Abstract:
A reactor (100) for electrochemical synthesis is proposed. The reactor (100) comprises a vessel (102) configured to receive a reaction mixture comprising an electrolytic medium and at least one reactant, at least a first electrode (108), and at least a second electrode (110). The first electrode (108) and the second electrode (110) are arranged within the vessel (102) and inter-penetrate one another without electrical contact. The first electrode (108) and/or the second electrode (110) are three dimensionally grid-shaped, the first electrode (108) and the second electrode (110) being arranged so as to allow and/or purposefully direct a flow of the reaction mixture therebetween. Further, a method for carrying out an electrochemical synthesis is pro-posed.
Abstract:
The invention relates to a process for coating plastics or plastic surfaces with metals, especially plastics composed of acrylonitrile/butadiene/styrene copolymers (ABS) and composed of mixtures of these copolymers with other plastics (e.g. ABS blends), wherein the process comprises the pretreatment of the plastic surfaces with a composition C (etch solution) comprising at least two different ionic liquids IL1 and IL2.
Abstract:
The invention relates to a process for coating plastic surfaces with metals, especially plastic surfaces composed of acrylonitrile/butadiene/styrene copolymers (ABS) and composed of mixtures of these copolymers with other plastics (ABS blends), using an etch solution (composition C) comprising at least one ionic liquid IL, wherein the process comprises the treating of the plastic surface after the etching with an aqueous rinse solution RS while applying ultrasound.
Abstract:
Mittels elektrochemischer reduktiver Kreuzkopplung von α,β-ungesättigten Estern mit Carbonyl-verbindungen in einer ungeteilten Elektrolysezelle mit einer Kathode aus Blei, Bleilegierungen, Kadmium, Kadmiumlegierungen, Quecksilber, Stahl, Glaskohlenstoff oder Bor-dotierten Diamanten und einem basischen wässrigen Elektrolyten mit einem die kathodische Wasserstoffbildung unterdrückenden Leitsalz, lassen sich γ-Hydroxycarbonsäureester und γ-Lactone herstellen, die als Aromastoffe geeignet sind.
Abstract:
The invention relates to a method for producing γ-hydroxycarboxylic esters and γ-lactones, which are suitable as aromatic substances, by electrochemical reductive cross-coupling of α,β-unsaturated esters with carbonyl compounds in an undivided electrolytic cell, said cell having a cathode that consists of lead, lead alloys, cadmium, cadmium alloys, mercury, steel, glassy carbon or boron-doped diamonds, and using an alkaline aqueous electrolyte comprising a conducting salt which suppresses cathodic hydrogen formation.
Abstract:
The invention relates to a process for coating plastic surfaces with metals, especially plastic surfaces composed of acrylonitrile/butadiene/styrene copolymers (ABS) and composed of mixtures of these copolymers with other plastics (ABS blends), using an etch solution (composition C) comprising at least one ionic liquid IL, wherein the process comprises the treating of the plastic surface after the etching with an aqueous rinse solution RS while applying ultrasound.