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    SEMICONDUCTING POLYMER
    1.
    发明申请
    SEMICONDUCTING POLYMER 审中-公开
    半导体聚合物

    公开(公告)号：WO2017148864A1

    公开(公告)日：2017-09-08

    申请号：PCT/EP2017/054507

    申请日：2017-02-27

    Applicant: BASF SE

    Inventor： FLORES, Jean-Charles ,  HAYOZ, Pascal ,  MCCULLOCH, Iain ,  ONWUBIKO, Nkechinyerem ,  KAELBLEIN, Daniel

    IPC: C07D487/04 ,  G03G5/06

    Abstract: Compounds of formula (I) and polymers comprising at least a structure of formula (II), wherein T 1 or T 2 are independently of each other a group of Formula (III), Formula (iv) Q a , Q b , Q c , Q d , Q e or Q f are independently of each other O, S or NR 1.

    Abstract translation: 式（I）的化合物和包含至少一个式（II）的结构的聚合物，其中T 1或T 2独立地为 （III），式（IV）Q a，Q b，Q c，Q d， Q，Q或Q相互独立地是O，S或NR 1。

    NAPHTHOINDACENODITHIOPHENES AND POLYMERS
    2.
    发明申请
    NAPHTHOINDACENODITHIOPHENES AND POLYMERS 审中-公开
    萘并二硫代亚苯基和聚合物

    公开(公告)号：WO2017097924A1

    公开(公告)日：2017-06-15

    申请号：PCT/EP2016/080309

    申请日：2016-12-08

    Applicant: BASF SE

    Inventor： HAYOZ, Pascal ,  KAELBLEIN, Daniel ,  MCCULLOCH, Iain ,  KNALL, Astrid-Caroline

    IPC: C07D495/02 ,  C08G61/12 ,  H01L51/00

    CPC classification number: C07D495/04 ,  C08G61/123 ,  C08G61/126 ,  C08G2261/124 ,  C08G2261/3246 ,  C08G2261/344 ,  C08G2261/411 ,  C08G2261/51 ,  C08G2261/92 ,  H01L51/0043 ,  H01L51/0545 ,  H01L51/0558

    Abstract: Polymers comprising at least one unit of formula1 and compounds of the formula 1' wherein, in formulae 1 and 1' n is 0, 1, 2, 3 or 4 mis 0, 1, 2, 3 or 4 X is at each occurrence selected from the group consisting of O, S, Se or Te, Q is at each occurrence selected from the group consisting of C, Si or Ge R is at each occurrence selected from the group consisting of hydrogen, C 1-30 -alkyl, C 2-30 -alkenyl, C 2-30 -alkynyl, C 5-12 -cycloalkyl, C 6-18 -aryl, R 2 , R 2' , R * are at each occurrence independently selected from the group consisting of hydrogen, C 1-30 -alkyl, C 2-30 -alkenyl, C 2-30 -alkynyl,C 5-12 -cycloalkyl, C 6-18 -aryl, 5 to 20 membered hetero-aryl, OR 21 , OC(O)-R 21 , C(O)-OR 21 , C(O)-R 21 , NR 21 R 22 , NR 21 -C(O)R 22 , C(O)-NR 21 R 22 , N[C(O)R 21 ][C(O)R 22 ], SR 21 , halogen, CN, SiR Sis R Sit R Siu and OH, L 1 and L 2 are independently from each other and at each occurrence selected from the group consisting of C 6-30 -arylene, 5 to 30 membered heteroarylene.

    Abstract translation: 包含至少一个式1的单元和式1'的化合物的聚合物，其中在式1和1'中n是0,1,2,3或4是0,1,2,3 或4 X在每次出现时选自O，S，Se或Te，Q在每次出现时选自C，Si或Ge，R在每次出现时选自氢， C 1-20 - 烷基，C 2-30 - 烯基，C 2-30 - 炔基，C 5-12 - 环烷基，C 6-18芳基，R 2，R 2，R 4，R 5， 在每次出现时独立地选自氢，C 1-30 - 烷基，C 2-30 - 链烯基，C 2-30 - 亚烷基，C 5-12环烷基，C 6-18芳基，5-20元杂芳基，OR 21 - ，OC（O）-R 21，C（O）-OR 21，C（O）-R 21，NR 18， （O）R 22，C（O）-NR 21，-C（O）NR 21 R 21， R 22，N [C（O）R s （O）R 22]，SR 21，卤素，CN，SiR S 1，R 3， 其中R 1和R 2与OH，L 1和L 2彼此独立并且在每次出现时选自基团 由C 6-30亚芳基，5-30元亚杂芳基组成。

    THIENO-INDENO-MONOMERS AND POLYMERS
    5.
    发明申请
    THIENO-INDENO-MONOMERS AND POLYMERS 审中-公开

    公开(公告)号：WO2018104367A3

    公开(公告)日：2018-06-14

    申请号：PCT/EP2017/081633

    申请日：2017-12-06

    Applicant: BASF SE ,  KING ABDULLAH UNIVERSITY OF SCIENCE AND TECHNOLOGY

    Inventor： CHEN, Hu ,  ZHANG, Weimin ,  HURHANGEE, Michael ,  MCCULLOCH, Iain ,  HAYOZ, Pascal ,  KAELBLEIN, Daniel

    IPC: C07D495/04 ,  C08G61/12 ,  H01B1/12 ,  H01L51/00 ,  H01L51/30 ,  H01L51/05

    Abstract: Polymers comprising at least one unit of formulae 1 or 1' and compounds of the formulae 2 or 2' wherein, in formulae 1, 1', 2 and 2', n is 0, 1, 2, 3 or 4, m is 0, 1, 2, 3 or 4, M1 and M2 are independently of each other an aromatic or heteroaromatic monocyclic or bicyclic ring system; X is at each occurrence selected from the group consisting of O, S, Se or Te, Q is at each occurrence selected from the group consisting of C, Si or Ge, R is at each occurrence selected from the group consisting of hydrogen, C 1-100 -alkyl, C 2-100 -alkenyl, C 2-100 -alkynyl, C 5-12 -cycloalkyl, C 6-18 -aryl, a 5 to 20 membered heteroaryl, C(O)-C 1-100 -alkyl, C(O)-C 5-12 -cycloalkyl and C(O)-OC 1-100 -alkyl. R 2 , R 2' , R 2" , R * are at each occurrence independently selected from the group consisting of hydrogen, C 1-30 -alkyl, C 2-30 -alkenyl, C 2-30 -alkynyl, C 5-12 -cycloalkyl, C 6-18 -aryl, 5 to 20 membered heteroaryl, OR 21 , OC(O)-R 21 , C(O)-OR 21 , C(O)-R 21 , NR 21 R 22 , NR 21 -C(O)R 22 , C(O)-NR 21 R 22 ,N[C(O)R 21 ][C(O)R 22 ], SR 21 , halogen, CN, SiR Sis R Sit R Siu and OH, L 1 and L 2 are independently from each other and at each occurrence selected from the group consisting of C 6-30 -arylene, 5 to 30 membered heteroarylene, (A) (B) and (C).

    STAR-SHAPED AND TRIBLOCK POLYMERS WITH ENHANCED CROSSLINKABILITY
    6.
    发明申请
    STAR-SHAPED AND TRIBLOCK POLYMERS WITH ENHANCED CROSSLINKABILITY 审中-公开
    星形和三嵌段聚合物具有增强的交联性

    公开(公告)号：WO2018060016A1

    公开(公告)日：2018-04-05

    申请号：PCT/EP2017/073689

    申请日：2017-09-20

    Applicant: BASF SE

    Inventor： MARTIN, Emmanuel ,  BRUNETTI, Fulvio Giacomo ,  KAELBLEIN, Daniel ,  KNOLL, Konrad ,  KOPPING, Jordan Thomas

    IPC: C08K5/00 ,  C08K5/28 ,  H01L29/772

    Abstract: The present invention provides compositions comprising a) at least one polymer consisting of one polymerblock A and at least two polymerblocks B, wherein each polymerblock B is attached to the polymerblock A, and wherein at least 60 mol% of the monomer units of polymerblock B are selected from the group consisting of Formulae (1A), (1B), (1C), (1D), (1E), (1F) and 1G, 1H and 1I wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 and R 8 are independently and at each occurrence H or C 1-10 -alkyl, and b) at least one crosslinking agent carrying at least two azide groups, as well as to layers formed from these compositions, electronic devices comprising these layers and to specific polymers encompassed by the polymers of the composition.

    Abstract translation: 本发明提供组合物，其包含a）至少一种由一个聚合物嵌段A和至少两个聚合物嵌段B组成的聚合物，其中每个聚合物嵌段B连接到聚合物嵌段A上，并且其中至少60mol％ （1A），（1B），（1C），（1D），（1E），（1F）和1G，1H和1I的聚合物嵌段B的单体单元选自其中R 1 R 2，R 3，R 4，R 5，R 6，R 5，R 5，R 5，R 5， R 7和R 8独立地在每次出现时为H或C 1-10 1-10烷基，和b）在 至少一种携带至少两个叠氮基团的交联剂，以及由这些组合物形成的层，包含这些层的电子器件以及包含在组合物的聚合物中的特定聚合物。

    THIENO-INDENO-MONOMERS AND POLYMERS
    8.
    发明申请
    THIENO-INDENO-MONOMERS AND POLYMERS 审中-公开

    公开(公告)号：WO2018104367A2

    公开(公告)日：2018-06-14

    申请号：PCT/EP2017/081633

    申请日：2017-12-06

    Applicant: BASF SE ,  KING ABDULLAH UNIVERSITY OF SCIENCE AND TECHNOLOGY

    Inventor： CHEN, Hu ,  ZHANG, Weimin ,  HURHANGEE, Michael ,  MCCULLOCH, Iain ,  HAYOZ, Pascal ,  KAELBLEIN, Daniel

    IPC: C07D495/04 ,  C08G61/12 ,  H01B1/12 ,  H01L51/00 ,  H01L51/30 ,  H01L51/05

    Abstract: Polymers comprising at least one unit of formulae 1 or 1' and compounds of the formulae 2 or 2' wherein, in formulae 1, 1', 2 and 2', n is 0, 1, 2, 3 or 4, m is 0, 1, 2, 3 or 4, M1 and M2 are independently of each other an aromatic or heteroaromatic monocyclic or bicyclic ring system; X is at each occurrence selected from the group consisting of O, S, Se or Te, Q is at each occurrence selected from the group consisting of C, Si or Ge, R is at each occurrence selected from the group consisting of hydrogen, C 1-100 -alkyl, C 2-100 -alkenyl, C 2-100 -alkynyl, C 5-12 -cycloalkyl, C 6-18 -aryl, a 5 to 20 membered heteroaryl, C(O)-C 1-100 -alkyl, C(O)-C 5-12 -cycloalkyl and C(O)-OC 1-100 -alkyl. R 2 , R 2' , R 2" , R * are at each occurrence independently selected from the group consisting of hydrogen, C 1-30 -alkyl, C 2-30 -alkenyl, C 2-30 -alkynyl, C 5-12 -cycloalkyl, C 6-18 -aryl, 5 to 20 membered heteroaryl, OR 21 , OC(O)-R 21 , C(O)-OR 21 , C(O)-R 21 , NR 21 R 22 , NR 21 -C(O)R 22 , C(O)-NR 21 R 22 ,N[C(O)R 21 ][C(O)R 22 ], SR 21 , halogen, CN, SiR Sis R Sit R Siu and OH, L 1 and L 2 are independently from each other and at each occurrence selected from the group consisting of C 6-30 -arylene, 5 to 30 membered heteroarylene, (A) (B) and (C).

    SEMICONDUCTORS
    9.
    发明申请
    SEMICONDUCTORS 审中-公开

    公开(公告)号：WO2017202635A1

    公开(公告)日：2017-11-30

    申请号：PCT/EP2017/061614

    申请日：2017-05-15

    Applicant: BASF SE

    Inventor： HAYOZ, Pascal ,  KAELBLEIN, Daniel

    IPC: C08G61/12 ,  H01L51/00

    Abstract: The present invention relates to polymers comprising a repeating unit of the formula - [Ar 3 ] c -[Ar 2 ] b -[Ar 1 ] a -Y(R 1 ) n1 (R 2 ) n2 -[Ar 1' ] a -[Ar 2' ] b´ -[Ar 3' ] c´ - (I), wherein γ is a bivalent heterocyclic group, or ring system, which may optionally be substituted, Ar 1 , Ar 1' Ar 2 , Ar 2' , Ar 3 and Ar 3' are independently of each other a C 6 -C 24 arylen group, which can optionally be substituted, or a C 2 -C 30 heteroarylen group, which can optionally be, Formula (1), substituted; at least one of R1 and R2 is a group of formula (II); and their use as organic semiconductor in organic devices, especially in organic photovoltaics and photodiodes, or in a device containing a diode and/or an organic field effect transistor. The polymers according to the invention can have excellent solubility in organic solvents and excellent film-forming properties. In addition, high efficiency of energy conversion, excellent field-effect mobility, good on/off current ratios and/or excellent stability can be observed, when the polymers according to the invention are used in organic field effect transistors, organic photovoltaics and photodiodes.

    Abstract translation: 本发明涉及包含下式的重复单元的聚合物： - [Ar 3] n - [Ar 2] ]]> b - [Ar 1] a -Y（R 1） n1 （R 2 2）n 2 - [Ar 1] 1 - [Ar 2] （I）的化合物，其中γ是二价杂环基团，或者 环系统，其可以任选地被取代，Ar 1，Ar 1，Ar 2，Ar 2， Ar 3和Ar 3各自独立地为C≡C24亚芳基，其可以是 任选地被取代的或C 2 -C 30亚杂芳基基团，其可以任选地被取代的式（1） R1和R2中的至少一个是式（II）的基团; 以及它们在有机器件中，特别是在有机光伏器件和光电二极管中，或者在包含二极管和/或有机场效应晶体管的器件中用作有机半导体。 根据本发明的聚合物可以在有机溶剂中具有优异的溶解性和优异的成膜性。 此外，当将根据本发明的聚合物用于有机场效应晶体管，有机光伏电池和光电二极管时，可以观察到高能量转换效率，优异的场效应迁移率，良好的开/关电流比和/或优异的稳定性。

    POLYMERS AND COMPOUNDS BASED ON DIPYRROLO[1,2-B:1',2'-G][2,6]NAPHTHYRIDINE-5,11-DIONE
    10.
    发明申请
    POLYMERS AND COMPOUNDS BASED ON DIPYRROLO[1,2-B:1',2'-G][2,6]NAPHTHYRIDINE-5,11-DIONE 审中-公开
    基于二吡咯并[1,2-B：1'，2'-G] [2,6]萘并吡啶-5,11-二酮的聚合物和化合物

    公开(公告)号：WO2017068009A1

    公开(公告)日：2017-04-27

    申请号：PCT/EP2016/075141

    申请日：2016-10-20

    Applicant: BASF SE

    Inventor： GRZYBOWSKI, Marek ,  GRYKO, Daniel ,  SADOWSKI, Bartlomiej ,  STRASSEL, Karen ,  HAYOZ, Pascal ,  KAELBLEIN, Daniel

    IPC: C07D471/22 ,  H01B1/12 ,  H01L51/00

    CPC classification number: C07D471/22 ,  H01B1/12 ,  H01B1/128 ,  H01L51/0035 ,  H01L51/0036 ,  H01L51/0043 ,  H01L51/0072 ,  H01L51/0541 ,  H01L51/0558 ,  H01L51/4253 ,  Y02E10/549

    Abstract: The present invention relates to polymers comprising a repeating unit of the formula -[Ar-Y-Ar']- (v), and compounds of formula R 10 –Ar-Y-Ar'-R 10' (I), wherein Y is a group of formula (A), and their use as organic semiconductor in organic devices, especially in organic photovoltaics and photodiodes, or in a device containing a diode and/or an organic field effect transistor. The polymers and compounds according to the invention can have excellent solubility in organic solvents and excellent film-forming properties. In addition, high efficiency of energy conversion, excellent field-effect mobility, good on/off current ratios and/or excellent stability can be observed, when the polymers and compounds according to the invention are used in organic field effect transistors, organic photovoltaics and photodiodes.

    Abstract translation: 本发明涉及包含式 - [Ar-Y-Ar'] - （v）的重复单元的聚合物和式R 10 -Ar （I）的基团，其中Y是式（A）的基团，以及它们作为有机半导体在有机器件中的用途，特别是在有机光伏器件和光电二极管中，或者在有机光伏器件中 包含二极管和/或有机场效应晶体管的器件。 根据本发明的聚合物和化合物可以在有机溶剂中具有优异的溶解性和优异的成膜性能。 另外，当将根据本发明的聚合物和化合物用于有机场效应晶体管，有机光伏电池和有机场效应晶体管时，能够观察到高能量转换效率，优异的场效应迁移率，良好的开/关电流比和/或优异的稳定性。 光电二极管。

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