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    CHA TYPE ZEOLITIC MATERIALS AND METHODS FOR THEIR PREPARATION USING COMBINATIONS OF CYCLOALKYL- AND TETRAALKYLAMMONIUM COMPOUNDS
    1.
    发明申请
    CHA TYPE ZEOLITIC MATERIALS AND METHODS FOR THEIR PREPARATION USING COMBINATIONS OF CYCLOALKYL- AND TETRAALKYLAMMONIUM COMPOUNDS 审中-公开
    CHA类型的ZEOLITIC材料及其使用环己基 - 和四氨基亚甲基化合物的组合制备方法

    公开(公告)号：WO2015185625A3

    公开(公告)日：2016-02-04

    申请号：PCT/EP2015062377

    申请日：2015-06-03

    Applicant: BASF SE

    Inventor： FEYEN MATHIAS ,  YANG JEFF ,  RUETZ ROGER ,  MÜLLER ULRICH

    IPC: C01B39/48 ,  B01J29/72

    CPC classification number: C01B39/48 ,  B01J29/7015 ,  B01J29/763 ,  B01J35/002 ,  B01J35/023 ,  B01J37/0246 ,  B01J2229/186 ,  B01J2229/42

    Abstract: The present invention relates to a process for the preparation of a zeolitic material having a CHA-type framework structure comprising YO2 and X2O3, wherein said process comprises the steps of: (1) providing a mixture comprising one or more sources for YO2, one or more sources for X2O3, one or more tetraalkylammonium cation R1R2R3R4N+-containing compounds, and one or more tetraalkylammonium cation R5R6R7R8N+-containing compounds as structure directing agent; (2) crystallizing the mixture obtained in step (1) for obtaining a zeolitic material having a CHA-type framework structure; wherein Y is a tetravalent element and X is a trivalent element, wherein R1, R2, R3, R4, R5, R6, and R7 independently from one another stand for alkyl, and wherein R8 stands for cycloalkyl, as well as to zeolitic materials which may be obtained according to the inventive process and to their use.

    Abstract translation: 本发明涉及一种制备具有包含YO 2和X 2 O 3的CHA型骨架结构的沸石材料的方法，其中所述方法包括以下步骤：（1）提供包含一种或多种YO 2， 更多的X2O3，一种或多种四烷基铵阳离子R1R2R3R4N +的化合物来源，以及一种或多种四烷基铵阳离子R5R6R7R8N +化合物作为结构导向剂; （2）使步骤（1）中得到的混合物结晶得到具有CHA型骨架结构的沸石材料; 其中Y是四价元素，X是三价元素，其中R 1，R 2，R 3，R 4，R 5，R 6和R 7彼此独立地代表烷基，并且其中R8代表环烷基，以及沸石材料， 可以根据本发明的方法和它们的用途获得。

    SYNTHESIS OF A BORON-CONTAINING ZEOLITE WITH AN MWW FRAMEWORK STRUCTURE
    5.
    发明申请
    SYNTHESIS OF A BORON-CONTAINING ZEOLITE WITH AN MWW FRAMEWORK STRUCTURE 审中-公开
    具有MWW框架结构的含硼硼沸石的合成

    公开(公告)号：WO2015185633A9

    公开(公告)日：2016-05-26

    申请号：PCT/EP2015062385

    申请日：2015-06-03

    Applicant: BASF SE

    Inventor： MAURER STEFAN ,  PARVULESCU ANDREI-NICOLAE ,  MÜLLER ULRICH ,  XIAO FENG-SHOU ,  MENG XIANGJU ,  WU YEQING

    IPC: C01B39/12 ,  C01B39/48

    CPC classification number: C01B39/48 ,  C01B39/12

    Abstract: The present invention relates to a process for the production of a boron-containing zeolitic material having an MWW framework structure comprising YO2 and B2O3, wherein Y stands for a tetravalent element, wherein said process comprises (a) providing a mixture comprising one or more sources for YO2, one or more sources for B2O3, one or more organotemplates, and seed crystals, (b) crystallizing the mixture obtained in (a) for obtaining a layered precursor of the boron-containing MWW-type zeolitic material, (c) calcining the layered precursor obtained in (b) for obtaining the boron-containing zeolitic material having an MWW framework structure, wherein the one or more organotemplates have the formula (I): R1R2R3N, wherein R1 is (C5-C8)cycloalkyl, and wherein R2 and R3 are independently from each other H or alkyl, as well as to a synthetic boron-containing zeolite which is obtainable and/or obtained according to the inventive process as well as to its use.

    Abstract translation: 本发明涉及一种生产具有包含YO 2和B 2 O 3的MWW骨架结构的含硼沸石材料的方法，其中Y代表四价元素，其中所述方法包括（a）提供包含一种或多种来源的混合物 对于YO2，一种或多种B 2 O 3，一种或多种有机模板和晶种的来源，（b）使（a）中获得的混合物结晶以获得含硼MWW型沸石材料的层状前体，（c）煅烧 （b）中获得的用于获得具有MWW骨架结构的含硼沸石材料的层状前体，其中所述一种或多种有机模板具有式（I）：R1R2R3N，其中R1是（C5-C8）环烷基，其中R2 和R3彼此独立地为H或烷基，以及可根据本发明方法获得和/或获得的合成含硼沸石以及其用途。

    SILICON-BRIDGED PILLARED SILICATE COMPOUNDS AND PROCESS FOR THEIR PRODUCTION
    6.
    发明申请
    SILICON-BRIDGED PILLARED SILICATE COMPOUNDS AND PROCESS FOR THEIR PRODUCTION 审中-公开
    有机硅填料的硅酸盐化合物及其生产工艺

    公开(公告)号：WO2015032851A3

    公开(公告)日：2015-06-04

    申请号：PCT/EP2014068822

    申请日：2014-09-04

    Applicant: BASF SE ,  TOKYO INST TECH

    Inventor： FEYEN MATHIAS ,  RUETZ ROGER ,  MÜLLER ULRICH ,  GAAB MANUELA ,  BAO XINHE ,  ZHANG WEIPING ,  DE VOS DIRK ,  WEISS RALF ,  GIES HERMANN ,  TATSUMI TAKASHI ,  XIAO FENG-SHOU ,  TOSHIYUKI YOKOI ,  YILMAZ BILGE ,  DE BAERDEMAEKER TREES

    IPC: C01B37/02 ,  B01J29/035 ,  B01J29/04 ,  C01B33/38 ,  C01B39/02 ,  C01B39/46 ,  C01B39/48 ,  C04B35/16 ,  C07C1/20 ,  C07C11/02 ,  C10G3/00

    CPC classification number: B01J29/035 ,  B01J29/049 ,  B01J29/06 ,  B01J35/002 ,  B01J35/1019 ,  B01J2229/32 ,  B01J2229/37 ,  B01J2229/40 ,  B01J2229/42 ,  C01B33/38 ,  C04B35/16 ,  C04B2235/5409 ,  C07C1/20 ,  C07C2521/08 ,  C07C2529/00 ,  C07C11/02

    Abstract: The present invention relates to a process for the preparation of a pillared silicate compound comprising a layered silicate structure and bridging silicon atoms located between adjacent silicate layers of the silicate structure, wherein said bridging silicon atoms form at least one covalent bond to each of the adjacent silicate layers, said process comprising (1) providing one or more layered silicates; (2) adding said one or more layered silicates to a solvent system, wherein the resulting mixture has a pH of 5 or less; and (3) subjecting the mixture obtained in step (2) to solvothermal conditions; wherein no silicon-containing compound according to formula (I) R4-mSi[-(SiR2)n-R]m (I) is used at any point of the process up to and including step (3), wherein m is 1, 2, 3, or 4, and n is an integer greater than or equal to 0, wherein when n is equal to 0, one or more residues R are leaving groups, and wherein none of the residues R contains Si, as well as to a pillared silicate compound per se, preferably as obtained and/or obtainable according to the inventive process as well as to the use of the inventive compounds. A further process is disclosed wherein a sulfur oxoacid is present in step (2), and wherein a silicon-containing compound may or may not be used.

    Abstract translation: 本发明涉及一种制备柱状硅酸盐化合物的方法，其包括层状硅酸盐结构和位于硅酸盐结构的相邻硅酸盐层之间的桥连硅原子，其中所述桥连硅原子与相邻的每个相邻的硅酸盐层形成至少一个共价键 所述方法包括（1）提供一层或多层层状硅酸盐; （2）将所述一种或多种层状硅酸盐加入到溶剂体系中，其中所得混合物的pH为5以下; 和（3）将步骤（2）中获得的混合物经受溶剂热条件; 其中在直到并包括步骤（3）的任何一个步骤中，不使用根据式（I）的含硅化合物R 4-m Si [ - （SiR 2）n R] m（I），其中m为1,2， 3或4，并且n是大于或等于0的整数，其中当n等于0时，一个或多个残基R是离去基团，并且其中残基R中没有一个含有Si，以及被支化的 硅酸盐化合物本身，优选根据本发明方法获得和/或可获得，以及本发明化合物的用途。 公开了另一种方法，其中在步骤（2）中存在硫含氧酸，并且其中可以使用或不使用含硅化合物。

    Catalyst for the Conversion of Syngas to Olefins and Preparation Thereof
    8.
    发明申请
    Catalyst for the Conversion of Syngas to Olefins and Preparation Thereof 审中-公开
    合成气转化为烯烃及其制备的催化剂

    公开(公告)号：WO2014060982A3

    公开(公告)日：2014-06-12

    申请号：PCT/IB2013059417

    申请日：2013-10-17

    Applicant: BASF SE ,  BASF CHINA CO LTD ,  TOKYO INST TECH

    Inventor： YILMAZ BILGE ,  MÜLLER ULRICH ,  BAO XINHE ,  ZHANG WEIPING ,  DE VOS DIRK ,  TATSUMI TAKASHI ,  XIAO FENG-SHOU ,  GIES HERMANN ,  IMAI HIROYUKI

    IPC: C01B37/00 ,  C01B37/02

    CPC classification number: C07C1/044 ,  B01J29/76 ,  B01J29/89 ,  B01J35/1019 ,  B01J35/1028 ,  B01J35/1038 ,  B01J35/1042 ,  B01J2229/186 ,  C10G25/003 ,  C10G25/03

    Abstract: A process for the production of a pillared silicate comprises: (i) providing a layered silicate; (ii) interlayer expanding the layered silicate provided in step (i) comprising a step of treating the layered silicate with one or more swelling agents; (iii) treating the interlayer expanded silicate with one or more hydrolysable silicon containing compounds; (iv) treating the interlayer expanded compound with an aqueous solution to obtain a pillared silicate; (v) removing at least a portion of the one or more swelling agents from the pillared silicate; (vi) impregnating the pillared silicate with one or more elements selected from the group consisting of Fe, Ru, Ir, and combinations of two or more thereof, as well as to a pillared silicate optionally obtainable from said process and its use, in particular in a process for the production of one or more olefins.

    Abstract translation: 用于生产柱状硅酸盐的方法包括：（i）提供层状硅酸盐; （ii）层间膨胀步骤（i）中提供的层状硅酸盐，包括用一种或多种溶胀剂处理层状硅酸盐的步骤; （iii）用一种或多种可水解含硅化合物处理层间发泡硅酸盐; （iv）用水溶液处理层间发泡化合物，得到柱状硅酸盐; （v）从柱状硅酸盐中去除至少一部分一种或多种溶胀剂; （vi）用一种或多种选自Fe，Ru，Ir及其两种或多种的组合的一种或多种元素浸渍柱状硅酸盐，以及任选地可从所述方法获得的柱状硅酸盐及其用途，特别是 在一种制备一种或多种烯烃的方法中。

    STORAGE UNIT FOR DRIVE SYSTEM IN VEHICLE AND METHOD FOR OPERATING THE SAME
    10.
    发明申请
    STORAGE UNIT FOR DRIVE SYSTEM IN VEHICLE AND METHOD FOR OPERATING THE SAME 审中-公开
    车辆驱动系统的存储单元及其操作方法

    公开(公告)号：WO2014083536A3

    公开(公告)日：2014-07-31

    申请号：PCT/IB2013060493

    申请日：2013-11-29

    Applicant: BASF SE ,  BASF CHINA CO LTD

    Inventor： WEICKERT MATHIAS ,  MARX STEFAN ,  MÜLLER ULRICH ,  WINKLER CHRISTIAN-ANDREAS

    IPC: B60K11/00 ,  B60H1/00

    CPC classification number: H01M8/0681 ,  H01M8/04029 ,  H01M10/625 ,  H01M10/6568 ,  H01M10/66

    Abstract: Provided are a storage unit (12) for a drive system (10) in a vehicle and a method of operating the storage unit (12). The storage unit (12) has at least one sorption store (18),at least one battery (16) and at least one cooling circuit (26), the sorption store (18) is coupled via the cooling circuit (26) to the battery (16). Heat is exchanged between the battery (16) and the sorption store (18). It can provide a very simple and efficient heat management concept for such storage unit (12).

    Abstract translation: 提供一种用于车辆中的驱动系统（10）的存储单元（12）和操作该存储单元（12）的方法。 存储单元（12）具有至少一个吸附存储器（18），至少一个电池（16）和至少一个冷却回路（26），吸附存储器（18）经由冷却回路（26）耦合到 电池（16）。 在电池（16）和吸附储存器（18）之间交换热量。 它可以为这种存储单元（12）提供非常简单和有效的热管理概念。

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