公开(公告)号：US08637619B2

公开(公告)日：2014-01-28

申请号：US13667828

申请日：2012-11-02

Applicant: BASF SE

Inventor： Hannah Maria Koenig ,  Klaus Muelbach ,  Matthias Kiefer ,  Sergei V. Kostjuk ,  Irina Vasilenko ,  Alexander Frolov

IPC: C08F4/14 ,  C08F10/10

CPC classification number: C08F10/10 ,  C08F110/10 ,  C08F210/12 ,  C08F4/14 ,  C08F2500/01 ,  C08F212/08

Abstract: Preparation of high-reactivity isobutene homo- or copolymers with a content of terminal vinylidene double bonds per polyisobutene chain end of at least 50 mol % and a polydispersity of preferably 1.05 to less than 3.5, by polymerizing isobutene or an isobutene-comprising monomer mixture in the presence of an aluminum trihalide-donor complex effective as a polymerization catalyst or of an alkylaluminum halide-donor complex, especially of an aluminum trichloride-donor complex, said complex comprising, as the donor, an organic compound with at least one ether function or a carboxylic ester function.

Abstract translation: 通过将异丁烯或含异丁烯的单体混合物聚合，制备具有至少50mol％的聚异丁烯链末端亚乙烯基双键的含量，优选1.05至小于3.5的多分散性的高反应性异丁烯均聚物或共聚物 作为聚合催化剂或卤化烷基铝供体络合物，特别是三氯化铝 - 供体络合物有效的铝三卤化铝 - 供体络合物的存在，所述络合物包含作为供体的具有至少一个醚官能团的有机化合物或 羧酸酯官能团。