-propyl-5-methylhexanol, 2-isopropylheptanol, 2-isopropyl-4-methylhexanol, 2-isopropyl-5-methylhexanol and/or 2-propyl-4,4-dimethylpentanol, and the use of a diester of dicarboxylic acids which have been esterified with N-oxyl-containing compounds as polymerization inhibitors in such a process.

Abstract translation: 通过冰（甲基）丙烯酸与由2-丙基庚醇组成的C 10醇作为主要异构体的异构体混合物和至少一种C 10醇2来制备C10-醇混合物的（甲基）丙烯酸酯的连续方法 丙基-4-甲基己醇，2-丙基-5-甲基己醇，2-异丙基庚醇，2-异丙基-4-甲基己醇，2-异丙基-5-甲基己醇和/或2-丙基-4,4-二甲基戊醇， 的二羧酸二酯在这种方法中被N-氧基化合物酯化作为聚合抑制剂。